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Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003698
EISBN: 978-1-62708-182-5
... Abstract This article discusses the definitions, classifications, structural features, vapor pressure values, corrosion inhibition mechanisms, and methods of evaluation of vapor-phase-corrosion inhibitors or volatile corrosion inhibitors (VCIs). Practical methods of using VCIs for corrosion...
Abstract
This article discusses the definitions, classifications, structural features, vapor pressure values, corrosion inhibition mechanisms, and methods of evaluation of vapor-phase-corrosion inhibitors or volatile corrosion inhibitors (VCIs). Practical methods of using VCIs for corrosion protection of aluminum, ferrous, and nonferrous alloys are discussed with specific examples. The article contains tables that summarize the applications of different VCIs used for protecting ferrous metals, copper and its alloys, and silver.
Book Chapter
Corrosion Inhibitors for Oil and Gas Production
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003699
EISBN: 978-1-62708-182-5
... and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs. corrosion inhibitors oil and gas production organic inhibitors oil wells gas wells water injection systems pipelines pumping wells water floods brine corrosion corrosion rate...
Abstract
The inhibitors currently in use are generally complex mixtures of reaction products and have been formulated to meet the demands of a very competitive industry. This article discusses these demands on inhibitor formulation. The varying characteristics and number of organic inhibitors are explained by the varying characteristics of oil wells and gas wells. Water injection systems and pipelines are also discussed. The article describes the factors that influence the corrosivity of produced fluids and the various treatments applicable for oil, gas, and pumping wells. It examines the primary causes of corrosion inhibition in waterfloods: oxygen contamination and acid gases dissolved in the brine. A discussion on the bacteria-induced corrosion is provided. The article also explains various tests available for field corrosion monitoring. It details the methods used to monitor corrosion rates and inhibitor effectiveness. The article concludes information on the computerization of inhibitor treating programs.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003700
EISBN: 978-1-62708-182-5
... Abstract This article provides useful information on the occurrence of corrosion in crude oil refinery units, namely, crude unit, catalytic and thermal cracking units, hydroprocessing units, amine sweetening units, and sour water units. Types and applications of corrosion inhibitors, namely...
Abstract
This article provides useful information on the occurrence of corrosion in crude oil refinery units, namely, crude unit, catalytic and thermal cracking units, hydroprocessing units, amine sweetening units, and sour water units. Types and applications of corrosion inhibitors, namely, neutralizers, filming inhibitors, scavengers, microbiocides, and anti-foulants and scale inhibitors, are reviewed. The article describes the direct and indirect corrosion monitoring methods used to reduce equipment damage due to corrosion events and to assess the reliability and useful service life of process equipment.
Book Chapter
Corrosion Inhibitors in the Water Treatment Industry
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003701
EISBN: 978-1-62708-182-5
... processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal...
Abstract
The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.
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Published: 31 December 2017
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Published: 31 August 2017
Fig. 32 Effect of various environments and corrosion inhibitors listed in Table 15 on the corrosion fatigue properties of gray iron. Courtesy of American Foundry Society. Source: Ref 3 , 52
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Increase in corrosion rate for steel treated with a corrosion inhibitor in ...
Available to PurchasePublished: 15 January 2021
Fig. 8 Increase in corrosion rate for steel treated with a corrosion inhibitor in carbon-dioxide-saturated 3% saline solution with addition of acetate. Source: Ref 52 . Reprinted with permission from NACE International
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Effect of various inhibitors on the corrosion rate of carbon steel in aerat...
Available to PurchasePublished: 01 January 2003
Fig. 5 Effect of various inhibitors on the corrosion rate of carbon steel in aerated water at 25 °C (77 °F). (a) HPO 4 2− ions. (b) SiO 3 2− ions. (c) CrO 4 2− ions. Line generated from electrochemical model and test data (squares) are given.
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Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006405
EISBN: 978-1-62708-192-4
.... The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also...
Abstract
This article focuses on lubricants classified as either internal combustion engine or nonengine lubricants, and the lubricant additives. The functional groups of chemically active and inert additives, as well as friction modifiers and other additives, are described in detail. The chemically active additives include dispersants, detergents, antiwear, and extreme-pressure agents, oxidation inhibitors, and rust and corrosion inhibitors. The chemically inert additives include emulsifiers, demulsifiers, pour-point depressants, foam inhibitors, and viscosity improvers. The article also discusses the multifunctional nature of additives and concludes with information on lubricant formulation.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006411
EISBN: 978-1-62708-192-4
.... It reviews the functions of additives, such as friction modifiers, antiwear additives, viscosity modifiers, corrosion inhibitors, oxidation inhibitors, dispersants, and detergents. The article discusses the physical properties of liquid lubricants and the performance characteristics of lubricants...
Abstract
The function of lubricants is to control friction and wear in a lubricating system containing machine elements such as gears and bearings. This article discusses the basic properties of lubricants to help scientists and engineers understand the principles behind lubricant selection. It reviews the functions of additives, such as friction modifiers, antiwear additives, viscosity modifiers, corrosion inhibitors, oxidation inhibitors, dispersants, and detergents. The article discusses the physical properties of liquid lubricants and the performance characteristics of lubricants. It describes the most common lubricant categories and provides information on the health and safety aspects of using liquid lubricants. The article concludes with a discussion on the lubricant-application method that plays a vital role in how the lubricant functions.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003556
EISBN: 978-1-62708-180-1
... the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling...
Abstract
This article focuses on the mechanisms of microbially induced or influenced corrosion (MIC) of metallic materials as an introduction to the recognition, management, and prevention of microbiological corrosion failures in piping, tanks, heat exchangers, and cooling towers. It discusses the degradation of various protective systems, such as corrosion inhibitors and lubricants. The article describes the failure analysis of steel, iron, copper, aluminum, and their alloys. It also discusses the probes available to monitor conditions relevant to MIC in industrial systems and the sampling and analysis of conditions usually achieved by the installation of removable coupons in the target system. The article also explains the prevention and control strategies of MIC in industrial systems.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003672
EISBN: 978-1-62708-182-5
... Abstract This article discusses the factors affecting corrosion behavior. It describes galvanic corrosion and its protection methods. The article also provides information on coatings and inhibitors, which are used in corrosion protection. corrosion galvanic corrosion coatings...
Abstract
This article discusses the factors affecting corrosion behavior. It describes galvanic corrosion and its protection methods. The article also provides information on coatings and inhibitors, which are used in corrosion protection.
Book Chapter
Corrosion in Service Water Distribution Systems
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004102
EISBN: 978-1-62708-184-9
... for controlling corrosion in service water systems consist of the addition of corrosion inhibitors to control general corrosion and the addition of biocides to control microbiological growth and prevent MIC. Some power plants utilize corrosion inhibitors. The decision to use corrosion inhibitors is based...
Abstract
This article describes the corrosion mechanisms, challenges, and control methods in service water distribution systems. It provides a discussion on typical designs and water qualities for distribution systems used in fossil-fueled and nuclear power plants. The article also explains the techniques for controlling corrosion in service water systems.
Book Chapter
Chemical Cleaning and Cleaning-Related Corrosion of Process Equipment
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004143
EISBN: 978-1-62708-184-9
... alkali is used) (a) All acids and chelants should be used with corrosion inhibitor additives. (b) Soft metals are low strength metals with low corrosion resistance, such as zinc (galvanizing), aluminum, and magnesium. For decades, common practice among industrial cleaning contractors...
Abstract
This article describes the eight chemical cleaning methods, namely, circulation, fill and soak, cascade, foam, vapor-phase organic, steam-injected, on-line chemical, and mechanical cleaning. It presents information on deposit types, solvents used to remove them, and construction material incompatibilities in a table. The article summarizes the uses of chemical cleaning solutions, including hydrochloric acid, phosphoric acid, and sulfamic acid, as well as the additives used to neutralize their impact on corrosion. It discusses the chemical cleaning procedures, including selection of cleaning method and solvent, documentation of cleaning, and corrosion monitoring in chemical cleaning.
Book Chapter
Engine Coolants and Coolant System Corrosion
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004164
EISBN: 978-1-62708-184-9
... components and inhibitors used for corrosion prevention. It reviews the coolant performance tests recommended by ASTM, SAE, and vehicle manufacturers. The article concludes with a description on the difference between light-duty automotive and heavy-duty diesel engine coolants. cavitation corrosion...
Abstract
Advances in vehicle design and technology require engine coolant technology to minimize the degradation of nonmetals and prevent the corrosion of the metals in the cooling system. This article provides a detailed discussion on the functions, operation, materials, and major components of the cooling system. It discusses various forms of corrosion that occur in cooling systems, including uniform corrosion, galvanic corrosion, crevice corrosion, pitting corrosion, intergranular corrosion, erosion corrosion, and cavitation corrosion. The article presents information on engine coolant base components and inhibitors used for corrosion prevention. It reviews the coolant performance tests recommended by ASTM, SAE, and vehicle manufacturers. The article concludes with a description on the difference between light-duty automotive and heavy-duty diesel engine coolants.
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Initial corrosion rates for steel exposed to carbonated 3% NaCl solution wi...
Available to PurchasePublished: 01 January 2002
Fig. 6 Initial corrosion rates for steel exposed to carbonated 3% NaCl solution with 0, 100, and 1000 ppm acetate of 4, 9, and 18 mm/year (0.2, 0.4, and 0.7 in./year), respectively. This order is sustained after addition of 25 ppm of a corrosion inhibitor, despite a significant reduction
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004210
EISBN: 978-1-62708-184-9
... proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration...
Abstract
This article discusses the particular corrosion problems encountered and the corrosion control methods used in petroleum production (i.e., upstream) and the storage and transportation of oil and gas (i.e., midstream) up to the refinery (i.e., downstream). These control methods include proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration and production. It discusses corrosion problems that are specific to the various types of environments or equipment used in secondary recovery, including producing wells, producing flow lines, and injection wells. Corrosion mitigation methods and guidelines are also discussed for each type of environment.
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Slow potentiodynamic scans of aluminum 6061-T6 in 3.5% NaCl with and withou...
Available to PurchasePublished: 01 January 2003
Fig. 2 Slow potentiodynamic scans of aluminum 6061-T6 in 3.5% NaCl with and without volatile corrosion inhibitor F. Source: Ref 39 .
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Book Chapter
Applications of Modern Analytical Instruments in Corrosion
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003710
EISBN: 978-1-62708-182-5
... and identifying the nature of protective corrosion inhibitor films. The focus of this review is to explain the principles of various surface-sensitive techniques and the usefulness and limitations of these techniques ( Ref 2 , 3 , 4 , 5 ). To gain additional insight into the use of various surface-sensitive...
Abstract
This article describes the analytical methods for analyzing surfaces for corrosion and corrosion inhibition processes as well as failure analysis based on surface structure and chemical identity and composition. The principles and applications of the surface-structure analysis techniques, namely, optical microscopy, scanning electron microscopy, scanning tunneling microscopy, and atomic force microscopy, are reviewed. The article discusses the principles and applications of chemical identity and composition analysis techniques. These techniques include the energy dispersive X-ray spectroscopy, Auger electron spectroscopy, X-ray photoelectron spectroscopy, ion scattering spectroscopy, reflectance Fourier transform infrared absorption spectroscopy, Raman and surface enhanced Raman spectroscopy, and extended X-ray absorption fine structure analysis.
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Fourier transform infrared spectra of unknown white solids in a tank under ...
Available to PurchasePublished: 15 January 2021
for the match (DB, sublibrary; FX, food additives), and the spectrum identification number (ID) in the database. During the investigation, it was determined that the contamination was likely due to either a cleaning solution or corrosion inhibitor. Courtesy of P. Howard, NASA
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