This article addresses the cobalt and cobalt-base alloys most suited for aqueous environments and those suited for high temperatures. The performance of cobalt alloys in aqueous environments encountered in commercial applications is discussed. The article provides information on the environmental cracking resistance of the cobalt alloys. Three welding processes that are used for hardfacing with the high-carbon Co-Cr-W alloys, namely, oxyacetylene, gas tungsten arc, and plasma-transferred arc are also discussed. The article examines the effects of various modes of high-temperature corrosion. It describes the applications and fabrication of cobalt alloys for high-temperature service.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

This article reviews some concepts considered important for an understanding of processes used for preparing cobalt-chromium alloy implants, the microstructures resulting from this processing, and the resulting material properties. The review includes the solidification of alloys, diffusionless (martensitic) phase transformation as occurs with face-centered cubic to hexagonal close-packed transformation in cobalt-chromium alloys, stacking faults and twins and their role in this transformation. It also includes strengthening mechanisms that are responsible for the mechanical properties of cast and wrought cobalt alloys. The article contains tables that list the commonly used cobalt alloys and their biomedical applications and chemical compositions. It discusses the mechanical and corrosion properties of cobalt alloys, and provides a description of the microstructure of cobalt alloys.

This article provides a discussion on forging methods, melting procedures, forging equipment, forging practices, grain refinement, and critical factors considered in forging process. It describes the different types of solid-solution-strengthened and precipitation-strengthened superalloys, namely, iron-nickel superalloys, nickel-base alloys, cobalt-base alloys, and powder alloys. The article discusses the microstructural mechanisms during hot deformation and presents processing maps for various superalloys. It concludes with a discussion on heat treatment of wrought heat-resistant alloy forgings.

Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.

Batch furnaces and continuous furnaces are commonly used in heat treating. This article provides a detailed account of various heat treating equipment and its furnace types, including salt bath equipment (externally heated, immersed-electrode and submerged-electrode furnaces), and fluidized-bed equipment (external-resistance-heated fluidized beds). It describes various auxiliary equipment used in cold-wall furnaces, namely, heating elements and pumping systems. Five types of heat-resistant alloys are used for furnace parts, trays, and fixtures: Fe-Cr alloys, Fe-Cr-Ni alloys, Fe-Ni-Cr alloys, nickel-base alloys and cobalt-base alloys. The article lists the recommended applications for alloys for parts and fixtures for various types of heat treating furnaces.

This article reviews the corrosion interactions between biomedical alloys, in particular iron-base, titanium-base, and cobalt-base alloys, in complex geometries and in applications where there are significant cyclic stresses and potential for wear and fretting motion. It discusses the nature of these metal surfaces and their propensity for corrosion reactions when combined with similar or different alloys in complex restrictive environments within the human body, and under loading conditions. The article describes factors that influence mechanically assisted crevice corrosion. It reviews tests, such as scratch test and in vitro fretting corrosion test, developed to investigate the aspects of mechanically assisted corrosion of metallic biomaterials.

This article focuses on the analysis of materials and mechanical- (or biomechanical-) based medical device failures. It reviews the failure analysis practices, including evidence receipt, cleaning, nondestructive examination, destructive examination, exemplars analysis, and device redesign. The article examines the common failure modes, such as overload, fatigue, corrosion, hydrogen embrittlement, and fretting, of medical devices. The failure analysis of orthopedic implants, such as permanent prostheses and internal fixation devices, is described. The article reviews the failure mechanisms in some of the more common medical device materials, namely, stainless steels, titanium alloys, cobalt-base alloys, and nitinol. It presents case histories with examples for failure analysis.

Selecting the proper cutting tool material for a specific machining application can provide substantial advantages, including increased productivity, improved quality, and reduced costs. This article begins with a description of the factors affecting the selection of a cutting tool material. This is followed by a schematic representation of their relative application ranges in terms of machining speeds and feed rates. The article provides a detailed account of chemical compositions of various tool materials, including high-speed tool steels, cobalt-base alloys, cemented carbides, cermets, ceramics, cubic boron nitride, and polycrystalline diamond. It compares the toughness, and wear resistance for these cutting tool materials. Finally, the article explains the steps for selecting tool material grades for specific application.

Hardfacing is defined as the application of a wear-resistant material, in depth, to the vulnerable surfaces of a component by a weld overlay or thermal spray process Hardfacing materials include a wide variety of alloys, carbides, and combinations of these materials. Iron-base hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type alloys. Hardfacing applications for wear control vary widely, ranging from very severe abrasive wear service, such as rock crushing and pulverizing to applications to minimize metal-to-metal wear. This article discusses the types of hardfacing alloys, namely iron-base alloys, nonferrous alloys, and tungsten carbides, and their applications and advantages.

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.

This article reviews specific processing characteristics and forging-related properties of commonly forged families of metals and alloys, including carbon and alloy steels, stainless steels, heat-resistant alloys (iron, cobalt, and nickel base alloys), aluminum alloys, copper and copper alloys, magnesium alloys, and titanium alloys. It provides forging process variables such as stock preparation, heating and cooling of forgings, die lubrication, trimming, and cleaning of these metals and alloys. The article explains the effect of temperature, deformation rate, and die temperature on forgeability and describes the forging methods of these metals and alloys.

This article describes the allotropic modification and atmospheric corrosion of pure tin. Corrosion of pure tin due to oxidation reaction, and reaction with the other gases, water, acids, bases, and other liquid media, is discussed. The article provides information on corrosion behavior on soft solders, pewter, bearing alloys, tin-copper alloys, and tin-silver alloys. It reviews the influence of corrosion on immersion tin coating, tin-cadmium alloy coatings, tin-cobalt coatings, tin-copper coatings, tin-lead coatings, tin-nickel coatings, and tin-zinc coatings. The general properties and corrosion resistance of tinplate are summarized. The article also describes the methods of corrosion testing of coatings; these include an analysis of coating thickness measurements, porosity and rust resistance testing, solderability test, and specific special tests.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of cobalt alloys (cast Vitallium and cast ASTM F75 alloys) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fatigue fracture, microcrack, and stair-step fracture surface of these alloys.

Although stainless steel is naturally passivated by exposure to air and other oxidizers, additional surface treatments are needed to prevent corrosion. Passivation, pickling, electropolishing, and mechanical cleaning are important surface treatments for the successful performance of stainless steel. This article describes the surface treatment of stainless steels including abrasive blast cleaning, acid pickling, salt bath descaling, passivation treatments, electropolishing, and the necessary coating processes involved. It also describes the surface treatment of heat-resistant alloys including metallic contaminant removal, tarnish removal, oxide and scale removal, finishing, and coating processes.

Characteristics of stainless steel that affect its formability include yield strength, tensile strength, and ductility, in addition to the effect of work hardening on these properties. This article discusses the forming process of stainless steel, heat-resistant alloys and refractory metals, detailing the major aspects of forming, including formability, lubrication, and forming methods and tools. The effect of factors such as alloy condition, cold reduction, forming direction (in the case of heat-resistant alloys) and temperature (in the case of refractory metals) on formability is also discussed.

This article contains a table that lists the density of metals and alloys. It presents information on aluminum, copper, iron, lead, magnesium, nickel, tin, titanium, and zinc, an their respective alloys. Information on wrought alloys, permanent magnet materials, precious metals, and rare earth metals is also listed.

Density allows for conversion of uniform corrosion rates from units of weight (or mass) loss per unit area per time to thickness per unit time. This article contains a table that lists density of metals and alloys. These include aluminum, copper, iron, stainless steels, magnesium, lead, and their alloys.

Cast nickel-base alloys are used extensively in corrosive-media and high-temperature applications. This article briefly reviews the common types of heat treatments of nickel alloy castings: homogenization, stress relieving, in-process annealing, full annealing, solution annealing, quenching, coating diffusion, and precipitation. It describes the three general strengthening mechanisms, namely, solid-solution hardening, age hardening, and carbide precipitation. The article summarizes the typical heat treatment of the general families of nickel-base castings used in industrial applications. It focuses on the solution treatment and age hardening of cast nickel-base superalloys and the heat treatment of cast solid-solution alloys for corrosion-resisting applications. The article also discusses the typical types of atmospheres used in annealing or solution treating: exothermic, endothermic, dry hydrogen, dry argon, and vacuum.