This article briefly describes the basic attributes of chromate conversion coatings and the processes for applying them. It provides information on the influence of substrate microstructure on the performance of coating deposits and on the mechanism of substrate protection supplied by chromate coatings. The article also discusses the development of replacement technologies in response to environmental constraints that have developed around the use of chromium-base compounds.

Chromate conversion coatings (CCCs) are primarily used to improve adhesion of subsequently applied organic coatings or to impart corrosion resistance during atmospheric exposure. This article describes the factors that affect the formation of CCCs. It provides information on the processing sequence, morphology, composition, and properties of CCCs. The article discusses the electrochemical impedance spectroscopy approach used for evaluating conversion coatings. The test methods for various CCCs properties are also reviewed. The article examines the various coatings associated with chromate-free conversion. These include: titanium and zirconium fluorocomplexes; cerium-base, manganese-base, cobalt-base, and molybdate-base conversion coatings; hydrotalcite coatings; and organic coatings.

Chemical conversion coatings are adherent surface layers of low-solubility oxide, phosphate, chromate, and chromate-free compounds produced by the reaction of suitable reagents with the metallic surface. This article provides an overview on chromate-free coatings, along with coverage on the processes of low-solubility oxide, phosphate, and chromate conversion coating. Some applications using chemical conversion coatings on various aluminum alloys are given in a table. The article also provides information on the advantages and disadvantages of chromate conversion coatings. It concludes a discussion on organic-based coatings.

This article focuses on alternatives to chromium in both hard chromium plating and chromate conversion coating. These include electroless nickel plating, nickel-tungsten composite electroplating, spray coating applications, and cobalt/molybdenum-base conversion coating. The article discusses the material and process substitutions that can be used to eliminate the use or emissions of chromium in industrial processes. It describes the physical characteristics of each coating, economics, environmental impacts, advantages, and disadvantages of alternative processes.

There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes continuous electrodeposition for steel strip and babbitting and discusses phosphate and chromate conversion coatings as well. It also addresses painting, discussing types and selection, surface preparation, and application methods. In addition, the article describes rust-preventive compounds and their application. It also provides information on weld-overlay and thermal spray coating, porcelain enameling, and the preparation of enamel frits for steels. The article closes by describing methods and materials for ceramic coating.

This article provides a brief discussion on the common types of overlayers that can be used on a metal surface to protect it from corrosion. These overlayers include phosphate, chromate, and chromate-free conversion coatings; hot dip galvanizing; cementitious linings; glass and porcelain enamels; electroplating; thermal spray coatings; and rubber linings.

This article is a general introduction to surface engineering of engineering components, providing an overview of the applications of surface treatments and the environmental protection regulations directly or indirectly related to surface engineering processes.

This guide rates the compatibility of dissimilar structural materials joined together for service in seawater, marine atmosphere, or industrial atmosphere. It contains a table that indicates the material code and most generally effective surface treatment typically used to reduce corrosion of bare metals.

This article describes the four major conditions that can cause beryllium to corrode in air. These include beryllium carbide particles exposed at the surface; surface contaminated with halide, sulfate, or nitrate ions; surface contaminated with other electrolyte fluids; and atmosphere that contains halide, sulfate, or nitrate ions. The article provides information on the behavior of beryllium under the combined effects of high-purity water environment, stress and chemical environment, and high-temperature environment. The compositions of the structural grades for intentionally controlled elements and major impurities are tabulated. The article discusses the in-process problems and procedures that are common but avoidable when processing beryllium and aluminum-beryllium composites. It also describes the types of coatings used on beryllium and aluminum-beryllium. These include chemical conversion coatings, anodized coatings, plated coatings, organic coatings, and plasma-sprayed coatings.

This article focuses on the various coatings used on Department of Defense (DoD) systems. These include electroplated coatings; conversion coatings; supplemental oils, waxes, and lubricants; organic paint coatings; and other finishes such as vacuum deposits, mechanical plating, thermal spray coatings, and hot-dip coatings. The article also lists the test requirements and time to failure of the coatings.

This article provides information on the compositions of alkaline and acid baths and process parameters for zinc-iron, zinc-cobalt, zinc-nickel, and tin-zinc plating.

Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.

This article describes the protective coatings technology used in naval aircrafts. It reviews the future needs and trends of the protective coatings technology based on advancing technology, environmental concerns, and operational requirements. The article discusses the standard finishing systems for aircrafts: the surface pretreatment system, primer, topcoat, advanced-performance topcoat, self-priming topcoat, and specialty coatings. It presents safe compliant solutions to environmental problems associated with the protective coatings technology. These solutions include the use of environmental regulations and hazardous materials, nonchromated pretreatments, waterborne technology, high-solids technology, and touch-up paints. The article also deals with the use of electrodeposition coatings, powder coatings, adhesive films, paint application equipment, and non-chromated sealants in the protective coatings technology.

Zinc and zinc alloys require surface engineering prior to coating or use to improve adhesion and corrosion resistance. Die-cast zinc parts, in addition, must be trimmed and finished to remove flash and parting lines. This article covers zinc cleaning procedures as well as coating and finishing processes. It explains how to remove parting lines and presents several mechanical finishing methods, including surface polishing, brushing, controlled shot peening, and buffing. It also provides information on solvent cleaning, emulsion cleaning, aqueous detergent or alkaline cleaning), electrocleaning, acid dipping, and zinc conversion coating treatments.

Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature of cadmium plating with attention to the materials of construction and equipment used. The article provides a description of the selection of plating method with examples, applications, and several postplating processes of cadmium plating.

Although aluminum alloys are inherently corrosion resistant, there are many operating environments where they require additional protection. This article describes the conditions under which aluminum is prone to corrode and explains how to prevent it through the addition of conversion coatings and paints. It addresses some of the more common corrosion mechanisms, including corrosion driven by pH extremes, pitting corrosion, crevice corrosion, galvanic corrosion, and filiform corrosion. The article also describes in-plant as well as field application procedures for cleaning and coating, and discusses the advantages and limitations of the various materials and chemicals used.

Commercial zinc plating is accomplished by a number of distinctively different systems: cyanide baths, alkaline noncyanide baths, and acid chloride baths. This article focuses on the composition, advantages, disadvantages, operating parameters, and applications of each of the baths. It provides information on the control of thicknesses of zinc specified for service in various indoor and outdoor atmospheres and on the similarities between cadmium and zinc plating.

This article discusses the various factors that affect the corrosion performance of electroplated coatings. It describes the effects of environment and the deposition process on substrate coatings. The article provides a discussion on the electrochemical techniques capable of predicting the corrosion performance of a plated part. It reviews the designs of coating systems for optimal protection of the substrate. The article also discusses controlled weathering tests and accelerated tests used to predict and determine the relative durability of the coating.

This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.

This article addresses the general effects of the composition, mechanical treatment, surface treatment, and processing on the corrosion resistance of aluminum and aluminum alloys. There are five major alloying elements: copper, manganese, silicon, magnesium, and zinc, which significantly influence the properties of aluminum alloys. There are organic coatings or paints that provide a barrier between a corrosive environment and aluminum surface. Inorganic coatings, including claddings, and enhanced oxides, such as anodized films, Boehmite films, and conversion coatings also help in corrosion prevention. The article assists in the information on selection of fabrication operations, as they play an important role in corrosion resistance.