This article provides information on the Unified Numbering System designations and temper designations of copper and copper alloys. It discusses the basic types of heat treating processes of copper and copper alloys, namely, homogenizing, annealing, and stress relieving, and hardening treatments such as precipitation hardening, spinodal hardening, order hardening, and quench hardening and tempering. The article presents tables that list the compositions and mechanical properties of copper alloys. It also discusses two strengthening mechanisms of copper alloys, solid-solution strengthening and work hardening. Finally, the article provides information on the equipment used for the heat treating of copper and copper alloys, including batch-type atmosphere furnaces, continuous atmosphere furnaces, and salt baths.

This article describes the fundamentals of various techniques used for the production of copper and copper alloy powders. These include atomization (water, air, and gas), oxide reduction, and electrolysis. The article discusses the effects of electrolyte composition and operating conditions on the characteristics of copper and copper alloy powders.

This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It discusses the production of copper alloy castings. The article concludes with information on the gating and feeding systems used in production of copper alloy castings.

The properties of copper alloys occur in unique combinations found in no other alloy system. This article focuses on the major and minor alloying additions and their impact on the properties of copper. It describes major alloying additions, such as zinc, tin, lead, aluminum, silicon, nickel, beryllium, chromium, and iron. The article discusses minor alloying additions, including antimony, bismuth, selenium, manganese, and phosphorus. Copper alloys can be cast by many processes, including sand casting, permanent mold casting, precision casting, high-pressure die casting, and low-pressure die casting. The article provides information on the types of copper castings and tabulates the nominal chemical composition and mechanical properties of several cast alloys.

This article reviews the general characteristics of copper and copper alloys and explains how these characteristics affect the behavior of strip in different types of forming operations. These forming operations include blanking, piercing, bending, drawing and stretch forming, spinning, rubber-pad forming, and contour roll forming. Specialized forming operations such as hydraulic forming, embossing and swaging, and high-velocity metal forming are also reviewed. The article discusses the forming of smaller and larger parts from copper and copper alloy strips, as well as their property requirements and applications.

This article focuses on forging processes and equipment, types of forging alloys, and the forging practices associated with the forging of copper and copper alloys. An overview of the forging tolerances for small copper-base forgings is presented in a table.

This article discusses the identifying characteristics of the forms or mechanisms of corrosion that commonly attack copper metals, as well as the most effective means of combating each. It tabulates the corrosion ratings of wrought copper alloys in various corrosive media. The article describes the corrosion behavior of copper alloys in specific environments. It reviews the corrosion characteristics of copper and copper alloys in various acids, alkalis, salts, organic compounds, and gases. The article provides information on the behavior of copper alloys that is susceptible to stress-corrosion cracking in various industrial and chemical environments. It concludes with information on various corrosion testing methods, including aqueous corrosion testing, dynamic corrosion tests, and stress-corrosion testing.

Copper and copper alloys are widely used because of their excellent electrical and thermal conductivities, outstanding resistance to corrosion, and ease of fabrication, together with good strength and fatigue resistance. This article provides an overview of property and fabrication characteristics, markets, and applications of copper and its alloys. It contains several tables that provide helpful information on the chemical composition, classification, designation, uses, and mechanical properties of wrought copper and copper alloys.

Copper and copper alloys are widely used in many environments and applications because of their excellent corrosion resistance, which is coupled with combinations of other desirable properties. This article lists the identifying characteristics of the forms of corrosion that commonly attack copper metals as well as the most effective means of combating each. General corrosion, galvanic corrosion, pitting, impingement, fretting, intergranular corrosion, dealloying, corrosion fatigue, and stress-corrosion cracking (SCC) are some forms of corrosion. The article also lists a galvanic series of metals and alloys valid for dilute aqueous solutions, such as seawater and weak acids. It provides useful information on the effects of alloy compositions, selection for specific environments, and atmospheric corrosion of selected copper alloys. The article also tabulates the corrosion ratings of wrought copper alloys in various corrosive media.

The selection of surface treatments for copper and copper alloys is generally based on application requirements for appearance and corrosion resistance. This article describes cleaning, finishing, and coating processes for copper and copper alloys. These processes include pickling and bright dipping, abrasive blast cleaning, chemical and electrochemical cleaning, mass finishing, polishing and buffing, electroless plating, immersion plating, electroplating, passivation, coloring, and organic coatings.

Copper, copper alloys, and precious metals are probably the most easily brazed metals because of their resistance to oxidation at high temperatures. This article provides a brief discussion on the metallurgy of copper, copper alloys, and precious metals and discusses the filler metals, brazing fluxes, joint clearance and design, and different brazing processes used in brazing of copper, copper alloys, and precious metals.

Copper and copper alloys constitute one of the major groups of commercial metals due to their excellent electrical and thermal conductivities, corrosion and fatigue resistance, ease of fabrication, and good strength. This article lists the types, properties, fabrication characteristics, corrosion ratings, temper designations, and applications of wrought copper and copper alloys. It also presents an outline of the most commonly used mechanical working and heat treating processes. The copper industry in the United States is broadly composed of two segments: producers (mining, smelting, and refining companies) and fabricators (wire mills, brass mills, foundries, and powder plants). The article discusses copper production methods and describes major changes in the structure of the U.S. copper and copper alloys industry.

Wrought copper and copper alloys are produced in various mill-product forms for a variety of applications due to their high electrical conductivity, corrosion resistance, ease of fabrication, and good heat-transfer properties. This article describes the manufacturing processes used to produce wrought copper and copper alloys in the form of sheet and strip products, tubular products, and wire and cable. Common processes include melting, casting, hot and cold rolling, milling or scalping, annealing, cleaning, slitting, cutting, and leveling. In addition, the article discusses stress-relaxation characteristics of copper alloys.

This article begins with a discussion on machinability ratings of copper and copper alloys and then describes the factors influencing the machinability ratings. It explains the effect of alloying elements, cold working, and cutting fluid on the machinability of copper and copper alloys. In addition, the article provides a comprehensive discussion on various machining techniques that are employed for machining of copper and copper alloys: turning, planing, drilling, reaming, tapping and threading, multiple operation machining, milling, slitting and circular sawing, power band sawing and power hacksawing, grinding, and honing.

This article is a detailed account of additive manufacturing (AM) processes for copper and copper alloys such as copper-chromium alloys, GRCop, oxide-dispersion-strengthened copper, copper-nickel alloys, copper-tin alloys, copper-zinc alloys, and copper-base shape memory alloys. The AM processes include binder jetting, ultrasonic additive manufacturing, directed-energy deposition, laser powder-bed fusion, and electron beam powder-bed fusion. The article presents a review of the literature and state of the art for copper alloy AM and features data on AM processes and industrial practices, copper alloys used, selected applications, material properties, and where applicable, compares these data and properties to traditionally processed materials. The data presented and the surrounding discussion focus on bulk metallurgical processing of copper components. The discussion covers the composition and performance criteria for copper alloys that have been reported for AM and discusses key differences in process-structure-property relationships compared to conventionally processed material. The article also provides information on feedstock considerations for copper powder handling.

This article is a compilation of ternary alloy phase diagrams for which copper (Cu) is the first-named element in the ternary system. The other elements are Fe, Mn, Ni, Pb, S, Sb, Si, Sn, Ti and Zn. The diagrams are presented with element compositions in weight percent. The article includes 42 phase diagrams (liquidus projection, solidus projection, isopleths, isothermal section and vertical section).

This article is a compilation of binary alloy phase diagrams for which copper (Cu) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Selection of the process steps used, powder chosen, and lubricant choice have marked effects on the quality of a sintered component. This article describes the alloy composition, mechanical and structural properties, processing routes, and advantages of the common members of the copper alloy family, namely, pure copper, brass, and bronze, which all aid in the selection of the suitable material for structural and bearing applications. It outlines the structural applications of nickel silver alloys.

Copper and copper alloys are used extensively in structural applications in which they are subject to moderately elevated temperatures. At relatively low operating temperatures, these alloys can undergo thermal softening or stress relaxation, which can lead to service failures. This article is a collection of curves and tables that present data on thermal softening and stress-relaxation in copper and copper alloys. Thermal softening occurs over extended periods at temperatures lower than those inducing recrystallization in commercial heat treatments. Stress relaxation occurs because of the transformation of elastic strain in the material to plastic, or permanent strain.

Copper and copper alloys offer a unique combination of material properties that makes them advantageous for many manufacturing environments. This article begins with a discussion on common metals that are alloyed with copper to produce the various copper alloys. It then reviews the factors that affect the weldability of copper alloys, including thermal conductivity of the alloy being welded, shielding gas, type of current used during welding, joint design, welding position, and surface condition. The article provides information on arc welding processes such as gas-metal arc welding, shielded metal arc welding, submerged arc welding, plasma arc welding, and gas-tungsten arc welding. It concludes with a discussion on safe welding practices.