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corrosion kinetics

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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003583
EISBN: 978-1-62708-182-5
... Abstract This article provides a general introduction to the kinetics of aqueous corrosion with an emphasis on electrochemical principles. It describes the thermodynamic basis for corrosion by determining the equilibrium potentials of electrochemical reactions from the Nernst equation...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003589
EISBN: 978-1-62708-182-5
... rule-of-thumb, is usually correct. The Pilling- Bedworth volume ratios for many common oxides are listed in Table 2 of the article “Thermodynamics of Gaseous Corrosion” in this Volume. Defect Structure of Oxides The basic defect structures of solids were first published by Frenkel (in metals...
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Published: 15 June 2019
Fig. 4 Effect of stress intensity on the kinetics of stress-corrosion cracking. Stages I and II may not always be straight lines but may be strongly curved, and one or the other may be absent in some systems. Stage III is of little interest and is generally absent in K -decreasing tests. More
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003577
EISBN: 978-1-62708-182-5
... by a group of articles discussing the fundamentals of aqueous corrosion kinetics. The fundamentals of gaseous corrosion are addressed next. The fundamental electrochemical reactions of corrosion and their uses are finally described. corrosion aqueous corrosion corrosion kinetics gaseous corrosion...
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Published: 01 January 2003
Fig. 10 Dimensionless empirical model for atmospheric corrosion with precipitation runoff losses showing effect of exposure time on cumulative mass loss and corrosion kinetics More
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003615
EISBN: 978-1-62708-182-5
... Abstract This article provides an introduction on the metal side of the corrosion reaction and describes a wide range of metallurgical factors that influence corrosion. corrosion metallurgical factors THE FUNDAMENTAL UNDERSTANDING of electrochemical corrosion kinetics is based...
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003649
EISBN: 978-1-62708-182-5
... in the absence of precipitation runoff losses: (Eq 4) M T ( t ) = a o t 1 / ( n + 1 ) where a o is a proportionality constant. When n = 0, the corrosion kinetics are linear, and the corrosion film is essentially non-protective; when n = 1, the corrosion kinetics...