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desulfurization
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004153
EISBN: 978-1-62708-184-9
... Abstract This article begins with a discussion on the components and importance of flue gas desulfurization (FGD) technology used in power plant for pollution control. It further discusses the corrosion problems encountered in different operating zones of FGD system and the major forms...
Abstract
This article begins with a discussion on the components and importance of flue gas desulfurization (FGD) technology used in power plant for pollution control. It further discusses the corrosion problems encountered in different operating zones of FGD system and the major forms of corrosive attack encountered in those zones, including crevice corrosion, pitting corrosion, and acid attack. The article concludes with information on the materials selection and design features for minimizing the possibility of corrosion.
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Published: 01 January 2002
Fig. 26 Cracks in naphtha desulfurization reactor attributed to hydrogen damage. (a) Note decarburized region adjacent to crack. 25×. (b) Higher-magnification view. 200×
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in Failures of Pressure Vessels and Process Piping
> Analysis and Prevention of Component and Equipment Failures
Published: 30 August 2021
Fig. 99 Cracks in naphtha desulfurization reactor attributed to hydrogen damage. (a) Note decarburized region adjacent to crack. Original magnification: 25×. (b) Higher-magnification view. Original magnification: 200×
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Published: 01 January 1990
Fig. 18 Pitting of type 316L stainless steel in flue gas desulfurization scrubber environments. Solid lines indicate zones of differing severity of corrosion; because the zones are not clearly defined, the lines cannot be precisely drawn. Source: Ref 52
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in Metallurgy of Induction Melting Processes for Iron and Non-Iron Materials
> Induction Heating and Heat Treatment
Published: 09 June 2014
Fig. 18 Desulfurization in the through-flow process
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in Metallurgy of Induction Melting Processes for Iron and Non-Iron Materials
> Induction Heating and Heat Treatment
Published: 09 June 2014
Fig. 22 Desulfurization and cleaning steel melts by slag reaction with simultaneous argon flushing in a medium frequency (induction furnace. Source: Ref 27
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Published: 01 December 2008
Fig. 1 Weight fraction desulfurizer required to achieve given desulfurization ratios. Plots for electric-melted iron and steel (curve A) assume initial sulfur concentrations [%(S) i = 0.03] different from those of cupola-melted iron [(%S) i = 0.10] (curve B).
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Published: 01 December 2008
Fig. 2 Desulfurization ratio-basicity comparisons for cupola (closed circles) and laboratory data (open circles). Equilibrium values are indicated by the angled line. The vertical line indicates the slag basicity above which slags are saturated at 1500 °C (2730 °F), with respect to dicalcium
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Published: 01 December 2008
Fig. 3 Slag sulfide capacities, oxygen activities, and desulfurization ratios, measured and calculated, for a cupola operated with municipal ferrous refuse as a charge material. Source: Ref 8
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Published: 01 December 2008
Fig. 4 Equilibrium sulfur concentrations for CaO desulfurization calculated with Eq 11 and 12 , assuming a CaO = a CaS = a SiO 2 = 1. Source: Ref 2
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Published: 01 December 2008
Fig. 6 Desulfurization rates of carbon-saturated iron, containing 0.4% Si, with CaO and varying amounts of CaF 2 at 1450 °C (2640 °F). Source: Ref 9
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Published: 01 December 2008
Fig. 7 Dependence of CaO desulfurization rate constant on the rate of gas flow through a reactor. Source: Ref 16
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Published: 31 August 2017
Fig. 23 Weight ratio desulfurizer required to achieve given desulfurization ratios. Plots for electric-melted iron and steel (line A) assume initial sulfur concentration (%S) i = 0.03, different from that of cupola-melted iron (line B) at (%S) i = 0.01. Source: Ref 35
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Published: 31 August 2017
Fig. 24 Desulfurization rates of carbon-saturated iron, containing 0.4% Si, with CaO and varying amounts of CaF 2 at 1450 °C (2640 °F). Source: Ref 42
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Published: 01 January 1997
Fig. 8 The effect of desulfurization (1280 °C, or 2335 °F, 100 h hydrogen anneal) or yttrium additions (100–150 ppm) on the 1150 °C (2100 °F) cyclic oxidation behavior of René N5. Source: Ref 8
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Published: 01 January 2005
Fig. 16 Pitting of type 316L stainless steel in flue gas desulfurization scrubber environment. Solid lines indicate zones of differing severity of corrosion; because the zones are not clearly defined, the lines cannot be precisely drawn. Source: Ref 39
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005190
EISBN: 978-1-62708-187-0
... Abstract This article addresses two issues on thermodynamics, namely, the calculation of solubility lines and the calculation of the activity of various components. It discusses alloying elements in terms of their influence on the activity of carbon. The article describes the desulfurization...
Abstract
This article addresses two issues on thermodynamics, namely, the calculation of solubility lines and the calculation of the activity of various components. It discusses alloying elements in terms of their influence on the activity of carbon. The article describes the desulfurization and deoxidation of cast iron and steel. It illustrates the thermodynamics of the iron-carbon system and the iron-silicon system. The article examines solubility and saturation degrees of carbon in multicomponent iron-carbon systems. One of the main applications of the thermodynamics of the iron-carbon system is the calculation of structure-composition correlations. The article concludes with information on the structural diagrams for cast iron: the Maurer diagram and the Laplanche diagram.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005903
EISBN: 978-1-62708-167-2
... Abstract Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out...
Abstract
Interplays of metallurgical factors, such as dissolved oxygen, carbon, and silicon content, that control the molten metal from melting to pouring, have a decisive influence on the quality of the castings. This article focuses on the magnesium treatment and desulfurization carried out during inoculation and nucleation of molten cast iron, assisting in the formation of cast iron. The different types of cast irons are gray cast iron, nodular cast iron, compacted graphite iron, malleable cast iron, and alloyed cast iron. The article provides an overview of the melt treatment processes carried out in cast steel, wrought and cast aluminum, and copper materials.
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in Elevated-Temperature Properties of Ferritic Steels
> Properties and Selection: Irons, Steels, and High-Performance Alloys
Published: 01 January 1990
Fig. 31 Effect of temperature and hydrogen sulfide content on high-temperature H 2 S/H 2 corrosion of (a) carbon steel, (b) 5Cr-0.5Mo steel, and (c) 9Cr-1Mo steel. These corrosion rates are based on the use of gas oil desulfurizers; corrosion rates with naphtha desulfurizers may be slightly
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004137
EISBN: 978-1-62708-184-9
... Abstract Corrosion problems and materials selection for emissions control equipment can be difficult because of varied corrosive compounds present and the severe environments encountered. This article discusses the selection of materials for construction of flue gas desulfurization systems...
Abstract
Corrosion problems and materials selection for emissions control equipment can be difficult because of varied corrosive compounds present and the severe environments encountered. This article discusses the selection of materials for construction of flue gas desulfurization systems. It addresses the problems associated with materials for incinerator off-gas treatment equipment. The off-gases can be classified according to their corrosiveness as: industrial chemical, hospital, municipal solid, and sewage sludge. The article provides information on the selection of materials for the three most common types of dust collection equipment used in bulk solids processing, namely, fabric filters, electrostatic precipitators, and wet scrubbers. It also discusses a wide variety of corrosion problems encountered in chemical and pharmaceutical industries.
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