This article discusses the commonly encountered forms of automotive body corrosion. The corrosion forms include general or uniform corrosion, cosmetic or under-film corrosion, galvanic corrosion, crevice corrosion, poultice or under-deposit corrosion, and pitting corrosion. Corrosion-resistant sheet metals, such as electrogalvanized steel, hot dip galvanized steel, and hot dip galvannealed steel, are reviewed. The article provides information on the paint and sealant systems for corrosion control in automotive body applications.

This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

This article discusses the corrosion of chromium electrodeposits and the ways for optimizing corrosion resistance. It describes the processing steps and conditions for hard chromium plating. These steps include pretreatment, electroplating, and posttreatment. The article also provides information on duplex coatings and the applications of chromium electrodeposits.

This article focuses on the various forms of corrosion that occur in the passive range of aluminum and its alloys. It discusses pitting corrosion, galvanic corrosion, deposition corrosion, intergranular corrosion, stress-corrosion cracking, exfoliation corrosion, corrosion fatigue, erosion-corrosion, atmospheric corrosion, filiform corrosion, and corrosion in water and soils. The article describes the effects of composition, microstructure, stress-intensity factor, and nonmetallic building materials on the corrosion behavior of aluminum and its alloys. It also provides information on the corrosion resistance of anodized aluminum in contact with foods, pharmaceuticals, and chemicals.

This article briefly describes water and steam chemistry, which influence the effect of corrosion in boilers. The appropriate control measures to prevent corrosion in boilers are also presented. The article provides a discussion on the common causes of fluid-side corrosion such as flow-accelerated corrosion, oxygen pitting, chelant corrosion, caustic corrosion, acid corrosion, organic corrosion, phosphate corrosion, hydrogen damage, and corrosion-assisted cracking.

This article describes the eight chemical cleaning methods, namely, circulation, fill and soak, cascade, foam, vapor-phase organic, steam-injected, on-line chemical, and mechanical cleaning. It presents information on deposit types, solvents used to remove them, and construction material incompatibilities in a table. The article summarizes the uses of chemical cleaning solutions, including hydrochloric acid, phosphoric acid, and sulfamic acid, as well as the additives used to neutralize their impact on corrosion. It discusses the chemical cleaning procedures, including selection of cleaning method and solvent, documentation of cleaning, and corrosion monitoring in chemical cleaning.

This article describes the corrosion mechanisms, challenges, and control methods in service water distribution systems. It provides a discussion on typical designs and water qualities for distribution systems used in fossil-fueled and nuclear power plants. The article also explains the techniques for controlling corrosion in service water systems.

Weldments exhibit special microstructural features that need to be recognized and understood in order to predict acceptable corrosion service life of welded structures. This article describes some of the general characteristics associated with the corrosion of weldments. It emphasizes the role of macrocompositional and microcompositional variations to bring out differences that need to be realized in comparing corrosion of weldments to that of wrought materials. The article concludes with a discussion on important welding practices used to minimize corrosion in weldments.

This article provides information on the liquid lithium systems that are exposed to liquid metal. It discusses the forms in which liquid-metal corrosion is manifested. The influence of several key factors on the corrosion of metals and alloys by liquid-metal systems or liquid-vapor metal coolants is described. Some information on safety precautions for handling liquid metals, operating circulating systems, dealing with fire and spillage, and cleaning contaminated components, are also provided.

Electroless nickel plating is used to deposit nickel without the use of an electric current. This article provides an overview of the solution composition and characteristics of the electroless nickel bath. It focuses on the metallurgical, mechanical and physical properties of electroless nickel-phosphorus coatings and electroless nickel-boron coatings. The effect of electroless nickel coatings on the fatigue strength of steel is also described. The article includes information on the recommended pretreatment procedures for different ferrous alloys, aluminum alloys, and copper alloys. It presents a detailed account of the equipment and various processes—including bulk and barrel plating—involved in electroless nickel plating, and discusses hydrogen relief methods. The article includes a comprehensive table on nickel plating applications, and concludes with information on electroless nickel coatings on composites and plastics.

This article briefly describes the basic attributes of chromate conversion coatings and the processes for applying them. It provides information on the influence of substrate microstructure on the performance of coating deposits and on the mechanism of substrate protection supplied by chromate coatings. The article also discusses the development of replacement technologies in response to environmental constraints that have developed around the use of chromium-base compounds.

Vapor-deposition processes fall into two major categories, namely, physical vapor deposition (PVD) and chemical vapor deposition (CVD). This article describes major deposition processes such as sputtering, evaporation, ion plating, and CVD. The list of materials that can be vapor deposited is extensive and covers almost any coating requirement. The article provides a table of some corrosion-resistant vapor deposited materials. It concludes with an overview of the applications of CVD and PVD coatings and a discussion on coatings for graphite, the aluminum coating of steel, and alloy coatings for aircraft turbines, marine turbines, and industrial turbines.

This article focuses on the testing and typical corrosion behavior of coating-substrate systems in aqueous solutions and humid aggressive atmospheres. It includes a short review of the fundamentals of corrosion, followed by a discussion of specific system behavior, electrochemical and laboratory accelerated tests, and simulated service tests. The article also contains examples of different types of corrosion damage and presents guidelines for improving corrosion resistance.

Coatings and other surface modifications are used for a variety of functional, economic, and aesthetic purposes. Two major applications of thermal spray coatings are for wear resistance and corrosion resistance. This article discusses thermal (surface hardening) and thermochemical (carburizing, nitriding, and boriding) surface modifications, electrochemical treatments (electroplating, and anodizing), chemical treatments (electroless plating, phosphating, and hot dip coating), hardfacing, and thermal spray processes. It provides information on chemical and physical vapor deposition techniques such as conventional CVD, laser-assisted CVD, cathodic arc deposition, molecular beam epitaxy, ion plating, and sputtering.

Heat exchangers are devices used to transfer thermal energy between two or more fluids, between a solid surface and a fluid, or between a solid particulate and a fluid at different temperatures. This article first addresses the causes of failures in heat exchangers. It then provides a description of heat-transfer surface area, discussing the design of the tubular heat exchanger. Next, the article discusses the processes involved in the examination of failed parts. Finally, it describes the most important types of corrosion, including uniform, galvanic, pitting, stress, and erosion corrosion.

This article focuses on the mechanisms of microbially induced or influenced corrosion (MIC) of metallic materials as an introduction to the recognition, management, and prevention of microbiological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It discusses the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling and analysis of conditions usually achieved by the installation of removable coupons in the target system. The article also explains the prevention and control strategies of MIC in industrial systems.