This article discusses factors that influence the effect of alloying, metallurgical treatments, and mechanical treatments on the corrosion resistance of metallic materials, with schematic illustrations.

This article addresses the general effects of the composition, mechanical treatment, surface treatment, and processing on the corrosion resistance of aluminum and aluminum alloys. There are five major alloying elements: copper, manganese, silicon, magnesium, and zinc, which significantly influence the properties of aluminum alloys. There are organic coatings or paints that provide a barrier between a corrosive environment and aluminum surface. Inorganic coatings, including claddings, and enhanced oxides, such as anodized films, Boehmite films, and conversion coatings also help in corrosion prevention. The article assists in the information on selection of fabrication operations, as they play an important role in corrosion resistance.

This article begins with a discussion on the corrosion characteristics of unalloyed magnesium and two major magnesium alloy systems. It shows the effects of iron and 13 other elements on the saltwater corrosion performance of magnesium in binary alloys with increasing levels of the individual elements. The article illustrates the effect of increasing iron, nickel, and copper contamination on the standard ASTM B 117 salt-spray performance of the die-cast AZ91 test specimens as compared to the range of performance observed for cold-rolled steel and die-cast aluminum alloy 380 samples. It discusses the effect of heat treating and cold working on the corrosion rates of the die-cast AZ91 alloy. The article concludes with a description on the causes of corrosion failures in magnesium alloys.

Stainless steels and nickel-base alloys are recognized for their resistance to general corrosion and other categories of corrosion. This article examines the effects of specific alloying elements, metallurgical structure, and mechanical conditioning on corrosion resistance of these materials. It provides information on the compositions of selected stainless steels, copper-nickel, and nickel-base alloys in a tabular form. The article also illustrates the compositional and property linkages for stainless steels and nickel-base alloys.

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

This article discusses corrosion resistance of titanium and titanium alloys to different types of corrosion, including galvanic corrosion, crevice corrosion, stress-corrosion cracking (SCC), erosion-corrosion, cavitation, hot salt corrosion, accelerated crack propagation, and solid and liquid metal embrittlement. A short section discusses the addition of alloys that can improve the corrosion resistance of titanium.

This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

This article reviews various test methods used for evaluating the corrosion resistance of powder metallurgy stainless steels. These include immersion testing, salt spray testing, and electrochemical testing. The article discusses the factors that affect corrosion resistance of sintered stainless steels: compaction-related factors, sintering-related factors, and effects of alloy composition. Corrosion resistance data for sintered stainless steels is provided.

This article provides a background of the complex relationship between titanium and its alloys with aqueous environments, which is dictated by the presence of a passivating oxide film. It describes the corrosion vulnerability of titanium and titanium oxides by the classification of oxide failure mechanisms. The mechanisms are spatially localized oxide film breakdown by the ingress of aggressive anions; spatially local or homogenous chemical dissolution of the oxide in a strong reducing-acid environment; and mechanical disruptions or depassivation such as scratching, abrading, or fretting. Titanium alloys can be classified into three primary groups such as titanium alloys with hexagonal close-packed crystallographic structure; beta titanium alloys with body-centered cubic crystallographic structures; and alpha + beta titanium alloys including near-alpha and near-beta titanium alloys. The article also illustrates the effects of alloying on active anodic corrosion of titanium and repassivation behavior of titanium and titanium-base alloys.

This article discusses the principles of corrosion and the basis of the various prevention measures that can be taken for different corrosion modes. It describes aqueous corrosion phenomena in terms of the electrochemical reactions that occur at the metal-environment interface. The article explains the specific forms of corrosion, including general corrosion, localized attack, and environmentally assisted cracking. It provides a discussion on the engineering aspects of design that can, without due care and attention, precipitate unexpected premature failure. The article reviews ways to improve corrosion awareness and prevent corrosion/degradation. It describes a life prediction method with an example of environmental degradation in light-water nuclear reactors. The article concludes with a discussion on the validation of life-prediction algorithms and their applications.