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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001248
EISBN: 978-1-62708-170-2
... Abstract Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. This article focuses on the composition, advantages, disadvantages, operating parameters, and applications of each of the baths...
Abstract
Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. This article focuses on the composition, advantages, disadvantages, operating parameters, and applications of each of the baths. It provides information on the control of thicknesses of zinc specified for service in various indoor and outdoor atmospheres and on the similarities between cadmium and zinc plating.
Image
Variation in thickness of zinc plate obtained in automatic plating in cyani...
Available to PurchasePublished: 01 January 1994
Fig. 6 Variation in thickness of zinc plate obtained in automatic plating in cyanide zinc bath, 75 tests
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Book Chapter
Electrodeposition Processes
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... for coating iron and steel parts when protection from either atmospheric or indoor corrosion is the primary objective. Plating Baths Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. In the 1970s...
Abstract
Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
... baths are fine-grain and semibright. For pyrophosphate plating on steel, zinc die castings, magnesium, or aluminum, a preliminary strike should be used. For striking, a dilute cyanide or pyrophosphate copper, nickel, or other solution may be used. Acid Plating Baths Electrodeposition of copper...
Abstract
This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... solution clean-up, including removal of excess sodium carbonate, purification with zinc dust, treatment with activated carbon, and filtration. Formation and Elimination of Carbonate Sodium carbonate forms in the cyanide bath as a result of the decomposition of sodium cyanide and the reaction...
Abstract
Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.
Book Chapter
Plating on Aluminum
Available to PurchaseSeries: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006491
EISBN: 978-1-62708-207-5
... salts 60 g per liter, and free sodium cyanide (max) 5.6 g per liter. A current density of 25 mA/cm 2 (24 A/ft 2 ) insures rapid coverage of the zinc film with copper. After 2 min at the initial level, density may be reduced to 13 mA/cm 2 (12 A/ft 2 ) and plating continued for an additional 3 to 5 min...
Abstract
Aluminum components are often plated with other metals to mitigate the effects of corrosion and wear, improve application performance, and extend service life. This article discusses some of the more common aluminum plating processes, including electroplating, immersion plating, and electroless plating, and describes various plating materials and the types of applications in which they are used. It provides critical processing details such as temperatures, ratios, ranges, times, and rates. The article explains how to prepare aluminum components for electroplating, discussing surface roughening, anodizing, and immersion procedures along with expected results.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001255
EISBN: 978-1-62708-170-2
... was cyanide based with a relatively high hydroxide content. Brass Plating Decorative Applications The largest use of brass plating is for decorative applications. Copper-zinc alloys that contain more than 60% Cu have distinct colors, depending on the composition. The 60Cu-40Zn alloys are pale yellow...
Abstract
Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes the decorative and engineering applications of brass and bronze plating. The article also provides information on the treatment of waste water from brass and bronze plating operations.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001388
EISBN: 978-1-62708-173-3
..., such as borax and cryolite, are added to neutral chloride salts to produce a fluxing environment in the bath. When these fluxing agents are used with silver alloy or copper-zinc filler metals, periodic flux additions are required to maintain the fluxing potential of the bath. Above 650 °C (1200 °F), the fluxing...
Abstract
This article describes the dip brazing process and the principal types of furnaces used for molten-salt-bath dip-brazing applications. It provides information on equipment maintenance, which is divided into temperature control, control of the liquid, and maintenance of the vessel. The article presents the typical salts used for molten-salt dip brazing of carbon and low-alloy steels with selected filler metals in tabular form. It concludes with information on dip brazing of stainless steels, cast irons, and aluminum alloys and safety precautions of the process.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001249
EISBN: 978-1-62708-170-2
... overcome by adding gelatin or glue to the bath to increase its viscosity. Plating Baths The four most commonly used indium plating baths are indium cyanide, indium fluoborate, indium sulfamate, and indium sulfate. Table 1 compares these processes. The details of the processes are shown in Tables...
Abstract
This article focuses on the electrodeposition of indium and its alloys, such as indium-antimony, indium-gallium, and indium-bismuth, in nonaqueous indium plating baths. It also provides information on the stripping of indium plate from plated components and presents an overview of the specifications, standards, and hazards of indium plating.
Image
Effects of bath composition variables and cathode current density on cathod...
Available to PurchasePublished: 01 January 1994
Fig. 3 Effects of bath composition variables and cathode current density on cathode efficiency in cyanide zinc plating. (a) Effect of NaCN/Zn ratio. 60 g/L (8 oz/gal) Zn (CN); 17.5 to 43.7 g/L (2.33 to 5.82 oz/gal) NaCN; 75.2 g/L (10 oz/gal) NaOH; 2.0-to-1 to 2.75-to-1 ratios of NaCN to zinc
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001256
EISBN: 978-1-62708-170-2
...-15Zn have been used. Electrolytes are made from a mixture of potassium stannate, zinc cyanide, potassium cyanide, and potassium hydroxide. The amount of potassium cyanide determined by analysis is higher than that added to the bath initially, because the analysis also detects the cyanide in zinc...
Abstract
Electrodeposition of tin alloys is used to protect steel against corrosion or wear, to impart resistance to etching, and to facilitate soldering. This article focuses on the compositions, operating conditions, advantages, and limitations of methane sulfonic acid plating solutions and fluoborate plating solutions for tin-lead. It briefly describes the solution compositions and operating conditions of tin-bismuth, tin-nickel, and tin-zinc.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001257
EISBN: 978-1-62708-170-2
... 70 to 90% Sn and 10 to 30% Zn. Cyanide, acid, and neutral commercial baths are available. Tin-zinc baths are expensive to operate because they require the use of special cast tin-zinc anodes. Tin-zinc alloys exhibit excellent solderability, ductility, and corrosion resistance. Chromate...
Abstract
This article provides information on the compositions of alkaline and acid baths and process parameters for zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc plating.
Book Chapter
Surface Engineering of Aluminum and Aluminum Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
... surface with, or dip a test panel into, an unheated chromate conversion coating bath of the acid type until an orange-colored film is formed. A uniform orange film indicates a chemically clean surface. Solvent Cleaning The primary function of solvent cleaners is to remove oil and grease compounds...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004218
EISBN: 978-1-62708-184-9
... 0.05 0.3 90 5.2×10 −3 Zinc (cyanide) plating bath Zinc 35 0.054 0.35 70 1.1×10 −2 Cyanide (CN) 100 0.054 0.35 70 3.1×10 −2 Zinc (chloride) plating bath Zinc 40 0.043 0.28 95 7.4×10 −3 Zinc (alkaline noncyanide) plating bath Zinc 15 0.023 0.15 75 1.9×10 −3...
Abstract
The high-temperature corrosion processes that are most frequently responsible for the degradation of furnace accessories are oxidation, carburization, decarburization, sulfidation, molten-salt corrosion, and molten-metal corrosion. This article discusses each corrosion process, along with the corrosion behavior of important engineering alloys. It describes the corrosion of plating, anodizing, and parts of pickling equipment such as tanks, wirings and bus bars, racks, anode splines, pumps, and heaters.
Book Chapter
Phosphate Coatings
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001274
EISBN: 978-1-62708-170-2
... because all phosphating baths contain depolarizers or oxidizers that react with the hydrogen as it is formed and render it harmless to the metal. In some instances, however, zinc-phosphate processes, intended for use with rust-inhibiting oils for corrosion resistance or manganese-phosphate treatments, can...
Abstract
This article focuses on the types, composition, and applications of phosphate coatings and describes the characteristics of phosphate-coated ferrous and nonferrous materials, including steel and aluminum. It addresses five successive process fundamentals: cleaning, rinsing, phosphating, rinsing after phosphating, and chromic acid rinsing. The article describes the techniques for controlling the chemical composition of various phosphating solutions. It discusses the equipment and factors that influence equipment requirements in immersion and spray systems. The article also describes the controlling procedures of coating weight and crystal size. It provides guidelines for choosing phosphate coatings based on application, coating weight requirements, and recommended process parameters. The article concludes with a discussion on safety precautions and the treatment of effluents from phosphating plants.
Book Chapter
Cleaning and Coating of Cast Irons
Available to PurchaseSeries: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006335
EISBN: 978-1-62708-179-5
... and reduction of fatigue strength are not dissipated as heat treating temperature approaches stress-relieving temperature. Nonmechanical Cleaning Nonmechanical cleaning methods applicable to cast irons include molten salt bath cleaning, pickling, and chemical cleaning, with the latter method including...
Abstract
Coating of cast irons is done to improve appearance and resistance to degradation due to corrosion, erosion, and wear. This article describes inorganic coating methods commonly applied to cast irons. The coating methods include plating, hot dip coating, conversion coating, diffusion coating, cladding, porcelain enameling, and thermal spray. Organic coatings have a wide variety of properties, but their primary use is for corrosion resistance combined with a pleasing colored appearance. The article discusses the various types of organic coatings applied to cast irons. Practically any degree of smoothness or roughness and requirement for color and gloss can be filled by organic coatings. The article describes abrasive blast cleaning, abrasive waterjet cleaning and finishing, vibratory finishing, barrel finishing, and shot peening for processing iron castings.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006027
EISBN: 978-1-62708-172-6
... the workpiece in a bath or by spraying in a cabinet or tunnel. For painting purposes, crystalline zinc phosphate layers are formed on steel, zinc galvanized steel, and aluminum. The weight of the phosphate coating ranges from 1 to 7 g/m 2 (0.0033 to 0.023 oz/ft 2 ). The phosphate solution consists...
Abstract
This article provides a brief discussion on the common types of overlayers that can be used on a metal surface to protect it from corrosion. These overlayers include phosphate, chromate, and chromate-free conversion coatings; hot dip galvanizing; cementitious linings; glass and porcelain enamels; electroplating; thermal spray coatings; and rubber linings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001303
EISBN: 978-1-62708-170-2
... should be avoided. The corrosion performance of both cadmium and zinc is greatly enhanced by chromate conversion coatings. Most cadmium plating is carried out in alkaline cyanide baths prepared by dissolving cadmium oxide (CdO) in a sodium cyanide (NaCN) solution. Sodium hydroxide (NaOH) and sodium...
Abstract
This article provides a brief review of the classification and characteristics of cast irons. It describes the processes used to clean iron castings, including mechanical cleaning and finishing and nonmechanical cleaning. The article discusses surface treatments used to extend casting life when resistance to corrosion, wear, and erosion is required. The common methods include electroplating, electroless plating, hardfacing, weld cladding, surface hardening, porcelain enameling, and organic coatings.
Book Chapter
Surface Engineering of Copper and Copper Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001309
EISBN: 978-1-62708-170-2
... are used for pipes, valves, and fittings in systems carrying potable water, process water, or other aqueous fluids. The elements most commonly alloyed with copper are aluminum, nickel, silicon, tin, and zinc. Other elements and metals are alloyed in small quantities to improve certain material...
Abstract
The selection of surface treatments for copper and copper alloys is generally based on application requirements for appearance and corrosion resistance. This article describes cleaning, finishing, and coating processes for copper and copper alloys. These processes include pickling and bright dipping, abrasive blast cleaning, chemical and electrochemical cleaning, mass finishing, polishing and buffing, electroless plating, immersion plating, electroplating, passivation, coloring, and organic coatings.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001304
EISBN: 978-1-62708-170-2
..., hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment. alloy steel cadmium plating carbon...
Abstract
This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.
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