Hardfacing refers to the deposition of a specially selected material onto a component in order to reduce wear in service as a preventative measure or return a worn component to its original dimensions as a repair procedure. This article provides information on various hardfacing materials, namely, iron-base overlays, chromium carbide-based overlays, nickel- and cobalt-base alloys, and tungsten carbide-based metal-matrix composite overlays. It discusses the types of hardfacing processes, such as arc welding processes, and laser cladded, oxyacetylene brazing and vacuum brazing processes. The arc welding processes include shielding metal arc welding, gas metal arc welding/flux cored arc welding, gas tungsten arc welding, submerged arc welding, and plasma transferred arc welding. The article also reviews various factors influencing the selection of the appropriate hardfacing for specific applications.

This article focuses on coatings and overlays adopted for use as wear- and corrosion-resistant materials in oil sand processing. It describes the most common application processes for oil sand coatings and overlays, including welding, high-velocity oxyfuel thermal spray, laser cladding, and vacuum brazing. The article provides information on the selection of overlays and materials such as chromium-carbide-base overlays and tungsten carbide metal-matrix composites.

Hardfacing is defined as the application of a wear-resistant material, in depth, to the vulnerable surfaces of a component by a weld overlay or thermal spray process Hardfacing materials include a wide variety of alloys, carbides, and combinations of these materials. Iron-base hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type alloys. Hardfacing applications for wear control vary widely, ranging from very severe abrasive wear service, such as rock crushing and pulverizing to applications to minimize metal-to-metal wear. This article discusses the types of hardfacing alloys, namely iron-base alloys, nonferrous alloys, and tungsten carbides, and their applications and advantages.

This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as this is the single largest application area of cobalt-base alloys.

Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

Surface treatments are used in a variety of ways to improve the material properties of a component. This article provides information on surface treatments that improve service performance so that the design engineer may consider surface-engineered components as an alternative to more costly materials. It describes solidification surface treatments such as hot dip coatings, weld overlays, and thermal spray coatings. The article discusses deposition surface treatments such as electrochemical plating, chemical vapor deposition, and physical vapor deposition processes. It explains surface hardening and diffusion coatings such as carburizing, nitriding, and carbonitriding. The article also tabulates typical characteristics of carburizing, nitriding, and carbonitriding diffusion treatments.

This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.

This article describes the process of selecting an optimum coating and material system for a specific application. It reviews critical coating functions that influence the coating selection process, and presents some application success stories. The article explores the benefits of thermal spray coatings and functions they provide. It also presents key references from various National Thermal Spray Conference, United Thermal Spray Conference, and International Thermal Spray Conference Proceedings from 2006 through 2012.

The process of making assemblies of solid-solution and precipitation hardening groups of alloys and superalloys often requires welding of dissimilar metals, welding of diffusion-bonded materials, and sometimes weld overlay cladding and even thermal spraying that in turn requires special knowledge and treatments developed specifically for each material. This article emphasizes the special metallurgical welding considerations for welding solid-solution and precipitation hardening nickel alloys, cobalt alloys, and superalloys.

This article discusses the general welding characteristics and metallurgical welding considerations that play an important function during the welding of nickel, nickel-copper, nickel-chromium, and nickel-chromium-iron alloys.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

This article focuses on noble and neutral coatings and the requirements necessary to achieve successful industrial applications. These include corrosion and wear control and repair applications in processing and chemical industries, and valve and downhole drilling applications in the petrochemical industry. The article also discusses substrate chemistry and preparation; coating selection process and microstructure; sealing by chemical, post-heat treatments, and laser processing; and thermal spray process alternatives.

Metals and alloy powders are used in welding, hardfacing, brazing, and soldering applications, which include hardface coatings, the manufacturing of welding stick electrodes and flux-cored wires, and additives in brazing pastes or creams. This article reviews these applications and the specific powder properties and characteristics they require.

This article addresses the cobalt and cobalt-base alloys most suited for aqueous environments and those suited for high temperatures. The performance of cobalt alloys in aqueous environments encountered in commercial applications is discussed. The article provides information on the environmental cracking resistance of the cobalt alloys. Three welding processes that are used for hardfacing with the high-carbon Co-Cr-W alloys, namely, oxyacetylene, gas tungsten arc, and plasma-transferred arc are also discussed. The article examines the effects of various modes of high-temperature corrosion. It describes the applications and fabrication of cobalt alloys for high-temperature service.

This article provides a brief introduction to abrasive wear-resistant coating materials that contain a large amount of hard phases, such as borides, carbides, or carboborides. It describes some of the commonly used methods of producing thick wear-resistant coatings. The article also provides information on metal-matrix composites and cemented carbides. The three base-alloying concepts, including cobalt-, iron-, and nickel-base alloys used for wear-protection applications, are also described. The article compares the tribomechanical properties of the materials in a qualitative manner, thus allowing a rough materials selection for practitioners. It presents a brief discussion on hot isostatic pressing (HIP) cladding, sinter cladding, and manufacturing of thick wear-resistant coatings by extrusion or ring rolling. The article also discusses the processing sequence of thick wear-resistant coatings, namely, compound casting, deposition welding, and thermal spraying.

This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

High temperature corrosion may occur in numerous environments and is affected by factors such as temperature, alloy or protective coating composition, time, and gas composition. This article explains a number of potential degradation processes, namely, oxidation, carburization and metal dusting, sulfidation, hot corrosion, chloridation, hydrogen interactions, molten metals, molten salts, and aging reactions including sensitization, stress-corrosion cracking, and corrosion fatigue. It concludes with a discussion on various protective coatings, such as aluminide coatings, overlay coatings, thermal barrier coatings, and ceramic coatings.

Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.