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copper-phosphorus alloys
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001389
EISBN: 978-1-62708-173-3
... that contribute to high quality in an RB joint. The article discusses the classification of RB such as manual RB or automatic RB. It describes the selection of metal electrodes and filler metals for RB. The filler metals include silver alloys, aluminum-silicon alloys, and copper-phosphorus alloys. aluminum...
Abstract
This article presents an overview of resistance brazing (RB) used for many applications involving small workpieces, for small joints that are part of very large equipment, or for low-volume production runs. It lists the advantages and limitations of RB and outlines the factors that contribute to high quality in an RB joint. The article discusses the classification of RB such as manual RB or automatic RB. It describes the selection of metal electrodes and filler metals for RB. The filler metals include silver alloys, aluminum-silicon alloys, and copper-phosphorus alloys.
Image
Published: 01 December 2004
Fig. 13 Alloy C12200 (deoxidized high-phosphorus copper), continuously cast in a 102 mm (4 in.) diameter ingot. Top, transverse section showing radial grain growth. Bottom, longitudinal section. Dark center is columnar grains oriented along the axis of the ingot. Waterbury reagent was used
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Published: 01 December 2004
Fig. 14 The same C12200 (deoxidized high-phosphorus copper) continuously cast alloy in a 102 mm (4 in.) diameter ingot as in Figure 13 Section taken near the ingot surface normal to the radial grain growth. The structure is coarse, unbranched dendrites. Waterbury reagent was used, which has
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Image
Published: 01 December 2004
Fig. 15 The same C12200 (deoxidized high-phosphorus copper) continuously cast alloy in a 102 mm (4 in.) diameter ingot as in Fig. 14 Section taken near the ingot core normal to the radial grain growth. The dendrite structure is much finer than in Fig. 14 . Waterbury reagent was used, which
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005247
EISBN: 978-1-62708-187-0
... fell out of favor because the fumes associated with breakdown of salts or vaporizing of PCl 5 were unpleasant if not unhealthy. Another additive researched and reported in the 1960s ( Ref 2 ) and continuing in use even today (2008) is the alloy of phosphorus and copper. Commonly called phos-copper...
Abstract
Primary silicon in hypereutectic aluminum-silicon alloys is very hard, not only imparting improved wear resistance but also decreasing tool life during machining. This article discusses the importance of primary silicon refinement and the process of accomplishing primary silicon refinement.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006191
EISBN: 978-1-62708-163-4
....” “Cu-P (Copper - Phosphorus)” in the article “Cu (Copper) Binary Alloy Phase Diagrams.” “Fe-P (Iron - Phosphorus)” in the article “Fe (Iron) Binary Alloy Phase Diagrams.” “Ge-P (Germanium - Phosphorus)” in the article “Ge (Germanium) Binary Alloy Phase Diagrams.” “In-P (Indium...
Abstract
This article is a compilation of binary alloy phase diagrams for which phosphorus (P) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.
Book Chapter
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006278
EISBN: 978-1-62708-169-6
... among the cast copper alloys, but it is essentially identical to phosphorus-deoxidized copper (C81200) in other respects. Both oxygen-free and deoxidized coppers are readily weldable. Typical mechanical properties are similar for the different grades: UNS designation As-cast mechanical properties...
Abstract
Cast and wrought coppers can be strengthened by cold working. This article provides information on minor alloying elements, such as beryllium, silicon, nickel, tin, zinc, and chromium, used to strengthen copper. It details annealing and recrystallization and grain growth characteristics of copper. The article also discusses the tensile-stress-relaxation behavior of selected types of copper wires.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003772
EISBN: 978-1-62708-177-1
... BCuP-5 brazing alloy 80 Cu, 15 Ag, 5 P Coppers The alloys designated as coppers contain 99.3% or more copper. These have the highest electrical and thermal conductivity. Impurities such as phosphorus, tin, selenium, tellurium, and arsenic are detrimental to properties such as electrical...
Abstract
This article describes the microstructure of copper alloys, including copper-zinc (brasses), bronzes, copper-nickel, and copper-nickel-zinc, and examines the effect of oxygen content on alloy phases observed in different product forms. The article also discusses inclusions, etchants, and the effect of composition and processing on grain structure and growth rates.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001454
EISBN: 978-1-62708-173-3
... filler metal can be used without flux, although flux is sometimes recommended. The brazing characteristics of most copper filler metals and alloys are improved when a flux is used. In this case, phosphorus-deoxidized and oxygen-free coppers can be joined with a brazing filler metal from the silver...
Abstract
Copper, copper alloys, and precious metals are probably the most easily brazed metals because of their resistance to oxidation at high temperatures. This article provides a brief discussion on the metallurgy of copper, copper alloys, and precious metals and discusses the filler metals, brazing fluxes, joint clearance and design, and different brazing processes used in brazing of copper, copper alloys, and precious metals.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005332
EISBN: 978-1-62708-187-0
..., nickel, beryllium, chromium, and iron. The article discusses minor alloying additions, including antimony, bismuth, selenium, manganese, and phosphorus. Copper alloys can be cast by many processes, including sand casting, permanent mold casting, precision casting, high-pressure die casting, and low...
Abstract
The properties of copper alloys occur in unique combinations found in no other alloy system. This article focuses on the major and minor alloying additions and their impact on the properties of copper. It describes major alloying additions, such as zinc, tin, lead, aluminum, silicon, nickel, beryllium, chromium, and iron. The article discusses minor alloying additions, including antimony, bismuth, selenium, manganese, and phosphorus. Copper alloys can be cast by many processes, including sand casting, permanent mold casting, precision casting, high-pressure die casting, and low-pressure die casting. The article provides information on the types of copper castings and tabulates the nominal chemical composition and mechanical properties of several cast alloys.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001267
EISBN: 978-1-62708-170-2
... of the reducing agent. Examples of this type of ternary system are alloys of nickel-copper-phosphorus or nickel-thallium-boron. Nonelectrolytic processes generally operate at slightly elevated temperatures up to the temperature of boiling. These processing solutions contain the primary element and may contain...
Abstract
Metallic nonelectrolytic alloy coatings produced from aqueous solutions are commercially used in several industries, including electronics, aerospace, medical, oil and gas production, chemical processing, and automotive. Nonelectrolytic coating systems use two types of reactions to deposit metal onto a part: electroless and displacement. This article explains the various types of electroless and dispersion alloy coating systems. It provides information on the processing of parts, process control, deposit analysis, and equipment used for coating nonelectrolytic displacement alloys. The article concludes with a discussion on the safety and environmental concerns associated with nonelectrolytic deposition processes.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001450
EISBN: 978-1-62708-173-3
...- and nickel-base alloys) and phosphorus (in the case of copper- and nickel-base alloys) are added. The presence of one or more of these elements in the alloys tends to impart lower melting temperatures and surface tensions to the filler metal, as well as compatibility with the base material in terms...
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003831
EISBN: 978-1-62708-183-2
... alloys have been made on joints involving stainless steel. Copper filler alloys containing significant amounts of zinc (such as naval brass welding and brazing rod, RBCuZn, similar to UNS C4700) or phosphorus (such as copper-phosphorus brazing filler metal, BCuP, similar to UNS C55180...
Abstract
Corrosion is often thought of as rusting, the process of deterioration undergone by a metal when it is exposed to air or water. This article provides the fundamentals of joints corrosion and primarily addresses the various forms of corrosion observed in brazed and soldered joints and their causes. It describes the role of proper brazing procedures in controlling corrosion. The article concludes with information on the corrosion resistance of various brazing alloy systems.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006281
EISBN: 978-1-62708-169-6
... Abstract Bronzes generally are used to describe many different copper-base alloys in which the major alloying addition is neither zinc nor nickel. They are generally classified by their major alloying elements, for example, tin bronzes with phosphorus used as a deoxidizer, aluminum bronzes...
Abstract
Bronzes generally are used to describe many different copper-base alloys in which the major alloying addition is neither zinc nor nickel. They are generally classified by their major alloying elements, for example, tin bronzes with phosphorus used as a deoxidizer, aluminum bronzes, nickel-aluminum bronzes, silicon bronzes, and beryllium bronzes. This article briefly discusses the types, hardening mechanisms, heat treatment processes, applications, and mechanical properties of these bronzes and high-copper alloys.
Book Chapter
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005303
EISBN: 978-1-62708-187-0
... Fire refining (oxidation) can be used to remove impurities from copper-base melts in approximately the following order: aluminum, manganese, silicon, phosphorus, iron, zinc, tin, and lead. Nickel, a deliberate alloying element in certain alloys but an impurity in others, is not readily removed by fire...
Abstract
This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It discusses the production of copper alloy castings. The article concludes with information on the gating and feeding systems used in production of copper alloy castings.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0007030
EISBN: 978-1-62708-387-4
... joint formation. In the soldering process, the metal on the soldering pad surface (i.e., copper, nickel, or silver) will react with the solder alloy and generate the IMC layer in the interface between the soldering pad and bulk solder. That said, the IMC layer is the intermedia to bond the solder alloy...
Abstract
Solder cracking is one of the dominant failure modes of the electronic assembly system. Experience shows that solder joints can fail due to processing defects during solder joint formation or due to excessive loading in various applications. This article introduces major fractography techniques to demonstrate typical solder joint failure and background failure mechanisms. These techniques may be helpful to readers in recognizing failure modes and in preventing further failures during product development and process implementation.
Image
in Systematic Analysis of Induction Coil Failures and Prevention
> Induction Heating and Heat Treatment
Published: 09 June 2014
Fig. 15 Effect of the presence of low concentrations of alloying elements on time-to-fracture of copper by stress-corrosion cracking under an applied tensile stress of 70 MPa (10 ksi) in a moist atmosphere. UNS C12200 is a wrought phosphorus deoxidized copper. Source: Ref 14
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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003136
EISBN: 978-1-62708-199-3
...-phosphorus), alloy C19400 (copper-iron-phosphorus-zinc), and alloy C19500 (copper-iron-cobalt-tin-phosphorus) are popular for these applications because they have good conductivity, good strength, and good softening resistance. Figures 2 and 3 compare the softening resistance of these alloys...
Abstract
Copper and copper alloys are used extensively in structural applications in which they are subject to moderately elevated temperatures. At relatively low operating temperatures, these alloys can undergo thermal softening or stress relaxation, which can lead to service failures. This article is a collection of curves and tables that present data on thermal softening and stress-relaxation in copper and copper alloys. Thermal softening occurs over extended periods at temperatures lower than those inducing recrystallization in commercial heat treatments. Stress relaxation occurs because of the transformation of elastic strain in the material to plastic, or permanent strain.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006388
EISBN: 978-1-62708-192-4
... Abstract This article begins by describing the designations of cast and wrought aluminum alloys. It explains the effects of main alloying elements in aluminum alloys: boron, chromium, copper, iron, lithium, magnesium, manganese, nickel, phosphorus, silicon, sodium, strontium, titanium, and zinc...
Abstract
This article begins by describing the designations of cast and wrought aluminum alloys. It explains the effects of main alloying elements in aluminum alloys: boron, chromium, copper, iron, lithium, magnesium, manganese, nickel, phosphorus, silicon, sodium, strontium, titanium, and zinc. The article describes the microstructure of cast and wrought aluminum alloys and the various strengthening mechanisms, including solid solution, grain refinement, strain or work hardening, precipitation (or age) hardening, and dispersoid strengthening. The article explicates the tribological behavior of aluminum alloys, aluminum-base composites, and metal-matrix composites. It presents the effect of material-related parameters and external factors on wear behavior and transitions of aluminum-silicon alloys. The article also presents the most important factors affecting the dry sliding wear behavior of particle-reinforced aluminum-base composites against a steel counterface.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001385
EISBN: 978-1-62708-173-3
..., and various heat-resistant materials. Most combinations of these materials can also be torch brazed. It is necessary to use flux with these materials, except when a phosphorus brazing alloy is used to braze pure copper parts. In this case, the phosphorus acts as the flux. The low-temperature silver-base...
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