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cycloaliphatic amines

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Published: 30 September 2015
Fig. 23 Structures of cycloaliphatic amines. (a) Diaminocyclohexane. (b) Isophorone diamine. Source: Ref 1 More
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Published: 01 January 2003
Fig. 15 The structure of cycloaliphatic amines. (a) Diaminocyclohexane. (b) Isophorone diamine More
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006077
EISBN: 978-1-62708-172-6
... epoxy, phosphorus-containing epoxy, fluorinated epoxies, epoxy esters, epoxy phosphate esters, and waterborne epoxy. The principal curatives are amines, amine adducts, cyanoethylated amines, ketimines, polyoxyalkylene amines, cycloaliphatic amines, aromatic amines, polyamides, amido amines...
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Published: 30 September 2015
Fig. 24 Structure of cycloaliphatic amine nocyclohexyl) methane. Source: Ref 1 More
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Published: 01 January 2003
Fig. 16 The structure of cycloaliphatic amine bis-(p-aminocyclohexyl) methane More
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003692
EISBN: 978-1-62708-182-5
... severe immersion service Least flexible of epoxy resins. Costly. Used for high-temperature chemical immersion service Polyamide-cured epoxies Superior to amine-cured epoxies for water resistance. Excellent adhesion, gloss, hardness impact, and abrasion resistance. More flexible and tougher than...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003362
EISBN: 978-1-62708-195-5
... glycidyl amines, and cycloaliphatics. Phenolic Glycidyl Ethers Phenolic glycidyl ethers are formed by the condensation reaction between epichlorohydrin and a phenol group. Within this class, the structure of the phenol-containing molecule and the number of phenol groups per molecule distinguish...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006047
EISBN: 978-1-62708-172-6
...-component polyurea elastomers. These co-chain extenders are either secondary or hindered aliphatic amines. They are typically derivatives of IPDA, hydrogenated methylene dianiline, or other cycloaliphatic diamines ( Ref 11 , 12 , 13 , 14 , 15 ). These provide for extending the dry time of the rapid-dry...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006029
EISBN: 978-1-62708-172-6
.... Using the functional groups available from silane monomers, resin formulators have created organo-functional (e.g., epoxy and amine) silicone resins for epoxy resin modification ( Ref 11 , 12 ). Whereas the use of silicone resin modifiers exploits the stability of the SiO 2 matrix, modification...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006036
EISBN: 978-1-62708-172-6
... on structural variations in the starting diamine. Fig. 2 Michael addition reaction to form a polyaspartic ester The aspartic structural feature of the polyaspartic ester creates a sterically hindered environment around the reactive center ( Fig. 3 ), the secondary amine (-NH-) group. Because...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003489
EISBN: 978-1-62708-195-5
...) chemistries. These are generally mixtures, to various degrees, of modified and unmodified aliphatic amines, polyamides, and modified cycloaliphatic amines. Curing of higher-temperature service two-part systems, which require an elevated-temperature cure, is usually accomplished singularly or with mixtures...
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003367
EISBN: 978-1-62708-195-5
... reaction of a cyanogen halide, such as cyanogen chloride, with alcohol or phenol in the presence of a tertiary amine. The low reaction temperatures are desirable in order to reduce the formation of the undesirable by-product diethylcyanamide, a volatile contaminant. It is also important to fully react...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
... differences in viscosity, cross-linked density, and chemical resistance. Hydrogenated bis A epoxy can be used for improved UV stability. Amines commonly used in flooring include polyamides (and amidoamines), cycloaliphatics, and aliphatics. They differ significantly in functionality (to give different cross...
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006411
EISBN: 978-1-62708-192-4
... and molecular structures of synthetic oil Table 1 Examples and molecular structures of synthetic oil Category Example Molecular structure Esters DBE-4 dibasic ester Cycloaliphatics 3,4-epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Polyglycols Poly(ethylene glycol) bis...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006009
EISBN: 978-1-62708-172-6
... to 520 °F) for the cross-linking reaction between hydroxyl polyesters and amino acid resins (the etherified type in particular), acidic catalysts must be used. P -toluolsulfonic acid or its salts with volatile amines, that is, morpholine or nonionically blocked acidic compounds, is a typical choice...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003010
EISBN: 978-1-62708-200-6
... for efficient conversion of high-purity dicyanates and their prepolymers: Soluble coordinating metal compounds, such as copper naphthenate, zinc octoate, or cobalt acetylacetonate. Active hydrogen source, such as an alkylphenol, bisphenol, alcohol, imidazole, or aromatic amine. Certain hydroxyl...
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006041
EISBN: 978-1-62708-172-6
... are tailored by the R groups. Cycloaliphatic R groups provide increased chemical resistance, while softer, lower- T g linear aliphatic groups provide flexibility. Acid-functional R groups improve pigment wetting. Hydroxyl-functional R groups allow for cross linking of FEVE resins with cross linkers...
Book Chapter

Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003001
EISBN: 978-1-62708-200-6
... coating 1000 811 Tungsten carbide, flame sprayed 1000 811 Mica, glass bonded 700 644 Polyetheretherketone 600 589 Polyimide 600 589 Silicone elastomer 600 589 Silicone plastic, reinforced 600 589 Epoxy, cycloaliphatic, unreinforced 550 561 Polytetrafluoroethylene...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003002
EISBN: 978-1-62708-200-6
... 34–76 5–11 1.4–3.4 0.2–0.5 0.16–0.37 0.3–0.7 230–260 450–500 205–260 400–500 Cycloaliphatic, no filler 1.12–1.18 69–121 10–17.5 3.4–4.8 0.5–0.7 … … 260–290 500–550 250–290 480–550 Melamines Cellulose filled 1.45–1.52 34–62 5–9 7.6 1.1 0.11–0.21 0.2–0.4 130 270...
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003026
EISBN: 978-1-62708-200-6