This article focuses on the modeling and simulation of diffusion-controlled processes related to both materials processing such as heat treatments, and materials degradation from a practical perspective by using the one-dimensional (1-D) sharp interface approach. It describes various diffusion simulation models, such as one-phase simulations, moving phase-boundary simulations, and dispersed system simulations. The article presents case studies that illustrate some examples where diffusion simulations have been applied to industrial-based problems, with an emphasis on the approaches used and the lessons learned from performing such simulations.

The thermoreactive deposition and diffusion process is a heat-treatment-based method to form coatings with compacted layers of carbides, nitrides, or carbonitrides, onto some carbon/nitrogen-containing materials, including steels. The amount of active carbide forming elements/nitride forming elements, coating temperatures and time, and thickness of substrates influence the growth rate of coatings. This article lists carbide and nitride coatings that are formed on carbon/nitrogen-containing metallic materials, and describes the coating process and mechanism of coating reagents. It details the growth process and nucleation process of carbide and nitride coatings formed on the metal surface. The article discusses the advantages, disadvantages, and characteristics of the various coating processes, including high-temperature salt bath carbide coating, high-temperature fluidized-bed carbide coating, and low-temperature salt bath nitride coating.

This article describes the solid-phase and liquid-phase processes involved in diffusion bonding of metals. It provides a detailed discussion on the diffusion bonding of steels and their alloys, nonferrous alloys, and dissimilar metals. Ceramic-ceramic diffusion welding and a variation on this process in which ceramic powder compacts are simultaneously sintered and bonded are also discussed.

This article provides a qualitative summary of the theory of diffusion bonding, as distinguished from the mechanisms of other solid-state welding processes. Diffusion bonding can be achieved for materials with adherent surface oxides, but the resultant interface strengths of these materials are considerably less than that measured for the parent material. The article describes three stages of diffusion bonding: microasperity deformation, diffusion-controlled mass transport, and interface migration. It concludes with information on diffusion bonding with interface aids.

This article describes the widespread use of diffusion coatings for elevated-temperature protection of the turbine components for aircraft engines and gas turbines. The principles of pack diffusion coating, namely, aluminizing, chromizing, and siliconizing, are discussed. The article presents information on the coating formation mechanism of superalloys and explains the steps involved in a typical pack cementation process. It concludes with information on the processing procedures and properties of pack aluminized steels.

This article presents various equations that are essential for the modeling of both single-phase and multiphase profiles. It includes the fundamental laws of diffusion, along with its equations and solutions. The article provides information on the series of applications that illustrate how various diffusional processes can be modeled.

Diffusion bonding is only one of many solid-state joining processes wherein joining is accomplished without the need for a liquid interface (brazing) or the creation of a cast product via melting and resolidification. This article offers a qualitative summary of the theory of diffusion bonding. It discusses factors that affect the relative difficulty of diffusion bonding oxide-bearing surfaces. These include surface roughness prior to welding, mechanical properties of the oxide, relative hardness of the metal and its oxide film, and prestraining or work hardening of the material. The article describes the mechanism of diffusion bonding in terms of microasperity deformation, diffusion-controlled mass transport, and interface migration. It concludes with a discussion on diffusion bonding with interface aids.

Diffusion brazing (DFB) is a process that coalesces, or joins, metals by heating them to a suitable brazing temperature at which either a preplaced filler metal will melt and flow by capillary attraction or a liquid phase will form in situ between one faying surface and another. This article discusses the two critical aspects of DFB, namely, a liquid filler metal must be formed and become active in the joint area and extensive diffusion of filler metal elements into the base metal must occur. It schematically illustrates a diffusion process that results in the loss of identity of original brazed joint. The article also discusses the advantages of DFB.

Diffusion welding involves minimal pressurization, but relatively high temperatures and long periods of time. This article discusses the process variants of diffusion welding: solid-phase and liquid-phase processes. It describes the diffusion welding of carbon and low-alloy steels, high-strength steels, stainless steels, and aluminum-base alloys. The article provides a discussion on dissimilar metal combinations, such as ferrous-to-ferrous combinations, nonferrous-to-nonferrous combinations, ferrous-to-nonferrous combinations, and metal-ceramic joining.

The goals of modeling diffusion bonding can be regarded as twofold: to optimize the selection of the process variables for a given material and to provide an understanding of the mechanisms by which bonding is achieved. This article describes the existing models of diffusion bonding with an assumption that the surfaces to be joined are free of contaminants and oxide, that bonding occurs between similar materials, and that the materials are single-phase metals. It discusses the mechanisms considered for diffusion bonding and limitations of existing models.

Diffusion is the process by which molecules, atoms, ions, point defects, or other particle types migrate from a region of higher concentration to one of lower concentration. This article focuses on the diffusivity data and modeling of lattice diffusion in solid-state materials, presenting their diffusion equations. It discusses different methods for evaluating the diffusivity of a material, including the measurement of diffusion coefficients, composition profiles, and layer growth widths. The article reviews the various types of direct and indirect diffusion experiments to extract tracer, intrinsic, and chemical diffusivities. It provides information on the applications of single-phase and multiphase diffusion.