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Image
Schematic diagram of a generic corrosion cell showing anodic oxidation of t...
Available to PurchasePublished: 01 January 2002
Fig. 2 Schematic diagram of a generic corrosion cell showing anodic oxidation of the metal ( M ) complemented by cathodic reduction of an electron acceptor ( X ). The corrosion rate can be controlled by the rate of arrival of X at the cathodic surface, a buildup of metal ions, M
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Image
Schematic diagram of the cathodic surface of an anaerobic corrosion cell in...
Available to PurchasePublished: 01 January 2002
Fig. 3 Schematic diagram of the cathodic surface of an anaerobic corrosion cell in which H + is reduced to H on metal surface. The atomic hydrogen formed escapes the cathodic surface by combining to form molecular hydrogen, 2H → H 2 , that desorbs from the surface or by entry as atomic
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Schematic diagram of the mechanism in an FeS corrosion cell created by the ...
Available to PurchasePublished: 01 January 2002
Fig. 4 Schematic diagram of the mechanism in an FeS corrosion cell created by the action of SRB. Iron sulfide sets up a galvanic couple with steel, sustained and extended by the further action of SRB. The bacteria use electrons from the corrosion process, possibly in the form of cathodic
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Image
Potential versus log current plot for corrosion cell with copper and silver...
Available to Purchase
in Introduction to Corrosion for Constructive Purposes
> Corrosion: Fundamentals, Testing, and Protection
Published: 01 January 2003
Image
Diagrams of the filiform-corrosion cell in steel (a), aluminum (b), and mag...
Available to PurchasePublished: 01 January 2003
Fig. 6 Diagrams of the filiform-corrosion cell in steel (a), aluminum (b), and magnesium (c). Corrosion products and predominant reactions are labeled. Filiform corrosion is a differential-aeration cell driven by differences in oxygen concentration in the head versus the tail section
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Differential corrosion cell created by differences in soils. Arrows indicat...
Available to PurchasePublished: 01 January 2006
Fig. 2 Differential corrosion cell created by differences in soils. Arrows indicate the direction of ionic and electronic current flow.
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Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004136
EISBN: 978-1-62708-184-9
... (MCFCs), and solid oxide fuel cells (SOFCs). The article explains the corrosion processes in fuel cells due to solid-gas interactions, solid-liquid interactions, and solid-solid interactions. It discusses the long-term performance stability and long-term degradation processes of PEMFCs, MCFCs, and SOFCs...
Abstract
This article describes the classification of fuel cells depending on the operating temperature and type of electrolytes used. This classification includes alkaline fuel cells, phosphoric acid fuel cells, polymer electrolyte membrane fuel cells (PEMFCs), molten carbonate fuel cells (MCFCs), and solid oxide fuel cells (SOFCs). The article explains the corrosion processes in fuel cells due to solid-gas interactions, solid-liquid interactions, and solid-solid interactions. It discusses the long-term performance stability and long-term degradation processes of PEMFCs, MCFCs, and SOFCs. The article reviews the development of chemically and structurally compatible component materials in PEMFCs, MCFCs, and SOFCs.
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Typical corrosion fatigue test cell. Maintenance of the equilibrium oxygen ...
Available to PurchasePublished: 01 January 1996
Fig. 22 Typical corrosion fatigue test cell. Maintenance of the equilibrium oxygen concentration is ensured by cascading the solution in the circulation rig.
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Published: 01 August 2013
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Published: 01 January 1994
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Schematic presentation of corrosion metal cell formed by anodic (A) and cat...
Available to PurchasePublished: 01 January 2003
Fig. 1 Schematic presentation of corrosion metal cell formed by anodic (A) and cathodic (C) sites. The A sites (M e 2 ) have a more negative potential ( E ) relative to that of the C sites (M e 1 ).
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Schematic presentation of the corrosion galvanic cell created in a zinc-cop...
Available to PurchasePublished: 01 January 2003
Fig. 2 Schematic presentation of the corrosion galvanic cell created in a zinc-copper alloy in an acid environment. The cathode is the copper-rich phase and the anode is the zinc-rich phase. The corrosion attack is selective to the zinc-rich phase.
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Differential flow cell sensor for localized corrosion. Valve adjusts relati...
Available to PurchasePublished: 01 January 2003
Fig. 1 Differential flow cell sensor for localized corrosion. Valve adjusts relative flow rates. Anode 0 and anode 1 are redundant, and zero resistance ammeter (ZRA) can be switched to either anode. Adapted from Ref 24 , with permission from the National Association of Corrosion Engineers
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Typical corrosion fatigue test cell. Maintenance of the equilibrium oxygen ...
Available to PurchasePublished: 01 January 2000
Fig. 24 Typical corrosion fatigue test cell. Maintenance of the equilibrium oxygen concentration is ensured by cascading the solution in the circulation rig.
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Soil test cell with three corrosion electrodes and four resistivity electro...
Available to PurchasePublished: 01 January 2006
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Published: 01 January 2006
Book Chapter
Introduction to Corrosion for Constructive Purposes
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003604
EISBN: 978-1-62708-182-5
... the electrode reactions are displaced from equilibrium and the electrode potential is no longer at the equilibrium potential. The article describes irreversible cell potential by using galvanic cells, electrolytic cells, and corrosion cells. metallic corrosion kinetics equilibrium electrode potential...
Abstract
Principles of metallic corrosion play a fundamental role in developing industrial processes that employ corrosion for constructive purposes. This article examines the changes in kinetics that occur with differentially small potential changes around the equilibrium electrode potentials of two reversible electrodes, such as copper and silver electrodes, in an electrochemical system. It provides a schematic illustration of a reversible cell with copper and silver electrodes to determine a reversible cell potential between the electrodes. An electrode becomes irreversible when the electrode reactions are displaced from equilibrium and the electrode potential is no longer at the equilibrium potential. The article describes irreversible cell potential by using galvanic cells, electrolytic cells, and corrosion cells.
Book Chapter
External Corrosion of Oil and Natural Gas Pipelines
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004213
EISBN: 978-1-62708-184-9
... Abstract This article describes the mechanisms of differential corrosion cells corrosion, microbiologically influenced corrosion, and stray direct current corrosion. It discusses the most common causes and contributing factors for corrosion and stress-corrosion cracking, as well as prevention...
Abstract
This article describes the mechanisms of differential corrosion cells corrosion, microbiologically influenced corrosion, and stray direct current corrosion. It discusses the most common causes and contributing factors for corrosion and stress-corrosion cracking, as well as prevention, mitigation, detection, and repair processes.
Image
Molecular hydrogen, H 2 , released from the cathodic surface in an anaerobi...
Available to PurchasePublished: 15 January 2021
Fig. 2 Molecular hydrogen, H 2 , released from the cathodic surface in an anaerobic corrosion cell can support the growth and activity of sulfate-reducing bacteria (SRB) away from the metal surface. Use of molecular hydrogen was traditionally accepted as the mechanism for microbiologically
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Published: 01 January 2003
Fig. 5 Close-up of the advancing head shown in Fig. 4(a) . Minute cracks can be seen at the head-tail interface of a filiform-corrosion cell. These cracks are entry points for water and air to provide a source of hydroxyl ions and an electrolyte. Intermediate corrosion products are just
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