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Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003377
EISBN: 978-1-62708-195-5
... expansion coefficients, moisture swelling coefficients, static and dynamic viscoelastic properties, conductivity, and moisture diffusivity. unidirectional fiber composites aligned continuous fibers analytical method physical properties elasticity thermal expansion coefficients moisture swelling...
Abstract
A unidirectional fiber composite (UDC) consists of aligned continuous fibers that are embedded in a matrix. This article describes a variety of analytical methods that are used to determine the various physical properties of the UDC. These properties include elasticity, thermal expansion coefficients, moisture swelling coefficients, static and dynamic viscoelastic properties, conductivity, and moisture diffusivity.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003442
EISBN: 978-1-62708-195-5
... of thermal expansion and coefficient of moisture expansion; glass transition temperature; thermal conductivity, diffusivity, and specific heat. lamina nonmechanical testing laminate nonmechanical testing nonmechanical properties composite materials ply thickness density coefficient of thermal...
Abstract
Characterization of nonmechanical properties is performed in the testing and certification of composite materials. This article focuses on the properties of composites that are commonly investigated. The properties include: per ply thickness; constituent content; density; coefficient of thermal expansion and coefficient of moisture expansion; glass transition temperature; thermal conductivity, diffusivity, and specific heat.
Book Chapter
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003378
EISBN: 978-1-62708-195-5
... the development of the relations between mid-surface strains and curvatures and membrane stress and moment resultants. The article discusses the properties, such as thermal expansion, moisture expansion, and conductivity, of symmetric laminates and unsymmetric laminates. It describes the distribution...
Abstract
The properties of unidirectional composite (UDC) materials are quite different from those of conventional, metallic materials. This article provides information on the treatment of UDC stress-strain relations in the forms appropriate for analysis of thin plies of material. It explains the development of the relations between mid-surface strains and curvatures and membrane stress and moment resultants. The article discusses the properties, such as thermal expansion, moisture expansion, and conductivity, of symmetric laminates and unsymmetric laminates. It describes the distribution of temperature and moisture through the thickness of a laminate. Stresses caused due to mechanical loads, temperature, and moisture on the laminate are analyzed. The article concludes with information on interlaminar cracking, free-edge delamination, and transverse cracks of laminates.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003367
EISBN: 978-1-62708-195-5
... free volume. These result in lower moisture absorption, higher diffusivity, low cure shrinkage, low coefficient of thermal expansion (CTE), and low dielectric constant and dielectric loss when compared with epoxy and bismaleimide (BMI) systems. These attributes are particularly attractive for stable...
Abstract
Cyanate ester resins are a family of high-temperature thermosetting resins that bridge the gap in thermal performance between engineering epoxy and high-temperature polyimides. This article discusses the chemistry, properties and characteristics of the cyanate ester resins. It describes the processing procedures for the cyanate ester resins and provides information on properties for selected applications, such as space applications, radomes, and printed circuit boards.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003023
EISBN: 978-1-62708-200-6
... deflection temperature at 1.82 MPa (0.264 ksi) UL index Thermal conductivity Coefficient of thermal expansion, 10 −6 /°C °C °F °C °F W/m · K Btu/ft · h · °F Acrylonitrile-butadiene-styrene (ABS) 99 210 60 140 0.27 0.16 53 ABS-polycarbonate alloy (ABS-PC) 115 240 60 140 0.25...
Abstract
Thermal analysis provides a powerful tool for researchers and engineers in determining both unknown and reproducible behavioral properties of polymer molecules. This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, conformation of the base polymers, processing of the base polymers with or without additives; and the response to chemical, physical, and mechanical stresses of base polymers as unfilled, shaped articles or as components of composite structures. It also describes thermal analysis techniques, including differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. This article also summarizes the basic thermal properties used in the application of engineering plastics, such as thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass transition temperatures. It concludes with a discussion of the thermal and related properties of nine thermostat resin systems divided into three groups by low, medium, and high service temperature capabilities.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003390
EISBN: 978-1-62708-195-5
... changes and moisture absorption can have a significant impact on composite behavior, so laminate programs should be able to handle environmental loads. Engineering constants should include laminate expansion coefficients, and stress/strain calculations should include temperature and moisture components...
Abstract
This article begins with a discussion on the criteria for evaluating computer programs for composites structural analysis, including database capabilities, types of engineering calculations supported, interface and operating systems, and technical support. It describes the capabilities of programs, such as CompositePro, ESAComp, and V-Lab that provide a graphical interface, built-in databases, and integrated modules for the different types of analyses. The article reviews the modules of other programs used for composite analysis. The programs include ASCA, CADEC, CoDA, COMPASS, ESDU, LAP, PROMAL, and SACL. The article concludes with information on on-line programs and recourses.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... the 1980s, a significant level of research activity focused on the protection of high-performance carbon-carbon that used heat-stabilized polyacrylonitrile (PAN) or pitch-based fibers. These composites have higher strength, higher elastic moduli, and lower thermal expansion coefficients than the rayon-based...
Abstract
Carbon-carbon is a unique composite material in which a nonstructural carbonaceous matrix is reinforced by carbon fibers to create a heat-resistant structural material that finds application in the aerospace and defense industries. This article provides a detailed account of the fundamentals of protecting carbon-carbon composites and explains the various coating deposition techniques, namely, pack cementation, chemical vapor deposition, and slurry coatings. It includes information on the practical limitations of coatings for the carbon-carbon composites.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003465
EISBN: 978-1-62708-195-5
... are the measurement of both T g and the changes in its coefficient of linear thermal expansion (CTE) with cure. In TMA, the T g is measured as the intersection of the expansion curves in the glassy and rubbery states of the polymer matrix, possible for most polymers because there is a threefold difference...
Abstract
This article focuses on various thermal analysis techniques used to verify the cure of a polymer composite. The techniques include differential scanning calorimetry (DSC), modulated DSC, thermomechanical analysis, dynamic mechanical analysis, and dielectric analysis. The article also provides an overview of the composite failure modes affected by matrix resin and testing approach.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003428
EISBN: 978-1-62708-195-5
... potential difference of the above materials. A comparison of thermal expansion coefficients is given in Table 2 . The combination of CFRC and aluminum would result in the greatest thermal expansion mismatch, which would increase loads on the fasteners, adhesives, or sealants as the joint is subjected...
Abstract
Environmental effects of ground and flight environments, including temperature extremes, damage by chemical fluids, moisture, and so forth, affect the durability of polymer-matrix composites. This article provides information on corrosion control methods in aircraft structures. It discusses the design considerations for sealants in joints. The article describes the common methods to seal aircraft structures: fay surface, fillet, butt joint, channel, brush, and form-in-place seals. It discusses the surface preparation and application method of primer and topcoat systems. Primer and paint application equipment as well as sealant application equipment are reviewed.
Series: ASM Handbook
Volume: 5B
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v05b.a0006037
EISBN: 978-1-62708-172-6
... are covered subsequently. Thermal Properties Thermal properties, including cure shrinkage, thermal cycling, thermal shock, and temperature limitations, are important properties to quantify and understand for polymer flooring systems. Cure shrinkage and the linear coefficient of thermal expansion (LCTE...
Abstract
Polymeric floor coatings refer to flooring materials composed of multicomponent thermoset resins formulated with various fillers and pigments that are installed in situ, usually over concrete substrates. Polymeric flooring systems, specified for all industrial and commercial environments, use a variety of polymer chemistries and are constructed in a variety of methods and designs. This article provides a description of the service conditions for the polymeric flooring systems. It provides information on polymeric flooring systems, including thin-film coatings, self-leveling systems, membrane systems, broadcast systems, troweled systems, and terrazzo. The article also focuses on properties, applications, testing, and factors and requirements to be considered during the installation of polymeric floor coatings. It concludes with a discussion about coating failures, including bonding, cracking, chemical attack, and moisture that affect the polymeric floor coatings on concrete.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003381
EISBN: 978-1-62708-195-5
... environment has not been ensured. Absorbing moisture induces some degree of volumetric expansion, which can induce warping and other structure-performance effects similar to thermal expansion issues, in addition to the fundamental effects on the base properties of the material. While this is not commonly...
Abstract
Hygrothermal behavior of cured composite materials relates to the combined and commonly synergistic effects of moisture absorption and temperature on various physical, chemical and mechanical properties. This article focuses on the influence of resins or matrices, reinforcements, processing, and diffusion on hygrothermal behavior of polymer-matrix composites and provides an outline on general considerations in assessing them. It discusses the hygrothermal testing and conditioning of polymer-matrix composites to assess fundamental hygrothermal behavior. The article provides information on the accelerated aging process for understanding the degradation mechanisms and failure modes in composites. It also describes the effect of moisture absorption on mechanical properties of polymer-matrix composites.
Series: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006923
EISBN: 978-1-62708-395-9
... Coefficient of thermal expansion, 10 −6 /°C °C °F °C °F W/m · K Btu/ft · h · °F Acrylonitrile-butadiene-styrene (ABS) 99 210 60 140 0.27 0.16 53 ABS-polycarbonate alloy (ABS-PC) 115 240 60 140 0.25 0.14 35 Diallyl phthalate (DAP) 285 545 130 265 0.36 0.21 27...
Abstract
This article discusses the thermal properties of engineering plastics and elastomers with respect to chemical composition, chain configuration, and base polymer conformation as determined by thermal analysis. It describes the processing of base polymers with or without additives and their response to chemical, physical, and mechanical stresses whether as an unfilled, shaped article or as a component of a composite structure. It summarizes the basic thermal properties of thermoplastics and thermosets, including thermal conductivity, temperature resistance, thermal expansion, specific heat, and glass transition temperature. It also provides information on polyimide and bismaleimide resin systems. Representative examples of different types of engineering thermoplastics are discussed primarily in terms of structure and thermal properties.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003156
EISBN: 978-1-62708-199-3
... Alloys The primary requirements for resistance alloys are uniform resistivity, stable resistance (no time-dependent aging effects), reproducible temperature coefficient of resistance, and low thermoelectric potential versus copper. Properties of secondary importance are coefficient of expansion...
Abstract
Electrical resistance alloys used to control or regulate electrical properties are called resistance alloys, and those used to generate heat are referred to as heating alloys. This article covers both alloy types, describing the construction and use of resistors as well as heating elements. It also discusses soldering and joining methods, sensitivity and stability factors, and various design coefficients. In addition, it provides a detailed account of the properties and applications of thermostat metals and discusses the design of resistance heaters and their operating ranges.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003385
EISBN: 978-1-62708-195-5
... edges by the expansion of the material due to thermal expansion and/or swelling of the matrix from moisture absorption. An interesting aspect of thermal buckling for graphite-fiber composites is that graphite fibers have a negative coefficient of thermal expansion, thus it is possible for plates...
Abstract
This article focuses on the unique characteristics of composites and laminated plates, including orthotropic, anisotropic, and unsymmetric plates. It discusses the stability issues associated with practical, structural laminates based on the finite stack effects and transverse shear stiffness effects. The article presents the study of instability associated with postbuckling behavior and hygrothermal buckling in composite sandwich panels and shell panels.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003432
EISBN: 978-1-62708-195-5
... ASTM D 1895 Thermal properties, including glass transition temperature, coefficient of thermal expansion, and weight loss at temperature User defined Chemical exposure to acetone, chlorinated solvents, oils, hydraulic fluids, jet fuel, body fluids, alcohol User defined Moisture effects User...
Abstract
This article focuses on epoxy because this resin category has widespread use and because it is tested using quality control measures typical of most resin systems. It explains that a typical resin system will consist of one or more epoxy resins, a curing agent, and a catalyst to control the rate of reaction. The article describes the component material tests, mixed resin system tests, and prepreg tests for the resin system. These tests include high-performance liquid chromatography, infrared spectroscopy, and gel permeation chromatography. The article contains a table that lists typical resin and prepreg property tests.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003447
EISBN: 978-1-62708-195-5
... strength Shear modulus Thermal Coefficient of thermal expansion Thermal conductivity Specific heat Elecrical Dielectric constant Dielectric strength Dissipation factor Volume resistivity In-service conditions Service temperature Thermogravimetric analysis...
Abstract
This article discusses the materials and properties of polymer-matrix composites to characterize each generic material according to its composition and method of manufacture. It contains a table that lists the key physical, mechanical, thermal, and electrical properties, and in-service conditions of concern for resin-matrix composites. Axes definitions, symbols, and special property calculations for composite material property tests are reviewed. The article provides an overview of the performance capabilities of selected polymer-matrix composite materials such as thermoplastic-matrix composites and thermoset-matrix composites. The thermoplastic-matrix composites include thermoplastic polyester resins and fiber resin composites; thermoplastic polyamide resins and fiber-resin composites; and thermoplastic polysulfone resins and fiber-resin composites.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003032
EISBN: 978-1-62708-200-6
... Compressive modulus Shear strength Shear modulus Thermal Coefficient of thermal expansion Thermal conductivity Specific heat Electrical Dielectric constant Dielectric strength Dissipation factor Volume resistivity In-service conditions Service temperature...
Abstract
The design and analysis of aerospace and industrial composite components and assemblies requires a detailed knowledge of materials properties, which, in turn, depend on the manufacturing, machining, and assembly methods used. This article, through several tables and graphs, provides the mechanical properties, physical properties, and service characteristics of representative composite fiber-resin combinations, including thermoplastic matrix composites such as thermoplastic polyester resins, thermoplastic polyamide resins, and thermoplastic polysulfone resins, and thermoset matrix composites such as thermoset polyester resins, thermoset phenolic resins, thermoset epoxy resins, thermoset polyimide resins, and thermoset bismaleimide resins.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002478
EISBN: 978-1-62708-194-8
..., the solution for curvature stability is obtainable over a wide range of coupling coefficients and is independent of the thermal expansion and moisture swelling coefficients of the individual laminates. Temperature changes warp most metal-, ceramic-, or polymer-matrix, asymmetric composites, while moisture...
Abstract
This article begins with a discussion on fiber-reinforced composite materials and describes the generic behavior and structure/property relationships of composites. The article summarizes lamina properties and presents equations that help in the calculation of lamina properties. Composite laminates are constructed from lamina with uniaxial fiber orientation and frequently from textile fabrics as well. The article explains the characteristics of symmetric in-plane and through-thickness laminates; asymmetric in-plane and symmetric through-thickness laminates; asymmetric laminates; and curved laminates. It provides information on controlled thermal expansion composites, metal-matrix composites, and ceramic-matrix composites. The article illustrates the types of bonded joints and concludes with a discussion on design for manufacturing.
Book: Composites
Series: ASM Handbook
Volume: 21
Publisher: ASM International
Published: 01 January 2001
DOI: 10.31399/asm.hb.v21.a0003452
EISBN: 978-1-62708-195-5
... induced residual stresses do not normally compromise the design of a composite bonded repair; however, it is important that they be considered during the design phase. Coefficients of thermal expansion of substrates and repair materials Table 2 Coefficients of thermal expansion of substrates...
Abstract
Composite bonded repair technology is based on the use of advanced composite repairs or reinforcements that are adhesively bonded to a damaged structure. This article discusses the key steps that are normally encountered in the design, certification, and application of an adhesively bonded repair. Some examples of successful repairs to military aircraft are also discussed.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003066
EISBN: 978-1-62708-200-6
... in predictable ways. For example, for selenides of the type Ge-As-Se, the glass transformation temperature, hardness, Young's modulus, and strength increase, while the thermal expansion coefficient and molar volume decrease with a tighter structure. The properties of these glasses also depend on the type...
Abstract
This article describes the chemical composition, physical properties, thermal properties, mechanical properties, electrical properties, optical properties, magnetic properties, and chemical properties of glasses, glass-matrix composites, and glass-ceramics.
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