Search Results for data reduction

Particle-induced x-ray emission (PIXE) is one of several quantitative analyses based on characteristic x-rays. This article provides a detailed account on the principles of PIXE, discussing the data-reduction codes used to identify, integrate, and reduce x-ray peaks into elemental concentrations. It provides information on the calibration of PIXE analysis, which is mostly performed using gravimetric standards to avoid serious absorption, refluorescence, or ion energy change corrections. A comparative study on PIXE and x-ray fluorescence is also included. Finally, the article discusses the applications of PIXE in three areas, namely, atmospheric physics and chemistry, external proton milliprobes and historical analysis, and PIXE microprobes.

Composites are complex engineered materials that often behave differently than common isotropic materials. Before testing a composite material, or before ordering or supervising such testing, the responsible party should review certain considerations. This article provides an overview of such considerations, namely, the differences between the testing of composites and testing of isotropic materials, role of certification agencies and importance of their involvement, building-block approach to composites testing, determining the purpose of testing, normalizing results, and statistical data reduction.

This article addresses the specialized aspects required to accurately quantify the behavior of soft materials, including polymers and polymeric composites, using the split-Hopkinson pressure bar (SHPB). It details some of the specialized SHPB techniques that facilitate testing soft materials. These techniques include the data-reduction techniques and assumptions required to use polymer pressure bars, the importance of sample-size considerations to polymer testing, and temperature-control methodologies to measure the high-strain-rate uniaxial stress response of polymers and other soft materials.

This article provides a detailed account of extended x-ray absorption fine structure (EXAFS). It begins with a description of the fundamentals of EXAFS, providing information on the physical mechanism, single-scattering approximation, and multiple-scattering effects. This is followed by a discussion on the use of synchrotron radiation as an X-ray source for EXAFS. Data-reduction procedures used to extract EXAFS signals are then described. The article also provides information on the analysis of x-ray absorption near-edge structure spectrum and ends with a discussion on the unique features and applications of EXAFS.

The diffraction pattern of any material contains structural and chemical property information that can be extracted using radial distribution function analysis. This article provides an introduction to the technique and presents several examples highlighting various ways in which it can be used. It begins with a discussion on the principles of diffraction and scattering and the effectiveness of x-ray, neutron, and electron energy sources for different types of measurements. It provides information on data collection and reduction and explains how to create atomic distribution plots from intensity and scattering angle data. The article also presents application parameters for defining short distances and background intensity and describes a procedure for generating pair distribution functions.

Voltammetry is the study of the current voltage relationships observed when electroactive species in solution are subject to oxidation or reduction at electrodes under carefully controlled conditions. This article describes the basic principle of voltammetry performed using the dropping mercury electrode (polarography). It discusses the various methods of voltammetry, namely, linear sweep voltammetry, cyclic voltammetry, and stripping voltammetry that are carried out with different electrode material. The article also explores the modern instrumentation and developments achieved in voltammetry, and provides an outline of additional data, such as values of the formation, or stability, and constants of complexes formed by shifting the half-wave potential, which can be obtained by voltammetry. Additionally, the article provides a brief account of the applications of voltammetry.

Magnesium and magnesium alloys are used in a wide variety of structural and nonstructural applications. This article provides information on selection and application of magnesium and magnesium alloys, mainly, casting alloys and wrought alloys. It also provides tabulated data for the composition, properties of these alloys, including compressive strength, bearing strength, shear strength, hardness, wear resistance, and fatigue strength. The article describes the selection of product forms (castings, extrusions, forgings) for structural applications which is based on mechanical property requirements, cost, availability, and fabricability. It also discusses the types of inserts used in magnesium. The article also deals with the joining of magnesium alloys by welding, adhesive bonding, and riveting. It concludes by describing the formability and machinability of magnesium and magnesium alloys, and explains the role of magnesium in design and weight reduction.

A computational tool would require the contribution of the strengthening mechanisms of metallic material to be predicted and then summed in an appropriate way to derive an estimate of the tensile properties. This article focuses on the modeling of deformation mechanisms pertinent to structural materials, namely, solid-solution strengthening, age/precipitation hardening, dispersion strengthening, grain size reduction, strengthening from cold work, and strengthening from interfaces. It explains the application of predictive models in the atomistic modeling of dislocation structures and cast aluminum property prediction. The article concludes with information on the use of rules-based approaches and data-mining techniques for quantitative predictions of tensile properties.

This article begins with a review of the purposes of mechanical characterization tests and the general considerations related to the mechanical properties of anisotropic systems, specimen fabrication, equipment and fixturing, environmental conditioning, and analysis of test results. It provides information on the specimen preparation, instrumentation, and procedures for various mechanical test methods of fiber-reinforced composites. These include the compression test, flexure test, shear test, open hole tension test, and compression after impact test. The article describes three distinct fracture modes, namely, crack opening mode, shearing mode, and tearing mode. It presents an overview of fatigue testing and fatigue damage mechanisms of composite materials and reviews the types of mechanical measurements that can be made during the course of testing to assess fatigue damage. The article concludes with a discussion on the split-Hopkinson pressure bar test.

Forming processes can be divided into three major categories: bulk forming, sheet-metal forming, and semisolid forming and polymer extrusion. This article introduces each process category with a description of the constitutive models. It outlines the required properties for process modeling and describes the test methods for determining these properties. The article discusses several compression tests used to determine stress-strain curves for bulk forming and tensile tests used to obtain stress-strain curves for sheet-metal forming. The article concludes with information on the measurement of viscosity of semisolid alloy materials by using three types of viscometers: the coaxial cylinder viscometer, the cone-and-plate viscometer, and the capillary viscometer.

Spark source mass spectrometry (SSMS) is an analytical technique used for determining the concentration of elements in a wide range of solid samples, including metals, semiconductors, ceramics, geological and biological materials, and air and water pollution samples. This article discusses the basic principles of spark source technique; SSMS instrumentation such as ion source, electric sector, and magnetic sector; sample preparation; and test procedures of SSMS. Some of the related techniques to SSMS are laser ionization mass spectrometry and laser-induced resonance ionization mass spectrometry. The ions produced in SSMS are detected by either the photometric method or electrical detection method and quantitatively measured by techniques such as internal standardization techniques, isotope dilution, multi element isotope dilution, and dry spike isotope dilution. The detected spark source spectrum contains all the elemental data of the tested sample. Finally, the article exemplifies the applications of SSMS.

Gas analysis by mass spectrometry, or gas mass spectrometry, is a general technique using a family of instrumentation that creates a charged ion from a gas phase chemical species and measures the mass-to-charge ratio. This article covers gas analysis applications that do not use chromatographic separation to physically isolate components of the sample prior to analysis. It is intended to provide an understanding of gas analysis instrumentation and terminology that will help make informed decisions in choosing an instrument and methodology appropriate for the data needed. Mass-analyzer technologies for gas mass spectrometry, namely quadrupole mass filters, magnetic sector mass filters, and time-of-flight mass analyzers are covered. Common factors to consider in choosing an analyzer for static or continuous gas measurement are also described. In addition, the article presents some examples of applications of gas mass spectrometry.

This article describes the techniques involved in measuring the high-strain-rate stress-strain response of materials using a split-Hopkinson pressure bar (SHPB). It focuses on the generalized techniques applicable to all SHPBs, whether compressive, tensile, or torsion. The article discusses the methods of collecting and analyzing compressive high-rate mechanical property data. A review of the critical experimental variables that must be controlled to yield valid and reproducible high-strain-rate stress-strain data is also included. Comparisons and contrasts to the differences invoked when using a tensile Hopkinson bar in terms of loading technique, sample design, and stress-state stability, are discussed.

This article discusses two types of hot-tension tests, namely, the Gleeble test and conventional isothermal hot-tension test, as well as their equipment. It summarizes the data for hot ductility, strength, and hot-tension for commercial alloys. The article presents isothermal hot-tension test data, which helps to gain information on a number of material parameters and material coefficients. It details the effect of test conditions on flow behavior. The article briefly describes the detailed interpretation of data from the isothermal hot-tension test using numerical model. It also explains the cavitation mechanism and failure modes that occur during hot-tension testing.