For the reinforcement of metal-matrix composites, four general classes of materials are commercially available: oxide fibers based primarily on alumina and alumina silica systems, nonoxide systems based on silicon carbide, boron fibers, and carbon fibers. This article discusses the key aspects of aluminum oxide fibers, silicon carbide fibers, boron fibers, and carbon fibers. The commercial fibers for reinforcement of metal-matrix composites are presented in a table. A tabulation of the coating schemes for silicon carbide monofilament fibers is also provided.

In general, metal-matrix composites (MMCs) are classified into three broad categories: continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. This article focuses on stir casting and melt infiltration as the two main methods of MMC solidification processing. It describes the MCC casting methods, such as sand and permanent mold casting, centrifugal casting, compocasting, and high-pressure die casting. The article discusses the MMC infiltration processes in terms of pressure infiltration casting and liquid metal infiltration. It reviews the powder metallurgy processing of aluminum MMCs and deformation processing of discontinuously reinforced aluminum composites. The article concludes with a discussion on the processing of fiber-reinforced aluminum.

Metal matrix composites (MMCs) can be synthesized by vapor phase, liquid phase, or solid phase processes. This article emphasizes the liquid phase processing where solid reinforcements are incorporated in the molten metal or alloy melt that is allowed to solidify to form a composite. It illustrates the three broad categories of MMCs depending on the aspect ratio of the reinforcing phase. The categories include continuous fiber-reinforced composites, discontinuous or short fiber-reinforced composites, and particle-reinforced composites. The article discusses the two main classes of solidification processing of composites, namely, stir casting and melt infiltration. It describes the effects of reinforcement present in the liquid alloy on solidification. The article examines the automotive, space, and electronic packaging applications of MMCs. It concludes with information on the development of select cast MMCs.

This article discusses the types, properties, and uses of continuous-fiber-reinforced composites, including glass, carbon, aramid, boron, continuous silicon carbide, and aluminum oxide fiber composites. While polyester and vinyl ester resins are the most used matrix materials for commercial applications, epoxy resins, bismaleimide resins, polyimide resins, and thermoplastic resins are used for aerospace applications. The article addresses design considerations as well as product forms and fabrication processes.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

This article provides information on the thermoplastic resins used as matrix materials for continuous fiber reinforced composites. It focuses on the materials that are suitable for fabrication of structural laminates and used for aerospace applications. The article provides a discussion on the background, categories, characteristics, product forms, properties, cost benefits, and processing techniques of thermoplastic resins. Strategies that have been advanced to deal with impregnation difficulties are also discussed.

This article reviews the abrasive and adhesive wear failure of several types of reinforced polymers, including particulate-reinforced polymers, short-fiber reinforced polymers (SFRP), continuous unidirectional fiber reinforced polymers (FRP), particulate-filled composites, mixed composites (SFRP and particulate-filled), unidirectional FRP composites, and fabric reinforced composites. Friction and wear performance of the composites, correlation of performance with various materials properties, and studies on wear-of failure mechanisms by scanning electron microscopy are discussed for each of these types.

Metal-matrix composites (MMCs) are used in structural applications, and in applications requiring wear resistance, thermal management, and weight savings. This article summarizes the mechanical and thermal properties of discontinuously reinforced aluminum MMCs, laminated metallic composites, and continuously aligned fiber reinforced MMCs.

Metal-matrix composites (MMCs) are a class of materials with a wide variety of structural, wear, and thermal management applications. This article discusses the primary processing methods used to manufacture discontinuous aluminum MMCs, namely, high-pressure die casting, pressure infiltration casting, liquid metal infiltration, spray deposition, and powder metallurgy methods. It describes the processing of continuous fiber-reinforced aluminum, discontinuously, reinforced titanium, and continuous fiber-reinforced titanium. The article concludes with information on work done to develop magnesium, copper, and superalloy MMCs.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

This article focuses on the production methods, properties, and applications of two main types of commercially available continuous-length ceramic fibers, namely, oxide fibers based on the alumina-silica system and on alpha-alumina, and nonoxide fibers based primarily on beta-phase silicon carbide. It provides a discussion on factors that are considered in understanding thermostructural capability of ceramic fiber for high-temperature ceramic-matrix composites (CMC) applications. The article tabulates other commercial oxide and nonoxide fiber types for CMC reinforcement.

Filament winding is a process for fabricating a composite structure in which continuous reinforcements, either previously impregnated with a matrix material or impregnated during winding, is placed over a rotating form or mandrel in a prescribed way to meet certain stress conditions. This article describes the advancements in filament winding and lists the advantages and disadvantages of filament winding. It discusses the effects of fiber tension in filament winding and the selection of fibers, resins, and materials for filament winding. The article emphasizes the three basic filament-winding patterns, such as helical, polar, and hoop. It presents information on the applications of filament winding, including rocket motors, natural gas vehicle (NGV) tanks, and sporting goods. The article presents recommendations for the basic design guidelines for filament-winding design/manufacturing process and concludes with a discussion on fabrication recommendations.

Interpretation of failures of ceramic-matrix composites, and in particular continuous fiber reinforced ceramic-matrix composites is complicated by the complex structure of the composite material. This article describes the failure characteristics and evidence of failure mechanisms of these composites, with illustrations.

This article discusses the mechanisms for enhancing the reliability of three types of ceramic-matrix composites: discontinuously reinforced ceramic-matrix composites, continuous fiber ceramic composites, and carbon-carbon composites. It also presents examples of their mechanical and physical properties. Examples that illustrate the properties of commercially available materials are also provided.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

The applications of discontinuously reinforced ceramic-matrix composites (CMCs) fall into four major categories, namely, cutting tool inserts; wear-resistant parts; aerospace and military applications; and other industrial applications, including engines and energy-related applications. This article provides examples for these four categories, with an emphasis on those applications/materials that have achieved commercial viability. The applications for continuous fiber ceramic composites are also summarized.

One of the key attributes of continuous fiber-reinforced ceramic composites (CFCCs) is their ability to undergo inelastic straining upon mechanical loading. This article reviews the mechanics of inelastic deformation and fracture of CFCCs, as needed for the development of damage-tolerant failure prediction methodologies for use in engineering design. It outlines a general framework for the description of fracture in structural materials in the presence of notches and cracks. The article describes the common classes of fracture behavior of CFCCs and presents the constitutive laws needed to describe crack-tip inelasticity. It demonstrates the effects of inelasticity on crack-tip stress fields and addresses the environmental degradation effects on damage tolerance.

This article presents general guidelines for machining metal matrix composites (MMC) and honeycomb structures. It provides guidelines for machining of specific MMCs, namely, aluminum-boron, aluminum-SiC, aluminum-Al 2 O 3 , and titanium-SiC MMCs. In addition, the article discusses the various parameters influencing drilling of dissimilar-material laminates.

Bulk molding compounds can be molded into a variety of complex shapes by methods that can be readily automated for high volume production. This article describes the formulation and processing (compound formation, and molding methods) of bulk molding compounds. It discusses the effects of fiber type, fiber length, and matrix type on thermoset bulk molding compounds. The markets for long-fiber-reinforced bulk molding compounds are electrical, ordnance, aerospace, industrial, sporting goods, and automotive applications.

This article begins with a brief history of composite materials and discusses its characteristics. It presents an introduction to the constituents, product forms, and fabrication processes of composite materials. The article concludes with a discussion on the applications of organic-matrix, metal-matrix, and ceramic-matrix composites.