This article discusses the mechanisms for enhancing the reliability of three types of ceramic-matrix composites: discontinuously reinforced ceramic-matrix composites, continuous fiber ceramic composites, and carbon-carbon composites. It also presents examples of their mechanical and physical properties. Examples that illustrate the properties of commercially available materials are also provided.

The applications of discontinuously reinforced ceramic-matrix composites (CMCs) fall into four major categories, namely, cutting tool inserts; wear-resistant parts; aerospace and military applications; and other industrial applications, including engines and energy-related applications. This article provides examples for these four categories, with an emphasis on those applications/materials that have achieved commercial viability. The applications for continuous fiber ceramic composites are also summarized.

Interpretation of failures of ceramic-matrix composites, and in particular continuous fiber reinforced ceramic-matrix composites is complicated by the complex structure of the composite material. This article describes the failure characteristics and evidence of failure mechanisms of these composites, with illustrations.

This article introduces the concepts of linear-elastic fracture mechanics (LEFM) and elastic-plastic fracture mechanics (EPFM). It reviews the fracture mechanics of ceramics and ceramic matrix composites (CMCs). The article describes some fracture toughness measurement techniques used on ceramics and CMCs: single edge notch bending, compact tension, double cantilever beam testing, chevron notch methods, and double torsion. It presents descriptions organized by their specimen types, and includes the advantages and disadvantages, as well as the experimental control schemes employed for each specimen type.

Post-processing includes various processes that might be required to produce finished components from the ceramic-matrix composites (CMC) materials. The processes consist of machining or finishing operations, coating, joining, assembly operations, and nondestructive evaluation of CMCs and its components. This article discusses the specific needs for science and technology in these areas relative to the goal of employing CMCs in a variety of applications.

Ceramic-matrix composites (CMCs) have ability to withstand high temperatures and have superior damage tolerance over monolithic ceramics. This article describes important processing techniques for CMCs: cold pressing, sintering, hot pressing, reaction-bonding, directed oxidation, in situ chemical reaction techniques, sol-gel techniques, pyrolysis, polymer infiltration, self-propagating high-temperature synthesis, and electrophoretic deposition. The advantages and disadvantages of each technique are highlighted to provide a comprehensive understanding of the achievements and challenges that remain in this area.

This article focuses on the production methods, properties, and applications of two main types of commercially available continuous-length ceramic fibers, namely, oxide fibers based on the alumina-silica system and on alpha-alumina, and nonoxide fibers based primarily on beta-phase silicon carbide. It provides a discussion on factors that are considered in understanding thermostructural capability of ceramic fiber for high-temperature ceramic-matrix composites (CMC) applications. The article tabulates other commercial oxide and nonoxide fiber types for CMC reinforcement.

This article highlights the selected applications of advanced polymer-matrix composites, metal-matrix composites, and ceramic matrix composites.

Ceramic-matrix composites (CMCs) are being developed for a number of high-temperature and high-performance applications in industrial, aerospace, and energy conservation sectors. This article focuses on processing, fabrication, testing, and characterization methods of CMCs, namely, discontinuously reinforced composites and continuous-fiber-reinforced composites. Processing methods include cold pressing, sintering, hot pressing, reaction bonding, melt infiltration, directed metal oxidation, sol-gel and polymer pyrolysis, self-propagating high-temperature synthesis and joining. A table summarizes the properties of various ceramic reinforcements and industrial applications of these composites.

This article addresses the types, properties, forms, and applications of fibers that are available for use in fiber-reinforced polymeric matrix composites, including glass, graphite, carbon, aramid, boron, silicon carbide, ceramic, continuous oxide and discontinuous oxide fibers. It describes the functions, types, and chemical composition of fiber sizing agents. The article discusses the styles, properties, applications, and weaving methods of unidirectional, two-directional and multidirectionally reinforced fabrics. The article also reviews the use of prepreg resins in aerospace and lower performance applications.

This article provides a summary of the concepts discussed in the articles under the Section “Constituent Materials” in ASM Handbook, Volume 21: Composites. The Section describes the major matrix resins and reinforcing fibers used in composite materials, as well as some of the intermediate material forms available for composite fabrication.

This article presents an overview of advanced composites, namely, polymer matrix composites, metal-matrix composites, ceramic-matrix composites, and carbon-matrix composites. It also provides information on the properties and applications of the composites in thermal management and electronic packaging.

For the reinforcement of metal-matrix composites, four general classes of materials are commercially available: oxide fibers based primarily on alumina and alumina silica systems, nonoxide systems based on silicon carbide, boron fibers, and carbon fibers. This article discusses the key aspects of aluminum oxide fibers, silicon carbide fibers, boron fibers, and carbon fibers. The commercial fibers for reinforcement of metal-matrix composites are presented in a table. A tabulation of the coating schemes for silicon carbide monofilament fibers is also provided.

Metal-matrix composites (MMCs) are a class of materials with potential for a wide variety of structural and thermal management applications. They are nonflammable, do not outgas in a vacuum, and suffer minimal attack by organic fluids, such as fuels and solvents. This article presents an overview of the status of MMCs, and provides information on physical and mechanical properties, processing methods, distinctive features, and various types of continuously and discontinuously reinforced aluminum, magnesium, titanium, copper, superalloy, and intermetallic-matrix composites. It further discusses the property prediction and processing methods for MMCs.

One of the key attributes of continuous fiber-reinforced ceramic composites (CFCCs) is their ability to undergo inelastic straining upon mechanical loading. This article reviews the mechanics of inelastic deformation and fracture of CFCCs, as needed for the development of damage-tolerant failure prediction methodologies for use in engineering design. It outlines a general framework for the description of fracture in structural materials in the presence of notches and cracks. The article describes the common classes of fracture behavior of CFCCs and presents the constitutive laws needed to describe crack-tip inelasticity. It demonstrates the effects of inelasticity on crack-tip stress fields and addresses the environmental degradation effects on damage tolerance.

This article reviews various rapid prototyping (RP) processes such as stereolithography, powder sintering, hot melt extrusion, sheet lamination, solid ground curing, and three-dimensional printing. It discusses the various material prototypes produced by RP technology. The list of materials includes particulate and fiber-reinforced polymers, ceramic-matrix composites, and metal-matrix composites. The article also provides information on freeform-fabrication techniques for composite part lay-up.