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This article is an overview of the division Surface Analysis of this volume. The division covers various developed surface-analysis techniques, such as scanning probe and atomic force microscopy. The division focuses on the analysis of surface layers that are less than 100 nm. A quick reference summary of surface-analysis methods is presented in this article.

This article discusses the properties of threaded fasteners made from carbon and low-alloy steels containing a maximum of 0.55% carbon. It provides guidelines for the selection of steels for bolts, studs, and nuts intended for use at temperatures between -50 and 370 deg C. The article also discusses steels rated for service above 370 deg C and describes internationally recognized grade designations. The specifications provided can be used to outline fastener requirements, control manufacturing processes, and establish functional or performance standards. The most commonly used protective metal coatings for ferrous metal fasteners; zinc, cadmium, and aluminum; are described as well.

Steel sheet is often coated in coil form prior to fabrication to save time, reduce production costs, and streamline operations. This article examines the most common precoating methods and provides a metallurgical understanding of how they impact the manufacturability, performance, and service life of the host material. The article covers metallic coatings, including zinc, aluminum, zinc-aluminum alloys, tin, and terne; pretreatment or phosphate coatings; and preprimed and painted finishes based on organic coatings.

Hot-rolled steel bars and other hot-rolled steel shapes are produced from ingots, blooms, or billets converted from ingots or from strand cast blooms or billets and comprise a variety of sizes and cross sections. Most carbon steel and alloy steel hot-rolled bars and shapes contain surface imperfections with varying degrees of severity. Seams, laps, and slivers are probably the most common defects in hot-rolled bars and shapes. Another condition that could be considered a surface defect is decarburization. Hot-rolled steel bars and shapes can be produced to chemical composition ranges or limits, mechanical property requirements, or both. Hot-rolled carbon steel bars are produced to two primary quality levels: merchant quality and special quality. Merchant quality is the least restrictive descriptor for hot-rolled carbon steel bars. Special quality bars are employed when end use, method of fabrication, or subsequent processing treatment requires characteristics not available in merchant quality bars.

Structural steels with very high strength levels are often referred to as ultrahigh-strength steels. This article describes the commercial structural steels capable of a minimum yield strength of 1380 MPa (200 ksi). The ultrahigh-strength class of constructional steels includes several distinctly different families of steels. The article focuses on medium-carbon low-alloy steels, medium-alloy air-hardening steels, and high fracture toughness steels. The medium-carbon low-alloy family of ultrahigh-strength steels includes AISI/SAE 4130, the higher-strength 4140, and the deeper hardening, higher-strength 4340. Also from this family are descriptions for the 300M, D-6a and D-6ac, 6150, and 8640 steels. The medium-alloy air-hardening family of ultrahigh-strength steels includes H11 modified and H13 steels. The high fracture toughness family of ultrahigh-strength steels includes HP-9-4-30 steel and AF1410 steel. The article explains the mechanical properties and the heat treatments of the medium-carbon low-alloy steels, medium-alloy air-hardening steels, and high fracture toughness steels.

Carbon steels have wider usage than any other metal because of their versatility and low cost. Required hardenability is the most important factor influencing a choice between carbon- and alloy steel. By increasing hardenability, alloying elements extend the potential for enhanced properties to the large sections required for many applications. Alloy steels are ordinarily quench hardened and tempered to the level of strength desired for the application. Distortion during heat treatment may occur with almost any hardenable carbon or alloy steel, although distortion is usually more severe for carbon grades than for alloy grades of equivalent carbon content. The relatively low hardenability of carbon steels is a primary reason for choosing them in preference to alloy steels for parts that are to be locally heat treated by flame or induction hardening. Fabrication processes are performed on hardenable carbon and alloy steels in the unhardened condition, that is, prior to heat treating.

This article discusses the composition, characteristics, and properties of the five groups of wrought stainless steels: martensitic stainless steels, ferritic stainless steels, austenitic stainless steels, duplex stainless steels, and precipitation-hardening stainless steels. The selection of stainless steels may be based on corrosion resistance, fabrication characteristics, availability, mechanical properties in specific temperature ranges and product cost. The fabrication characteristics of stainless steels include formability, forgeability, machinability, and weldability. The product forms of wrought stainless steels are plate, sheet, strip, foil, bar, wire, semifinished products, pipes, tubes, and tubing. The article describes tensile properties, elevated-temperature properties, subzero-temperature properties, physical properties, corrosion properties, and fatigue strength of stainless steels. It characterizes the experience of a few industrial sectors according to the corrosion problems most frequently encountered and suggests appropriate grade selections. Corrosion testing, surface finishing, mill finishes, and interim surface protection of stainless steels are also discussed.

This article discusses the compositions, properties, and typical applications for ductile irons that are defined by U.S. and international standards . It describes the various methods used to test and inspect the metallurgical control processes in ductile iron production. The article discusses the effect of composition, graphite shape, and section size on the properties of ductile iron. The article also describes the mechanical properties of ductile iron at elevated temperatures. The heat treatment of ductile iron castings produces a significant difference in mechanical properties from as-cast ductile iron. A ductile iron generally has higher hardenability than a eutectoid steel with comparable alloy content. The article also discusses the physical properties of ductile iron, including density, thermal conductivity, electrical conductivity, electrical resistivity, and magnetic properties. Ductile iron has been chosen in many instances on the basis of significantly lower machining costs, which resulted in lower overall cost of the part.

This article addresses classifications and designations for carbon and low-alloy steel sheet and strip product forms based on composition, quality descriptors, mechanical properties, and other factors. Carbon steel sheet and strip are available as hot-rolled and as cold-rolled products. Low-alloy steel sheet and strip are used primarily for applications that require the mechanical properties normally obtained by heat treatment. The descriptors of quality used for hot-rolled plain carbon steel sheet and strip and cold-rolled plain carbon steel sheet include structural quality, commercial quality, drawing quality, and drawing quality, special killed. The surface texture of low-carbon cold-rolled steel sheet and strip can be varied between rather wide limits. The modified low-carbon steel grades discussed in the article are designed to provide sheet and strip products having increased strength, formability, and/or corrosion resistance. The article also summarizes the key operations involved in the three alternative direct casting processes: thin slab, thin strip, and spray casting.

Damage to steels from neutron irradiation affects the properties of steels and is an important factor in the design of safe and economical components for fission and fusion reactors. This article discusses the effects of high-energy neutrons on steels. The effects of damage caused by neutron irradiation include swelling (volume increase), irradiation hardening, and irradiation embrittlement (the influence of irradiation hardening on fracture toughness). These effects are primarily associated with high-energy (greater than 0.1 MeV) neutrons. Consequently, irradiation damage from neutrons is of considerable importance in fast reactors, which produce a significant flux of high-energy neutrons during operation. Irradiation embrittlement must also be considered in the development of ferritic steels for fast reactors and fusion reactors. Although ferritic steels are more resistant to swelling than austenitic steels, irradiation may have a more critical effect on the mechanical properties of ferritic steels.

This article provides information on the infiltration mechanism of carbide structures. It reviews the basic techniques used for metal infiltration, including dip infiltration, contact filtration, gravity feed infiltration, and external-pressure infiltration. The article highlights various applications of contact infiltration in oil, gas, and blast-hole drilling such as fixed-cutter drill bits and diamond-impregnated coring bits. It also discusses the applications of infiltrated carbide material in erosion-resistant cladding.

Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.

This article discusses the chief magnetic characteristics of permanent magnet materials. It provides a detailed description on nominal compositions; principal magnet designations; magnetic, physical, and mechanical properties; selection criteria; and applications of the permanent magnet materials, which include magnet steels, magnet alloys, alnico alloys, platinum-cobalt alloys, cobalt and rare-earth alloys, hard ferrites, iron-chromium-cobalt alloys, and neodymium-iron-boron alloys.