This article addresses the cobalt and cobalt-base alloys most suited for aqueous environments and those suited for high temperatures. The performance of cobalt alloys in aqueous environments encountered in commercial applications is discussed. The article provides information on the environmental cracking resistance of the cobalt alloys. Three welding processes that are used for hardfacing with the high-carbon Co-Cr-W alloys, namely, oxyacetylene, gas tungsten arc, and plasma-transferred arc are also discussed. The article examines the effects of various modes of high-temperature corrosion. It describes the applications and fabrication of cobalt alloys for high-temperature service.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as this is the single largest application area of cobalt-base alloys.

This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.

This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

This article is a compilation of ternary alloy phase diagrams for which cobalt (Co) is the first-named element in the ternary system. The other elements are Cr, Cu, Fe, Mo, Ni, Ti, V, and W. The diagrams are presented with element compositions in weight percent. The article includes 36 phase diagrams (liquidus projection, solidus projection and isothermal section).

This article is a compilation of more than 35 binary alloy phase diagrams for which cobalt (Co) is the first named element in the binary pair. The diagrams plot alloy composition in terms of weight percent, while indicating atomic percent along a secondary scale. Each diagram is accompanied by a table of crystallographic data that includes composition ranges as well as the Pearson symbol, space group, and prototype for each phase.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of cobalt alloys (cast Vitallium and cast ASTM F75 alloys) and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the fatigue fracture, microcrack, and stair-step fracture surface of these alloys.

This article tabulates the nominal compositions for nickel and cobalt alloys. It illustrates the comparison of strain-hardening rates of a number of alloys in terms of the increase in hardness with increasing cold reduction. The forming practice for age-hardenable alloys and the lubricants used in the forming processes of nickel and cobalt alloys are also discussed. The article summarizes the modification of tools and dies used for cold forming other metals, as the physical and mechanical properties of nickel and cobalt alloys frequently necessitate it. It discusses forming techniques for these alloys and provides several examples of these techniques, which include shearing, blanking, piercing, deep drawing, spinning, explosive forming, bending, and expanding/tube forming.

Cast cobalt alloys were developed to bridge the gap between high-speed steels and carbides. Although comparable in room-temperature hardness to high-speed steel tools, cast cobalt alloy tools retain their hardness to a much higher temperature and can be used at higher cutting speeds than high-speed steel tools. This article provides an overview of the processing, properties, and applications of these alloys.

This article tabulates the chemical composition of iron-base, titanium-base, and cobalt-base alloys and illustrates the microstructures of these materials. It discusses the surface morphology and chemistry of oxide-film-covered alloys and provides insights into the interaction. The article illustrates the interfacial structure of a biomaterial surface contacting with the biological environment. It describes the corrosion behavior of stainless steel, cobalt-base alloy, and titanium alloys. The electrochemical methods used for studying metallic biomaterials corrosion are also discussed. The article concludes with information on the biological consequences of in vivo corrosion and biocompatibility.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

Hardenable steels with high-alloy content includes a family of nickel-cobalt steels with high strength and high toughness. This article describes various heat treatments, namely, normalizing, annealing, hardening, tempering, stress relieving, overaging, quenching, refrigeration, and straightening treatment, applied to HP9-4-20, HP9-4-25, HP9-4-30, and HP9-4-45 steels. These steels have high fracture toughness when heat treated to very high strength levels. The article also describes heat treatments applied to other alloys such as AF 1410, AerMet 100, AerMet 310, and AerMet 340, which provide a good combination of high strength and toughness that make them attractive for aerospace application. It also presents tables that provide information on the effect of aging temperatures and heat treatment on mechanical properties and impact energy of these steels.

This article focuses on the tribological behavior of group 1, 2, and 3 cobalt-base alloys, namely, carbide-type wear-resistant alloys and laves-type wear-resistant alloys. The behavior includes hardness, yield strength and ductility, and fracture toughness. The article contains a table that lists the nominal compositions and typical applications of cobalt-base alloys. It discusses the properties and relative performance of specific alloys when subjected to the more common types of wear. These include abrasive wear, high-temperature sliding wear, rolling-contact fatigue wear, and erosive wear.

The process of making assemblies of solid-solution and precipitation hardening groups of alloys and superalloys often requires welding of dissimilar metals, welding of diffusion-bonded materials, and sometimes weld overlay cladding and even thermal spraying that in turn requires special knowledge and treatments developed specifically for each material. This article emphasizes the special metallurgical welding considerations for welding solid-solution and precipitation hardening nickel alloys, cobalt alloys, and superalloys.

This article discusses the weldability characteristics of cobalt-base corrosion-resistant (CR) alloys, titanium-base CR alloys, zirconium-base CR alloys, and tantalum-base CR alloys that assist in the selection of suitable alloy and welding method for producing high-quality welds.

Traditional processing methods for the part production of Co-Cr alloys include casting, powder metallurgy, and metal forming. However, the steps involved during materials processing followed by metal forming and machining are time consuming and fraught with processing variables. Three-dimensional (3D) printing enables rapid evolution in design, personalization, and so on. This article presents a brief description of some common additive manufacturing (AM) processes for the production of cobalt alloy parts, and provides a comparison between AM and conventional processing methods. The discussion is centered on process-microstructure-properties correlation in additively manufactured cobalt alloys and applications of these alloys.

This article reviews the concepts considered important for an understanding of the processes used for preparing cobalt-chromium alloy implants, the microstructures resulting from this processing, and the resulting material properties. The review includes solidification of alloys, diffusionless (martensitic) phase transformation as occurs with face-centered cubic to hexagonal close-packed transformation in cobalt-chromium alloys, and stacking faults and twins and their role in this transformation. It also discusses the strengthening mechanisms that are responsible for the mechanical properties of cast and wrought cobalt alloys. The article contains tables that list the commonly used cobalt alloys and their biomedical applications and chemical compositions. It discusses the mechanical and corrosion properties of cobalt alloys, and provides a description of the microstructure of cobalt alloys.

This article discusses some of the additive manufacturing (AM) based fabrication of alloys and their respective mechanical, electrochemical, and in vivo performance. Firstly, it briefly discusses the three AM techniques that are most commonly used in the fabrication of metallic biomedical-based devices: binder jetting, powder-bed fusion, and directed-energy deposition. The article then characterizes the electrochemical properties of additive-manufactured/processed cobalt-chromium alloys. This is followed by sections providing an evaluation of the biological response to CoCr alloys in terms of the material and 3D printing fabrication. Discussion on the biological response as a function of direct cellular activity on the surface of CoCr alloys in static conditions (in vitro), in dynamic physiological conditions (in vivo), and in computer-simulated conditions (in silico) are further discussed in detail. Finally, the article provides information on the qualification and certification of AM-processed medical devices.