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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001255
EISBN: 978-1-62708-170-2
... Abstract Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes...
Abstract
Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes the decorative and engineering applications of brass and bronze plating. The article also provides information on the treatment of waste water from brass and bronze plating operations.
Image
Preparing magnesium alloys for copper plating. See text for details of solu...
Available to PurchasePublished: 01 January 1994
Fig. 12 Preparing magnesium alloys for copper plating. See text for details of solution composition and other operating conditions. Operation Cycle time, min Solution temperature Tank material °C °F Alkaline cleaning (a) 3–10 87–100 190–212 Low-carbon steel Acid
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Book Chapter
Procedure Development and Practice Considerations for Ultrasonic Welding
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001448
EISBN: 978-1-62708-173-3
... to join copper and aluminum alloys, this technique promotes the advantages of using aluminum as a backing plate and the solderability of copper for attaching circuitry. [For example, copper slugs are ultrasonically welded to an aluminum backing plate for automotive-engine ignition modules and for antilock...
Abstract
Ultrasonic welding (USW) is effectively used to join both similar and dissimilar metals with lap-joint welds. This article describes procedure considerations for the ultrasonic welding of specific material types. It reviews difficult-to-weld alloys, such as carbon and low-alloy steels, high-strength steels, and stainless steel, and provides information on the applications of weldable alloys such as aluminum alloys and copper alloys. The article concludes with a discussion on welding of dissimilar metal (nonferrous-to-nonferrous) combinations and its applications.
Book Chapter
Surface Engineering of Copper and Copper Alloys
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001309
EISBN: 978-1-62708-170-2
... coating coloring copper copper alloys corrosion resistance electrochemical cleaning electroless plating electroplating finishing immersion plating mass finishing organic coatings passivation pickling polishing surface treatment COPPER and copper alloys constitute one of the major...
Abstract
The selection of surface treatments for copper and copper alloys is generally based on application requirements for appearance and corrosion resistance. This article describes cleaning, finishing, and coating processes for copper and copper alloys. These processes include pickling and bright dipping, abrasive blast cleaning, chemical and electrochemical cleaning, mass finishing, polishing and buffing, electroless plating, immersion plating, electroplating, passivation, coloring, and organic coatings.
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003687
EISBN: 978-1-62708-182-5
... of Coatings The principal metals that are widely plated are cadmium, zinc and its alloys, chromium, copper, gold, nickel, tin, and silver. Other metals that are plated by in-house shops and some job platers are cobalt, indium, iron, lead, palladium, platinum, rhenium, and rhodium. Plateable alloys add...
Abstract
This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001260
EISBN: 978-1-62708-170-2
... for plating Ni/Cu multiple-layer alloys, where copper is more noble than nickel by nearly 600 mV. For the case of Ni/Cu alloy plating, one often starts with a nickel-sulfate-based electrolyte (Watts nickel bath) or a nickel sulfamate bath. Small amounts of copper sulfate (50 to 1000 ppm Cu +2 ) are then added...
Abstract
Multiple-layer alloy electrodeposition involves the formation of an inhomogeneous alloy consisting of lamellae of different composition. This article reviews the process description, engineering parameters, characterization, and applications of multiple-layer alloys. Pulsed-current plating and pulsed-potential plating are also discussed.
Book Chapter
Plating on Aluminum
Available to PurchaseSeries: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006491
EISBN: 978-1-62708-207-5
... 1.300 29 85 22 5 5052 1.300 29 85 22 10 6061 1.300 29 85 22 7 (a) With special care, phosphoric acid anodizing may be used also for aluminum-copper or aluminum-silicon alloys. Source: Ref 10 Because strongly alkaline plating solutions may dissolve the anodic coating...
Abstract
Aluminum components are often plated with other metals to mitigate the effects of corrosion and wear, improve application performance, and extend service life. This article discusses some of the more common aluminum plating processes, including electroplating, immersion plating, and electroless plating, and describes various plating materials and the types of applications in which they are used. It provides critical processing details such as temperatures, ratios, ranges, times, and rates. The article explains how to prepare aluminum components for electroplating, discussing surface roughening, anodizing, and immersion procedures along with expected results.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
... for mechanical smoothing for various substrates. A cyanide, noncyanide copper, or nickel strike must be applied to steel or zinc-alloy die castings before they are plated in acid copper solutions. Acid copper solutions cannot be used directly over substrates that are attacked by the high acidity or those where...
Abstract
This article provides a detailed account of the various alkaline and acid plating baths used for electrolytic copper plating. Dilute cyanide and Rochelle cyanide baths, high-efficiency sodium and potassium cyanide baths, alkaline noncyanide copper plating baths, and alkaline copper pyrophosphate baths, are discussed. The article reviews acid plating baths such as copper sulfate bath and copper fluoborate bath. It also presents information on the surface preparation considerations, bath composition, and operating variables of copper plating as well as the equipment used.
Book Chapter
Selective (Brush) Plating
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001261
EISBN: 978-1-62708-170-2
... in a production facility or be transported to the job site. Selective plating is also versatile; it permits most electroplate types to be deposited onto any conductive substrate that can be touched with an electrode. Cast iron, copper, steel, stainless steel, high-temperature nickel-base alloys, aluminum...
Abstract
Selective plating, also known as brush plating, differs from traditional tank or bath plating in that the workpiece is not immersed in a plating solution (electrolyte). Instead, the electrolyte is brought to the part and applied by a handheld anode or stylus, which incorporates an absorbent wrapping for applying the solution to the workpiece (cathode). This article focuses on the selective plating systems that include a power pack, plating tools, anode covers, specially formulated plating solutions, and any auxiliary equipment required for the particular application. It provides a detailed account of the applications of selective plating, with examples. The article describes the advantages, limitations, key process elements, and health and safety considerations of selective plating. It also includes the most important industrial, government, and military specifications.
Book Chapter
Electrodeposition Processes
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
... contact resistance, friction resistance, and atmospheric corrosion resistance when plated on aluminum, copper-base alloys, and steel, which are typically selected for their engineering properties. Indium can be readily electrodeposited from either acid or alkaline solutions. It is particularly useful...
Abstract
Copper can be electrodeposited from numerous electrolytes. Cyanide and pyrophosphate alkalines, along with sulfate and fluoborate acid baths, are the primary electrolytes used in copper plating. This article provides information on the chemical composition, plating baths, and operating conditions of electrodeposition processes for chromium plating, nickel plating, iron plating, cadmium plating, zinc plating, indium plating, lead plating, tin plating, silver plating, gold plating, brass plating, bronze plating, tin-lead plating, zinc-iron plating, and zinc-nickel plating. The article also discusses selective plating, electroforming, and other processes and where they are typically used.
Book Chapter
Nonelectrolytic Deposition Processes
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003216
EISBN: 978-1-62708-199-3
... uniformity Solderability and brazability Low labor costs Limitations Limitations Higher chemical cost than electroplating Brittleness Poor welding characteristics due to contamination of nickel plate with nickel-phosphorus deposits Need to copper strike plate alloys containing...
Abstract
This article describes the steps, bath composition and characteristics, equipment, plating rate, deposit thickness, and applications for different types of nonelectrolytic deposition processes, including electroless nickel plating, electroless copper plating and mechanical plating.
Book Chapter
Friction and Wear of Sliding Bearing Materials
Available to PurchaseSeries: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006412
EISBN: 978-1-62708-192-4
... … 80 18 2 … Alloy 194 PbIn7 93 … … 7 When a tin-containing overlay is plated directly onto a copper-lead or bronze surface, the tin has a tendency to migrate to the copper interface, forming a brittle copper-tin intermetallic compound. This decreases the corrosion resistance...
Abstract
A sliding bearing (plain bearing) is a machine element designed to transmit loads or reaction forces to a shaft that rotates relative to the bearing. This article discusses the properties of bearing materials. It provides information on bearing material systems: single-metal systems, bimetal systems, and trimetal systems. The article describes the designations, nominal compositions, mechanical properties, and applications of various sliding bearing alloys: tin-base alloys, lead-base alloys, copper-base alloys, aluminum-base alloys, silver-base alloys, zinc-base alloys, additional metallic materials, nonmetallic materials. It describes casting processes, powder metallurgy processes, and electroplating processes. The article also discusses the selection criteria for bearing materials.
Book Chapter
Corrosion in the Assembly of Semiconductor Integrated Circuits
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004172
EISBN: 978-1-62708-184-9
... treatment (drying, burn-in, or other heat treatment), the copper at the plated surface gives rise to a copper color. For Alloy 42-based leadframe, the migration of nickel and iron is probable; you may see a rusty color (due to the formation of an iron oxide) on the plated layer. Tarnishing by Plating...
Abstract
In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article focuses on the key factors contributing to corrosion of electronic components, namely, chemicals (salts containing halides, sulfides, acids, and alkalis), temperature, air (polluted air), moisture, contact between dissimilar metals in a wet condition, applied potential differences, and stress. It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration and plating additives.
Book Chapter
Corrosion Resistance of Aluminum Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003674
EISBN: 978-1-62708-182-5
... to 7%. Several also contain magnesium and/or manganese. The alloys in this series are strengthened by thermal processing. These alloys attain high strengths and are used in sheet, plate, and extruded forms, primarily in aerospace applications. Copper in aluminum alloys generally decreases...
Abstract
This article addresses the general effects of the composition, mechanical treatment, surface treatment, and processing on the corrosion resistance of aluminum and aluminum alloys. There are five major alloying elements: copper, manganese, silicon, magnesium, and zinc, which significantly influence the properties of aluminum alloys. There are organic coatings or paints that provide a barrier between a corrosive environment and aluminum surface. Inorganic coatings, including claddings, and enhanced oxides, such as anodized films, Boehmite films, and conversion coatings also help in corrosion prevention. The article assists in the information on selection of fabrication operations, as they play an important role in corrosion resistance.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001263
EISBN: 978-1-62708-170-2
... in the duplication of printing plates for coinage and currency because of its facility to produce the highest accuracy in copying engraved masters. Modern Applications Today, the electroforming industry sees a number of high-tech uses for nickel, copper, iron, and alloy deposits to electrofabricate...
Abstract
Electroforming is the process by which articles or shapes can be exactly reproduced by electrodeposition on a mandrel or form that is later removed, leaving a precise duplicate of the original. This article discusses electroforming applications, and explains electroforming of nickel, cobalt, iron, and copper, providing information on mandrel design and selection, electroforming solutions and operating variables. It discusses the significant aspects of electroforming that demand special considerations, such as metal distribution, internal deposit stress, roughness, and treeing. The article concludes with an overview of alloy electroforming.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005333
EISBN: 978-1-62708-187-0
... in the zinc. It concludes with information on the applications of zinc die castings. zinc alloy casings aging aluminum chromium plating copper zinc die castings electropainting finishing iron joining machining magnesium mechanical properties metalworking microstructure painting polishing...
Abstract
Die casting is the process most often used for shaping zinc alloys. This article tabulates the compositions of zinc casting alloys and comparison of typical mechanical properties of zinc casting alloys. It discusses additions of alloys to the zinc, including aluminum, magnesium, copper, and iron. The article illustrates a characteristic five-layer microstructure of zinc alloy casings. It discusses the various methods of finishing of zinc alloy die castings, including chromium plating, polishing, painting, and electropainting. The article describes the casting of inserts and their uses in the zinc. It concludes with information on the applications of zinc die castings.
Book Chapter
Surface Engineering of Nonferrous Metals
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003221
EISBN: 978-1-62708-199-3
... are the abrasive materials most often used in mass finishing of copper and copper alloys. Combinations of these abrasives may be used for specific applications. Surface Finishes Although mass finishing produces the final finishes for many parts, it is used more extensively for cleaning prior to plating...
Abstract
This article discusses surface engineering of nonferrous metals including aluminum and aluminum alloys, copper and copper alloys, magnesium alloys, nickel and nickel alloys, titanium and titanium alloys, zirconium and hafnium, zinc alloys, and refractory metals and alloys. It describes various techniques to improve functional surface properties and enhance the appearance of product forms. The article discusses various cleaning and finishing techniques such as abrasive blast cleaning, polishing and buffing, barrel burnishing, chemical cleaning, pickling, etching and bright dipping, electrochemical cleaning, mechanical cleaning, and mass finishing. It also examines coating processes such as plating, anodizing, chemical conversion coating, and thermal spray, and concludes with a discussion on oxidation-resistant coatings for refractory metals.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001264
EISBN: 978-1-62708-170-2
... on electroless nickel coatings on composites and plastics. aluminum alloys composites copper alloys electroless nickel baths electroless nickel plating electroless nickel plating equipment electroless nickel-boron coatings electroless nickel-phosphorus coatings fatigue strength ferrous alloys...
Abstract
Electroless nickel plating is used to deposit nickel without the use of an electric current. This article provides an overview of the solution composition and characteristics of the electroless nickel bath. It focuses on the metallurgical, mechanical and physical properties of electroless nickel-phosphorus coatings and electroless nickel-boron coatings. The effect of electroless nickel coatings on the fatigue strength of steel is also described. The article includes information on the recommended pretreatment procedures for different ferrous alloys, aluminum alloys, and copper alloys. It presents a detailed account of the equipment and various processes—including bulk and barrel plating—involved in electroless nickel plating, and discusses hydrogen relief methods. The article includes a comprehensive table on nickel plating applications, and concludes with information on electroless nickel coatings on composites and plastics.
Book Chapter
Brazing With Clad Brazing Materials
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001392
EISBN: 978-1-62708-173-3
... brazing filler alloy (BAlSi series) is clad to the aluminum-base alloy by hot roll bonding. The aluminum-clad brazing sheets can be brazed in a variety of atmospheres, and are used in numerous applications. Another commercial example of a clad brazing material is copper-clad stainless steel sheet...
Abstract
This article focuses on clad brazing material, which is defined as any base material or alloy that is clad with an appropriate lower-melting-point brazing filler metal. It provides information on typical clad brazing strip products in a tabular form and lists the advantages of using clad brazing materials. The article compares the steps in using brazing preforms to fabricate a brazed assembly with the steps involved in using clad brazing materials. It concludes with a discussion on design and manufacturing considerations, during brazing with clad brazing materials.
Book Chapter
Roll Welding
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001380
EISBN: 978-1-62708-173-3
... Pack used for roll welding. The top cover, which would be welded in place before rolling, is not shown. Titanium and titanium alloys are considerably more difficult to pack roll than are either steels or copper and aluminum alloys because most titanium alloys have very narrow working temperature...
Abstract
Roll welding (ROW) is a process in which two or more sheets or plates are stacked together and then passed through the rolls until sufficient deformation has occurred to produce solid-state welds. This article begins with a process description of two modes of roll welding, including pack rolling. It describes a patented roll welding process for fabrication of heat exchangers. The article presents a table showing the typical properties of common roll welded clad laminates. The relative weldability of selected dissimilar metals and alloys roll welded into clad-laminate form are also tabulated. The article concludes with information on cladding of metals by strip roll welding.
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