Porous coatings are used in the field of joint replacement, particularly in cementless total hip/knee arthroplasty. This article reviews the offerings and biomaterial properties in orthopedic surgery for the contemporary class of highly porous metals. It describes the traditional porous metals/coatings having an open-cell structure, high porosity, and a microstructure resembling that of the cancellous bone. The traditional porous metal/coating includes fiber-metal mesh, cobalt-chromium (CoCr) beads, cancellous-structured titanium, and plasma spray. The article discusses other porous metals/coatings that have been developed due to the limitations of traditional porous metals for numerous open-cell-structured metals, such as titanium-base foams and trabecular metals.

Metallography plays a significant role in the quality control of metals and alloys used in the manufacture of implantable surgical devices. This article provides information and data on metallographic techniques along with images showing the microstructure of biomedical orthopedic alloys, including stainless steels, cobalt-base alloys, titanium and titanium alloys, porous coatings, and emerging materials.

This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

Although stainless steel is naturally passivated by exposure to air and other oxidizers, additional surface treatments are needed to prevent corrosion. Passivation, pickling, electropolishing, and mechanical cleaning are important surface treatments for the successful performance of stainless steel. This article describes the surface treatment of stainless steels including abrasive blast cleaning, acid pickling, salt bath descaling, passivation treatments, electropolishing, and the necessary coating processes involved. It also describes the surface treatment of heat-resistant alloys including metallic contaminant removal, tarnish removal, oxide and scale removal, finishing, and coating processes.

Submerged arc welding (SAW) is an arc welding process in which the arc is concealed by a blanket of granular and fusible flux. This article provides a schematic illustration of a typical setup for automatic SAW and discusses the advantages and limitations and the process applications of SAW. The article discusses flux classification relative to production method, relative to effect on alloy content of weld deposit, and relative to basicity index. It describes the procedural variations and the effect of weld current, weld voltage, electrical stickout, travel speed, and flux layer depth on weld bead characteristics. The article concludes with information on weld defects, such as lack of fusion, slag entrapment, solidification cracking, hydrogen cracking, or porosity.

Hardfacing refers to the deposition of a specially selected material onto a component in order to reduce wear in service as a preventative measure or return a worn component to its original dimensions as a repair procedure. This article provides information on various hardfacing materials, namely, iron-base overlays, chromium carbide-based overlays, nickel- and cobalt-base alloys, and tungsten carbide-based metal-matrix composite overlays. It discusses the types of hardfacing processes, such as arc welding processes, and laser cladded, oxyacetylene brazing and vacuum brazing processes. The arc welding processes include shielding metal arc welding, gas metal arc welding/flux cored arc welding, gas tungsten arc welding, submerged arc welding, and plasma transferred arc welding. The article also reviews various factors influencing the selection of the appropriate hardfacing for specific applications.

Nickel alloys can be joined reliably by all types of welding processes or methods, with the exception of forge welding and oxyacetylene welding. This article discusses the heat treatment of nickel alloys and tabulates nominal compositions of selected weldable wrought nickel and nickel alloys. It provides information on gas-tungsten arc welding, gas-metal arc welding, plasma arc welding, shielded metal arc welding, and submerged arc welding for welding nickel alloys. The article reviews the defects encountered in the arc welding of nickel alloys, including porosity, cracking, and stress-corrosion cracking. It provides information on the factors that influence the choice of filler metal and welding process of nickel alloys.

This article provides an overview of how thermal spray technology has adapted to meet the needs of the orthopaedic industry. It includes the challenges facing the development of artificial joints, substrate material selection criteria, thermal spray solutions, and clinical outcomes of thermal spray coatings. The article focuses on plasma thermal spray, which is the technique most often used to make porous titanium and hydroxyapatite (HA) coatings, such as thermal spray titanium, thermal spray HA, solution-precipitated HA, thermal spray chromium oxide, and thermal spray chromium carbide cermet coatings.

Metal powders are used as fuels in solid propellants, fillers in various materials, such as polymers or other binder systems, and for material substitution. They are also used in food enrichment, environmental remediation market, and magnetic, electrical, and medical application areas. This article reviews some of the diverse and emerging applications of ferrous and nonferrous powders. It also discusses the functions of copier powders and the processes used frequently for copier powder coating.

Metals and alloy powders are used in welding, hardfacing, brazing, and soldering applications, which include hardface coatings, the manufacturing of welding stick electrodes and flux-cored wires, and additives in brazing pastes or creams. This article reviews these applications and the specific powder properties and characteristics they require.

This article provides a review of metallographic procedures and techniques for analyzing the microstructure of fusion welded joints. It discusses sample preparation, the use of backing plates, and common sectioning methods. It identifies the various types of defects that can occur in arc welded metals, organizing them according to the sectioning method by which they are observed. It describes the relationship between weld bead morphology and sectioning direction and its effect on measurement error. The article examines micrographs from stainless steel, aluminum, and titanium alloy joints, highlighting important details such as solidification and solid-state transformation structures and what they reveal about the welding process. Besides arc welding, it also discusses laser and electron beam welding methods, resistance and spot welding, and the welding of dissimilar metals.

Cast iron can be described as an alloy of predominantly iron, carbon, and silicon. This article discusses the classification of cast irons, such as gray cast iron, white cast iron, malleable cast iron, ductile cast iron, and compacted graphite iron. It reviews the various special techniques, such as groove face grooving, studding, joint design modifications, and peening, for improving the strength of a weld or its fitness for service. The article discusses the need for postweld heat treatment that depends on the condition of the casting, possible distortion during subsequent machining, the desired finish of the machined surfaces, and prior heat treatment. It describes various welding process for welding cast irons, including oxyfuel welding, braze welding, shielded metal arc welding, gas metal arc welding, and gas-tungsten arc welding.

The chemical process being catalyzed should have a high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the general catalyst preparation procedures, namely, impregnation, ion exchange, and precipitation. Catalyst carriers are usually high-surface-area inorganic materials with complex pore structures, into which catalytic materials such as palladium, platinum, cobalt, chromium oxide, and vanadium pentoxide are deposited using these procedures. The article also provides information on catalyst powder processing.

Chromate conversion coatings (CCCs) are primarily used to improve adhesion of subsequently applied organic coatings or to impart corrosion resistance during atmospheric exposure. This article describes the factors that affect the formation of CCCs. It provides information on the processing sequence, morphology, composition, and properties of CCCs. The article discusses the electrochemical impedance spectroscopy approach used for evaluating conversion coatings. The test methods for various CCCs properties are also reviewed. The article examines the various coatings associated with chromate-free conversion. These include: titanium and zirconium fluorocomplexes; cerium-base, manganese-base, cobalt-base, and molybdate-base conversion coatings; hydrotalcite coatings; and organic coatings.

This article tabulates the nominal compositions for nickel and cobalt alloys. It illustrates the comparison of strain-hardening rates of a number of alloys in terms of the increase in hardness with increasing cold reduction. The forming practice for age-hardenable alloys and the lubricants used in the forming processes of nickel and cobalt alloys are also discussed. The article summarizes the modification of tools and dies used for cold forming other metals, as the physical and mechanical properties of nickel and cobalt alloys frequently necessitate it. It discusses forming techniques for these alloys and provides several examples of these techniques, which include shearing, blanking, piercing, deep drawing, spinning, explosive forming, bending, and expanding/tube forming.

This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.

Chemical conversion coatings are adherent surface layers of low-solubility oxide, phosphate, chromate, and chromate-free compounds produced by the reaction of suitable reagents with the metallic surface. This article provides an overview on chromate-free coatings, along with coverage on the processes of low-solubility oxide, phosphate, and chromate conversion coating. Some applications using chemical conversion coatings on various aluminum alloys are given in a table. The article also provides information on the advantages and disadvantages of chromate conversion coatings. It concludes a discussion on organic-based coatings.

Metallographic examination is a critical step in the assessment of thermal spray coating characteristics. This article discusses the major steps involved in metallographic examination: sectioning, mounting, grinding, polishing, optical microscopy, and image analysis. It provides a discussion on etching to reveal grain structure. The article also provides recommendations for metallographic examination of some standard coatings.