The earliest commercial use of carbon fibers is often attributed to Thomas Edison's carbonization of cotton and bamboo fibers for incandescent lamp filaments. This article describes the manufacture of PAN-based carbon fibers and pitch-based carbon fibers. It discusses the properties and characteristics of carbon fibers in terms of axial structure, transverse structure, and interfacial bonding. The article discusses the typical applications of carbon fibers, including aerospace and sporting goods. It concludes with a discussion on anticipated developments in carbon fibers.

The chemical composition of Kevlar aramid fiber is poly para-phenyleneterephthalamide. Para-aramid fibers belong to a class of materials known as liquid crystalline polymers. This article discusses the manufacture of aramid fibers and the major fiber forms, such as continuous filament yarns, rovings, woven fabrics, discontinuous staple and spun yarns, fabrics, and pulp. Key representative properties of para-aramid fibers are listed in a table. The article reviews the properties of aramid fibers, including tensile modulus, tensile strength, creep and fatigue, compressive properties, toughness, thermal properties, as well as electrical and optical properties. It concludes with a discussion on the environmental behavior of para-aramid fibers.

The design and analysis of aerospace and industrial composite components and assemblies requires a detailed knowledge of materials properties, which, in turn, depend on the manufacturing, machining, and assembly methods used. This article, through several tables and graphs, provides the mechanical properties, physical properties, and service characteristics of representative composite fiber-resin combinations, including thermoplastic matrix composites such as thermoplastic polyester resins, thermoplastic polyamide resins, and thermoplastic polysulfone resins, and thermoset matrix composites such as thermoset polyester resins, thermoset phenolic resins, thermoset epoxy resins, thermoset polyimide resins, and thermoset bismaleimide resins.

This article discusses the materials and properties of polymer-matrix composites to characterize each generic material according to its composition and method of manufacture. It contains a table that lists the key physical, mechanical, thermal, and electrical properties, and in-service conditions of concern for resin-matrix composites. Axes definitions, symbols, and special property calculations for composite material property tests are reviewed. The article provides an overview of the performance capabilities of selected polymer-matrix composite materials such as thermoplastic-matrix composites and thermoset-matrix composites. The thermoplastic-matrix composites include thermoplastic polyester resins and fiber resin composites; thermoplastic polyamide resins and fiber-resin composites; and thermoplastic polysulfone resins and fiber-resin composites.

This article describes the types of fabrics and preforms used in the manufacture of advanced composites and related selection, design, manufacturing, and performance considerations. The types of fabrics and preforms include unidirectional and two-directional fabrics; multidirectionally reinforced fabrics; hybrid fabrics; woven fabric prepregs; unidirectional and multidirectional tape prepregs; and the prepreg tow. The article discusses three major categories of tape manufacturing processes, namely, the hand lay-up, machine-cut patterns that are laid up by hand, and the automatic machine lay-up. It provides a description of the two classes of prepregs. These include those that are suitable for high-performance applications and suitable for lower-performance molding compounds.

Polymer materials are key building blocks of the modern world, commonly used in packaging, automobiles, building materials, electronics, telecommunications, and many other industries. These commercial applications of polymeric materials would not be possible without the use of additives. This article is divided into five sections: mechanical property modifiers, physical property modifiers, biological function modifiers, processing aids, and colorants. It describes three classes of additives that are used to inhibit biological activity, six classes of mechanical property modifiers, three classes of physical property modifiers, and two classes of both colorants and processing aids.

This article reviews various phases and constituents found in the microstructures of low-carbon and coated steels. It provides information on the criteria for selecting proper metallographic procedures. Techniques used to prepare metallographic specimens of low-carbon steels and coated steels, such as sectioning, mounting, grinding, polishing, and etching, are discussed. The article also reviews the simple and proven manual sample preparation techniques of coated steel specimens.

This article describes the interaction of composition, manufacturing process, and composite properties of composites. The manufacturing process includes resin-matrix, metal-matrix, and carbon/carbon matrix processing. The article discusses various mechanical properties of composites. It explores how variations in the composition, manufacturing, shop process instructions, and loading/environmental conditions can affect the use of a composite product in a performance/service life operation.

In terms of their electrical properties, plastics can be divided into thermosetting and thermoplastic materials, some of which are conductive or semiconductive. This article provides detailed information on factors that affect the property of plastics. It discusses the major test methods used to determine the following dielectric properties of plastics: dielectric breakdown voltage, dielectric strength, dielectric constant, dissipation factor, arc tracking resistance, insulation resistance, volume, and surface resistivity or conductivity. The test specifications and conditions, recommended by several U.S. and foreign testing organizations for characterizing the electrical properties of plastic materials are listed. The article describes the influence of these properties on selection of plastics for insulation application. An outline of the electromagnetic shielding and testing methods of electromagnetic interference are also provided. Designations, electrical properties, and applications of elastomers are tabulated.

In-process inspection during composite material lay-up is essential if the structural, dimensional, and environmental performance designed into a part is to be consistently achieved. This article discusses the requirements to be met by the facilities and equipment to produce high-quality composites. It reviews the procedures that are allowed and prohibited in controlled-contamination areas of lay-up. The article emphasizes significant areas, such as material control and lay-up process, in which quality-control personnel can be effective in preventing production problems. It concludes with a discussion on automated tape laying and fiber placement, as well as the numerically aided lay-up process.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

Maintainability is a function of the durability, damage tolerance, and repairability of a structure. This article discusses the configurations of composite structures, such as sandwich, stiffened-skin, and monolithic structures, used in commercial aircraft composites. It describes the considerations for maintainability of the composite structures during the conceptual design phase. Sources of the defects and damage, such as manufacturing defects and in-service defects, are reviewed. The article describes the nondestructive inspection methods that are used in the repair of composite structures to locate damage, characterize the extent of damage, and ensure post-repair quality. It lists suggestions that can be used as design guidelines for adhesive bonding, general composite structure, sandwich structure, material selection, and lightning-strike protection. The article also provides the basic considerations for personnel, facilities, and equipment during maintenance.

Macroetching is a procedure for revealing the large-scale structure of a metallic specimen, that is, the structure visible with the unaided eye, by etching an appropriately prepared surface. This article provides information on the basic procedures for macroetching as well as the apparatus used. It discusses selected etchants for efficient macroetching of various metals and their alloys, including iron, steel, high-alloy steels, stainless steels, high-temperature alloys, titanium, titanium alloys, aluminum, aluminum alloys, copper, and copper alloys. The article also describes various conditions that are revealed by the macroetching of aluminum.

This article is a collection of tables that present information on the physical properties of periodic table elements, and maximum service temperatures, dielectric constants and typical dielectric properties of selected nonmetallic materials.

Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.

This article addresses electrical testing and characterization of plastics and presents a number of techniques for evaluating the electrical properties of insulating materials, with a special focus on plastics, accompanied by a list of the electrical properties of different types of plastics. It provides the reader with sufficient information to select the appropriate electrical test(s) for a specific application. The tests covered in this article are widely used in industry to determine the electrical properties of insulating materials, particularly plastics. The article lists and defines terms used in connection with testing and specification of plastics for electrical applications.

This article is a compilation of definitions for terms related to engineering materials, including plastics, elastomers, polymer-matrix composites, adhesives and sealants, ceramics, ceramic-matrix composites, glasses, and carbon-carbon composites.

A material is flammable if it is subject to easy ignition and rapidly flaming combustion. The plastics that are most widely used are the least expensive and tend to be the most flammable. This article describes the two basic approaches to improving the fire resistance of a polymeric material: modifying or substituting the basic polymer so that exposure to heat and oxygen will not produce rapid combustion, and using flame-retardant additives. It also provides an overview of the burning process and presents two flammability test methods.

Tribology is the science and technology of interacting surfaces in relative motion or, the study of friction, wear, and lubrication. This article focuses on friction and wear processes that aid in the evaluation and selection of materials, for polymers and some composites used in friction and wear applications. It provides information on friction, types of wear, and lubrication. The article includes a brief description of the friction and wear test methods, laboratory-scale friction, and wear testing, usually performed either to rank the performance of candidate materials for an application or to investigate a particular wear process. It describes the wear tests conducted with/without abrasives and explains the concept of PV limit (where P is contact pressure and V is velocity). The article concludes with references and tables of friction and wear test data for polymeric materials.