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Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006071
EISBN: 978-1-62708-172-6
... resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides...
Abstract
An alkyd is an ester-based polymer derived from the polycondensation reaction of polyhydric alcohol and polybasic acid. This article provides useful information on the chemistry, production, coating formulations, modification, commercial products, and application methods of alkyd resins. It also provides a section on drying oil, which is used in the manufacture of resins. The article describes the three categories of metals that have been used in drier compounds: primary driers (active or oxidation driers), secondary driers (through-driers), and auxiliary driers. It also provides information on the oil length of an alkyd resin and on solvents, which play a critical role in the formulation and use of the coating. The article concludes with a description of the concerns that a user, specifier, or applicator should be aware of when using alkyd coatings.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... Alkyds Good resistance to atmospheric weathering and moderate chemical fumes; not resistant to chemical splash and spillage. Long oil alkyds have good penetration but are slow drying; short oil alkyds are fast drying. Temperature resistant to 105 °C (225 °F) Not chemically resistant; not suitable...
Abstract
This article discusses the coating systems categorized by the generic type of binder or resin and grouped according to the curing or hardening mechanism inherent within that generic type. It focuses on the properties, advantages, and limitations of various autooxidative cross-linked resins, thermoplastic resins, and cross-linked thermosetting resins. The autooxidative cross-linked resins include alkyd resins and epoxy esters. The article examines the two types of coatings based on thermoplastic resins: those deposited by evaporation of a solvent, commonly called lacquers, and those deposited by evaporation of water, a class of coatings called water-borne coatings. The coatings that chemically cross link by copolymerization, including epoxies, unsaturated polyesters, urethanes, high-temperature curing silicones, and phenolic linings, are also described.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006051
EISBN: 978-1-62708-172-6
... but are slow drying; short-oil alkyds are fast drying. Temperature resistant to 105 °C (225 °F) Not chemically resistant; not suitable for application over alkaline surfaces, such as fresh concrete, or for water immersion Long-oil alkyds make excellent primers for rusted and pitted steel and wooden surfaces...
Abstract
A coating can be defined as a substance spread over a surface to provide protection or to serve decorative purposes. This article discusses two industrial coating components, namely, nonvolatile components such as the resin or binder, pigments, and any additives that may be incorporated into the formulation; and volatile components such as solvents, or water in emulsions and their composition. It provides general information on volatile organic compounds. The article describes the film-forming mechanisms of various coating types, namely, lacquers, chemically converting coatings, latex coatings, alkyds and other resins, which cure by oxidation, moisture-curing polyurethanes and inorganic zinc primers, and powder coatings. The article concludes with a discussion on the functions of the primer, intermediate coat, and topcoat in coating systems.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001277
EISBN: 978-1-62708-170-2
..., epoxies, alkyds, or drying oils as binding or drying agents. Air drying or baking putties can be used, although air drying putty is most frequently used. Baking of thick putty films, either for curing the putty or for curing subsequent paint films, usually results in blisters or pinholes, because...
Abstract
Painting is a generic term for the application of a thin organic coating to the surface of a material for decorative, protective, or functional purposes. This article provides a detailed account of the types and selection factors of paints and the various application methods, including conventional air atomized, airless, and electrostatic spray; roller coating; dip coating; flow coating; curtain coating; tumble coating; electrocoating; and powder coating. Surface preparation methods and prepaint treatments for coating systems are also discussed. The article includes information on quality control procedures, causes of paint film defects, cost calculation, and safety and environmental precautions. The composition and characteristics of organic coatings, coating system selection factors, the types of paints for structural steel, and the applications of paint on structural steel are also reviewed.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006024
EISBN: 978-1-62708-172-6
... Abstract This article reviews the steps involved in presurface-preparation inspection: substrate replacement; removal of weld spatter, rounding of sharp edges, and grinding of slivers/laminations; and removal of rust scale, grease, oil, and chemical (soluble salt) contamination. It focuses...
Abstract
This article reviews the steps involved in presurface-preparation inspection: substrate replacement; removal of weld spatter, rounding of sharp edges, and grinding of slivers/laminations; and removal of rust scale, grease, oil, and chemical (soluble salt) contamination. It focuses on surface preparation methods that range from simple solvent cleaning to hand and power tool cleaning, dry and wet abrasive blast cleaning, centrifugal wheel blast cleaning, chemical stripping, and waterjetting for the application of the coating system. In addition, the article provides a description of the Society for Protective Coatings' (SSPC) standards and NACE International standards as well as the International Organization for Standardization (ISO) standards and International Concrete Repair Institute (ICRI) guidelines for surface cleanliness.
Book Chapter
Shop and Field Quality Control and Quality Assurance
Available to PurchaseSeries: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006016
EISBN: 978-1-62708-172-6
... cleanliness Visual Removal of all visible grease, oil, and debris Verify correct type and cleanliness of abrasive media Visual and conductivity meter Expendable, angular slag, no visible oil; <1000 μS/cm conductivity Verify compressed air cleanliness Blotter test Clean, dry air; no evidence...
Abstract
This article discusses the concepts of quality control (QC) and quality assurance (QA), and clarifies the differences and similarities in the roles and responsibilities of QC and QA personnel. It describes the inspection procedures used to verify proper surface preparation and installation of the protective coating/lining system. Prior to beginning surface-preparation operations, many specifications will require a presurface-preparation inspection to verify the correction of fabrication defects and removal of surface contamination such as grease, oil, cutting compounds, lubricants, and chemical contaminants. When inspecting concrete prior to coating installation, three areas of concern exist: surface roughness, moisture content in concrete, and acidity/alkalinity of the surface. The article provides information on the industry standards for assessing surface cleanliness. It details postcoating application quality requirements, including measuring of dry-film thickness, assessing intercoat cleanliness, verifying minimum and maximum recoat intervals, performing holiday/pinhole detection, conducting cure/hardness testing, and assessing adhesion of the applied coating system.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001276
EISBN: 978-1-62708-170-2
... compound, bituminous, solvent type, black Black asphalt, dry coating; solvent cutback Protect battery racks; coat interior of projectiles MIL-C-4339 Corrosion-preventive soluble oil, for water-injection systems Mineral oil with emulsifying agents and inhibitors Protection against corrosion by water...
Abstract
Rust-preventive compounds are removable coatings used for the protection of the surfaces of iron, steel, coated or galvanized products, and other alloys. This article describes the basic parts of rust-preventive compounds, namely, carrier, film former, polar materials, and specialty additives. It explains types of rust-preventive compounds, including dry films and water-based dry films. The article also discusses the methods of application of various compounds, such as petrolatum compounds and emulsion compounds. It contains tables that provide information on the characteristics, applications, and physical properties of rust-preventive materials covered by military specifications. Finally, the article describes the various considerations and parameters for selecting rust-preventive materials.
Book Chapter
Corrosion of Metal Artifacts and Works of Art in Museum and Collection Environments
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004140
EISBN: 978-1-62708-184-9
... hydrolyze and release corrosive lower fatty acids. Drying oil, semidrying oil paints, or paints containing esters of volatile acids are potential sources of corrosive vapors ( Ref 15 ). Although damage to artifacts was first reported in the late 19th century ( Ref 16 ), it was only in the middle decades...
Abstract
This article presents a general survey of corrosive agents and processes that exist within what are usually considered the protective environments of museums and historic collections. It reviews the corrosion influencing factors, such as humidity, temperature, and light. The article provides a list of pollutants and their sources in museums and collections. It discusses the sources of corrosion, including plastic and wood, sulfur, and carbonyl compounds. The article describes the preservation steps for materials in museum to eliminate the corrosive sources acting on the objects and to avoid other potentially damaging materials.
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Effect of baking time and temperature on tensile strength of oil-sand cores...
Available to PurchasePublished: 01 December 2008
Fig. 7 Effect of baking time and temperature on tensile strength of oil-sand cores. The dry mixture was 99% silica sand (fineness, AFS 40) and 1% cereal. Based on total weight of dry material, 1% linseed oil and 3% water were added.
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004108
EISBN: 978-1-62708-184-9
... in.); such thick films would not be possible in a paint containing volatile solvents, because the thickness of the film would prevent solvent evaporation. Paints can be classified by the type of binder or resin into categories: Air-drying oils (for example, linseed oil, alkyds) Lacquers (vinyls...
Abstract
Organic coatings are the principal means of corrosion control for the hulls and topsides of ships and for the splash zones on permanent offshore structures. This article describes surface preparation which is the most important consideration in determining the performance of organic coating systems. It contains a table that lists the uses and applicable standards for various surface preparation techniques. The article provides information on organic coatings in topside coating systems and reviews the importance of primers in the protection of steel substrates. It also explains the property requirements and the common types of immersion coatings.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004126
EISBN: 978-1-62708-184-9
... Abstract This article focuses on the various coatings used on Department of Defense (DoD) systems. These include electroplated coatings; conversion coatings; supplemental oils, waxes, and lubricants; organic paint coatings; and other finishes such as vacuum deposits, mechanical plating, thermal...
Abstract
This article focuses on the various coatings used on Department of Defense (DoD) systems. These include electroplated coatings; conversion coatings; supplemental oils, waxes, and lubricants; organic paint coatings; and other finishes such as vacuum deposits, mechanical plating, thermal spray coatings, and hot-dip coatings. The article also lists the test requirements and time to failure of the coatings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001224
EISBN: 978-1-62708-170-2
... be required to remove the alkaline. If parts must come out of the system dry, then an ambient or heated air drier must be included. Thus, many emulsion cleaning systems have four stages, which will be discussed below. Concerns and Limitations Oil-Like Residue If the oil-like residue is not desired...
Abstract
Emulsion cleaning is an industrial cleaning process that uses an organic solvent as the main active agent. This article provides information on the applications, concerns and limitations, and process parameters of emulsion cleaning. It describes the processing variables and equipment for three main stages of emulsion cleaning: immersion cleaning, secondary cleaning, and spray cleaning. In addition, the classifications, composition, and selection criteria are also discussed.
Book Chapter
Vapor Degreasing Alternatives
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001324
EISBN: 978-1-62708-170-2
... hydrocarbon-based oils, salts, and water-based materials. Treatment of spent aqueous solutions and rinse water can also often be accomplished on site. Disadvantages These systems generally require wash, rinse, and dry stages as a minimum. This often means that additional floor space is required...
Abstract
The chemicals that have been used in traditional vapor degreasing have serious health and environmental hazards that have prompted the search for modified and alternative techniques. This article provides a detailed discussion on the regulatory mandates that affect the use of industrial degreasing methods. It describes the aqueous degreasing technique, which forms an attractive alternative to the traditional vapor degreasing process. The article includes information on the materials and equipment used in the process, and discusses the advantages and disadvantages of hot and dip tank systems of aqueous degreasing. It explains how to convert an existing vapor degreaser to an aqueous cleaning system.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006073
EISBN: 978-1-62708-172-6
... or noncorrosive contact type of fireproofing 1A: Interior, normally dry (or temporary protection). Very mild (oil-base paints do not last six years or more) 1B: Exteriors, normally dry (includes most areas where oil-based paints last six years or more) 2A: Frequently wet with freshwater. Involves...
Abstract
This article discusses the environmental influences on protective coating films that can result in deterioration. These environmental factors can be classified into four groups: (1) energy: solar, heat; (2) permeation: moisture, solvent, chemical, and gas; (3) stress: drying and curing-internal stress, and vibration-external stress; and (4) biological influences such as microbiological, mildew, and marine fouling.
Book Chapter
Solvent Cold Cleaning and Vapor Degreasing
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001223
EISBN: 978-1-62708-170-2
... recovery solvent waste solvent waste disposal spray system equipment surface preparation temperature baths vapor degreasing SOLVENT CLEANING is a surface preparation process that is especially adept at removing organic compounds such as grease or oil from the surface of a metal. Most organic...
Abstract
Solvent cleaning is a surface preparation process that can be accomplished in room temperature baths (cold cleaning ) or by condensing vapors of a solvent on a workpiece (vapor degreasing). This article provides a detailed discussion on solvents, equipment, process limitations and applications, and safety and health hazards of cold cleaning and vapor degreasing. It also includes information on control of contamination, conservation and recovery of solvent, and disposal of solvent wastes.
Book Chapter
Liquid-Penetrant Inspection
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003231
EISBN: 978-1-62708-199-3
... be free from oil, water, and other contaminants for at least 25 mm (1 in.) beyond the area being inspected to increase the probability of detection. Penetrant Application Liquid penetrant is applied in a suitable manner to form a film of the penetrant over the surface for at least 13 mm ( 1 2...
Abstract
Liquid-penetrant inspection is a nondestructive method used to find discontinuities that are open to the surface of solid, essentially nonporous materials. This article describes the physical principles and the process of liquid-penetrant inspection. It also describes the basic penetrant systems, such as the water-washable system, the post-emulsifiable system, and the solvent-removable system. The article provides information on the liquid-penetrant materials, emulsifiers, solvent cleaners, and developers. It details the equipment requirements, selection of penetrant system, and specifications and standards for the liquid-penetrant inspection.
Book Chapter
Phosphate Coatings
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001274
EISBN: 978-1-62708-170-2
... is used to increase the corrosion resistance of these coatings. Frequently, phosphate-coated articles are finished by a dip in nondrying or drying oils that contain corrosion inhibitors. The articles are then drained or centrifuged to remove the excess oil. Medium to heavy zinc phosphate coatings...
Abstract
This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating, rinsing after phosphating, and chromic acid rinsing. The article describes the techniques for controlling the chemical composition of various phosphating solutions. It discusses the equipment and factors that influence equipment requirements in immersion and spray systems. The article also describes the controlling procedures of coating weight and crystal size. It provides guidelines for choosing phosphate coatings based on application, coating weight requirements, and recommended process parameters. The article concludes with a discussion on safety precautions and the treatment of effluents from phosphating plants.
Book Chapter
Cutting Fluids
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003189
EISBN: 978-1-62708-199-3
..., advantages and limitations of cutting and grinding fluids, such as cutting oils, water-miscible fluids, gaseous fluids, pastes, and solid lubricants along with their subtypes. It discusses the factors considered during the selection of cutting fluid, focusing on machinability (or grindability...
Abstract
Cutting fluids play a major role in increasing productivity and reducing costs by making possible the use of higher cutting speeds, higher feed rates, and greater depths of cut. After listing the functions of cutting fluids, this article then covers the major types, characteristics, advantages and limitations of cutting and grinding fluids, such as cutting oils, water-miscible fluids, gaseous fluids, pastes, and solid lubricants along with their subtypes. It discusses the factors considered during the selection of cutting fluid, focusing on machinability (or grindability) of the material, compatibility (metallurgical, chemical, and human), and acceptability (fluid properties, reliability, and stability). The article also describes various application methods of cutting fluids and precautions that should be observed by the operator.
Book Chapter
Selection and Use of Lubricants in Forming of Sheet Metal
Available to PurchaseSeries: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005159
EISBN: 978-1-62708-186-3
... used mostly in pastes, greases, and high-viscosity oils designed for use on heavy-gage material or in pressing at elevated temperatures. Some bonded films can survive severe ironing. For demanding applications, particularly for metals that do not react readily with lubricants, dry films deposited from...
Abstract
This article provides an overview of the interfacial interactions with a lubricant film between a die and a metal, lubricant mechanisms, chemistry, qualification testing, application methods, and property test methods. It focuses on sheet metal-forming operations, although the discussions are relevant to metal-forming operations in general. The article also deals with lubricant selection as influenced by the metal to be formed and particular sheet-metal forming operations. The article also discusses some aspects of microbiology and toxicity in lubricants.
Book Chapter
Coremaking
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005244
EISBN: 978-1-62708-187-0
.... Core sands bonded with air-drying binders, such as sodium silicate or portland cement, must be rammed well to bring the sand grains into proper contact. Oil-sand core mixtures do not require hard ramming; many cores are made from oil-sand mixtures by jarring, blowing, or pressing. The size and shape...
Abstract
Cores are separate shapes of sand that are placed in the mold to provide castings with contours, cavities, and passages that are not otherwise practical or physically obtainable by the mold. This article describes the basic principles of coremaking and the types of core sands, binders, and additives used in coremaking. It discusses the curing of compacted cores by core baking and the hot box processes. The article provides an overview of the core coatings, assembling and core setting, coring of tortuous passages, and cores in permanent mold castings and investment castings. It also discusses the design considerations in coremaking to eliminate cores and compares coring with drilling.
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