This article reviews the concepts considered important for an understanding of the processes used for preparing cobalt-chromium alloy implants, the microstructures resulting from this processing, and the resulting material properties. The review includes solidification of alloys, diffusionless (martensitic) phase transformation as occurs with face-centered cubic to hexagonal close-packed transformation in cobalt-chromium alloys, and stacking faults and twins and their role in this transformation. It also discusses the strengthening mechanisms that are responsible for the mechanical properties of cast and wrought cobalt alloys. The article contains tables that list the commonly used cobalt alloys and their biomedical applications and chemical compositions. It discusses the mechanical and corrosion properties of cobalt alloys, and provides a description of the microstructure of cobalt alloys.

This article focuses on the fractography of Nitinol, a shape memory alloy of nickel and titanium, in superelastic biomedical applications, which primarily comprise drawn and/or laser-cut wire and tube components. Overload fracture, hydrogen embrittlement fracture, and fatigue fracture are discussed in detail.

Martensite is a metastable structure that forms during athermal (nonisothermal) conditions. This article reviews the crystallographic theory, morphologies, orientation relationships, habit plane, and transformation temperature of ferrous martensite microstructures. It examines the stages of the tempering process involved in ferrous martensite. The article also describes the formation of the martensite structure in nonferrous systems. It concludes with a discussion on shape memory alloys.

This article introduces the mechanism of diffusion and the common types of heat treatments such as annealing and precipitation hardening, which are applicable to most ferrous and nonferrous systems. Three distinct processes occur during annealing: recovery, recrystallization, and grain growth. The article also describes the various types of solid-state transformations such as isothermal transformation and athermal transformation, resulting from the heat treatment of nonferrous alloys. It provides information on the homogenization of chemical composition within a cast structure.

This article introduces basic physical metallurgy concepts that may be useful for understanding and interpreting variations in metallographic features and how processing affects microstructure. It presents some basic concepts in structure-property relationships. The article describes the use of equilibrium binary phase diagrams as a tool in the interpretation of microstructures. It reviews an account of the two types of solid-state phase transformations: isothermal and athermal. The article discusses isothermal transformation and continuous cooling transformation diagrams which are useful in determining the conditions for proper heat treatment (solid-state transformation) of metals and alloys. The influence of the mechanisms of phase nucleation and growth on the morphology, size, and distribution of grains and second phases is also described.

Dual-phase steels are a new class of high-strength low alloy (HSLA) steels characterized by a microstructure consisting of about 20% hard martensite particles dispersed in a soft ductile ferrite matrix. In addition to high tensile strength, in the range of 550 MPa (80 ksi), dual-phase steels exhibit continuous yielding behavior, a low 0.2% offset yield strength, and a higher total elongation than other HSLA steels of similar strength. The article discusses some of the more pertinent aspects of dual-phase steels, such as heat treatment, microstructure, mechanical properties, chemical composition, and manufacturability. In general, these steels have a carbon content of less than 0.1%, which ensures that they can be spot welded. However, newer high-carbon dual-phase steels in development are generating interest due to their unique combination of total elongation and tensile strength.

This article provides a detailed discussion on the heat treatment processes for titanium and titanium alloys. These processes are age hardening, solution treatment, aging, and annealing. The article illustrates the characteristics of equilibrium phase diagrams that are important for understanding the heat treatment of titanium alloys. It explains the types of metastable phases encountered in titanium alloys. The article also provides information on the equilibrium phase relationships and properties of titanium alloys.

This article is a compilation of definitions of terms related to metallography and microstructures.

This article describes microstructures and microstructure-property relationships in steels. It emphasizes the correlation of microstructure and properties as a function of carbon content and processing in low-alloy steels. The article discusses the iron-carbon phase diagram and the phase transformations that change the structure and properties at varying levels of carbon content. Microstructures described include pearlite, bainite, proeutectoid ferrite and cementite, ferrite-pearlite, and martensite. The article depicts some of the primary processing steps that result in ferrite-pearlite microstructures. It shows the range of hardness levels which may be obtained by tempering at various temperatures as a function of the carbon content of the steel. To reduce the number of processing steps associated with producing quenched and tempered microstructures, new alloying approaches have been developed to produce high-strength microstructures directly during cooling after forging.

This article provides a discussion on the analytical modeling and simulation of residual stress states developed in steel parts and the reasons for these varied final stress states. It illustrates how the metallurgical phase transformation of steel alloys can be applied in the simulation of induction hardening processes and the role of these phase transformations in affecting stress and distortion. Emphasis is placed on induction surface hardening, which is the main application of induction heating in steel heat treatment. The article concludes with examples of induction surface-hardened shafts and through-hardened shafts made of plain carbon steel, alloy steel, and limited hardenability steel.

Steels are among the most versatile materials in modifying their microstructure and properties by heat treatment. This article outlines the basic concepts of physical metallurgy relating to the heat treatment of steel. It considers the phases and microstructures of steel together with the transformations observed and critical temperatures during heat treatment. Additionally, the different types of steels, heat treatments, and their purposes are also discussed.

Copper steels are precipitation-strengthened steels that are designed to have a unique combination of physical and mechanical properties. This article provides an overview of copper precipitate-strengthened steels and their applications, and discusses appropriate ASTM International standards. It describes the common phases and alloying elements present in copper precipitate-strengthened steels, and reviews the influences of alloying elements on processing, phase diagrams, microstructures, and mechanical properties. The article also discusses the thermomechanical process, solutionizing heat treatment, and isothermal aging in detail. It concludes with a review of the interrelationships between heat treatments, microstructures, and mechanical properties.

Maraging steels are highly alloyed low-carbon iron-nickel martensite steels that possess an excellent combination of strength and toughness superior to that of most carbon-hardened steels. This article provides a detailed account of the formation of martensite in maraging steels. It discusses the heat treatment of these steels, namely, aging, solution annealing, age hardening, and nitriding. Their hardening during aging has been attributed to two different mechanisms: short-range ordering and precipitation. The article concludes with a discussion on the grain refinement using thermal cycling and transformation-induced plasticity maraging methods.

The heat treatment of steel is based on the physical metallurgical principles that relate to its processing, properties, and structure. The microstructures that result from the heat treatment of steel are composed of one or more phases in which the atoms of iron, carbon, and other elements in steel are associated. This article describes the phases of heat treated steel, and provides information on effect of temperature change and the size of carbon atoms relative to that of iron atoms during the heat treatment.

Very high density materials are used for such applications as counterweights and radiation shields. This article focuses on the metallurgy, processing, properties, fabrication, design considerations, health and safety considerations, and applications of the most commonly used very high density materials: depleted uranium and tungsten and their alloys.

This article describes the integration of thermodynamic modeling, mobility database, and phase-transformation crystallography into phase-field modeling and its combination with transformation texture modeling to predict phase equilibrium, phase transformation, microstructure evolution, and transformation texture development during heat treatment of multicomponent alpha/beta and beta titanium alloys. It includes quantitative description of Burgers orientation relationship and path, discussion of lattice correspondence between the alpha and beta phases, and determination of the total number of Burgers correspondence variants and orientation variants. The article also includes calculation of the transformation strain with contributions from defect structures developed at alpha/beta interfaces as a precipitates grow in size. In the CALculation of PHAse Diagram (CALPHAD) framework, the Gibbs free energies and atomic mobilities are established as functions of temperature, pressure, and composition and serve directly as key inputs of any microstructure modeling. The article presents examples of the integrated computation tool set in simulating microstructural evolution.

This article describes the fundamentals of titanium metallographic sample preparation. Representative micrographs are presented for each class of titanium alloys, including unalloyed titanium, alpha alloys, alpha-beta alloys, and beta titanium alloys. The article provides information on the macroexamination and microexamination for these alloys. It concludes with a discussion on the several metallographic techniques developed for specific purposes, such as recrystallization studies and microstructure/fracture topography correlations.

This article discusses the principles of physical metallurgy and metallography of depleted uranium. It describes the techniques involved in the preparation of thin foils for transmission electron microscopy and illustrates the resulting microstructure of uranium and uranium alloys, with the aid of black and white images. The article also provides information on the applications of etching and examination of uranium alloys, at both macro and micro scales, in characterizing the grain structures, segregation patterns, inclusions, and the metal flow geometries produced by solidification and mechanical working processes.