This article discusses the corrosion of metals and nonmetals by dry chlorine, refrigerated liquid chlorine, dry gaseous chlorine, moist chlorine, selected mixed gases with chlorine, and chlorine-water. It also provides information on the handling of commercial chlorine.

This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.

The lifetime assessment of polymeric products is complicated, and if the methodology utilized leads to inaccurate predictions, the mistakes could lead to financial loss as well as potential loss of life, depending on the service application of the product. This article provides information on the common aging mechanisms of polymeric materials and the common accelerated testing methods used to obtain relevant data that are used with the prediction models that enable service life assessment. Beginning with a discussion of what constitutes a product failure, this article then reviews four of the eight major aging mechanisms, namely environmental stress cracking, chemical degradation, creep, and fatigue, as well as the methods used in product service lifetime assessment for them. Later, several methods of service lifetime prediction that have gained industry-wide acceptance, namely the hydrostatic design basis approach, Miner's rule, the Arrhenius model, and the Paris Law for fatigue crack propagation, are discussed.

This article provides an overview of the interfacial interactions with a lubricant film between a die and a metal, lubricant mechanisms, chemistry, qualification testing, application methods, and property test methods. It focuses on sheet metal-forming operations, although the discussions are relevant to metal-forming operations in general. The article also deals with lubricant selection as influenced by the metal to be formed and particular sheet-metal forming operations. The article also discusses some aspects of microbiology and toxicity in lubricants.

The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.

This article presents a detailed examination of corrosion at the various production stages of wafer fabrication. The corrosion issues related to batch metal-etch systems and single-wafer metal-etch systems are also discussed. The article provides a case study, which illustrates that the factors outside the normal processing of wafers or tool-specific problems can contribute to metal-line corrosion.

This article describes elastomeric coatings that are suitable for painting flexible plastic substrates. It focuses on coatings systems that find utility in automotive exterior applications, where the requirements of appearance and durability are most severe. The article discusses acrylic polyols, condensation polymers, vapor curing systems, water-based coatings, and coatings for thermoplastic olefins.

Supercritical water oxidation (SCWO) is an effective process for the destruction of military and industrial wastes including wastewater sludge. This article discusses the unique properties of supercritical water and lists the main technological advantages of SCWO. For many waste streams, corrosion continues to be one of the central challenges to the full development of the SCWO technology. The article presents a summary of selected materials exposed to various environments as well as the observed form of corrosion in a table. It also illustrates the necessity to adopt a synergistic approach incorporating feed chemistry control, reactor design modifications, and intelligent materials selection, for mitigating degradation of SCWO systems.

With any polymeric material, chemical exposure may have one or more different effects. Some chemicals act as plasticizers, changing the polymer from one that is hard, stiff, and brittle to one which is softer, more flexible, and sometimes tougher. Often these chemicals can dissolve the polymer if they are present in large enough quantity and if the polymer is not crosslinked. Other chemicals can induce environmental stress cracking (ESC), an effect in which brittle fracture of a polymer will occur at a level of stress well below that required to cause failure in the absence of the ESC reagent. Finally, there are some chemicals that cause actual degradation of the polymer, breaking the macromolecular chains, reducing molecular weight, and diminishing polymer properties as a result. This article examines each of these effects. The discussion also covers the effects of surface embrittlement and temperature on polymer performance.

Cutting fluids play a major role in increasing productivity and reducing costs by making possible the use of higher cutting speeds, higher feed rates, and greater depths of cut. After listing the functions of cutting fluids, this article then covers the major types, characteristics, advantages and limitations of cutting and grinding fluids, such as cutting oils, water-miscible fluids, gaseous fluids, pastes, and solid lubricants along with their subtypes. It discusses the factors considered during the selection of cutting fluid, focusing on machinability (or grindability) of the material, compatibility (metallurgical, chemical, and human), and acceptability (fluid properties, reliability, and stability). The article also describes various application methods of cutting fluids and precautions that should be observed by the operator.

This article focuses on high-temperature corrosion in synthetic gas (syngas) coolers. Extensive laboratory corrosion studies on both model and commercial alloys are summarized. The article describes the material selection criteria for long-term performance of materials in service. It provides information on the fuels with chlorine contents used in gasification plants.

This article discusses the functions and chemistry of metal cutting or grinding fluids. It reviews the choice of cutting or grinding fluids that is influenced by the workpiece material, fluid characteristics, and machining operation. The article describes two application methods of cutting or grinding fluids: flooding and misting. It discusses and lists the American Society for Testing and Materials standard test procedures used in establishing control of cutting and grinding fluids. The article provides information on the storage, distribution, cleaning, and disposal of cutting and grinding fluids. It concludes with information on the health implications and biology of cutting fluids.

Solvent cleaning is a surface preparation process that can be accomplished in room temperature baths (cold cleaning ) or by condensing vapors of a solvent on a workpiece (vapor degreasing). This article provides a detailed discussion on solvents, equipment, process limitations and applications, and safety and health hazards of cold cleaning and vapor degreasing. It also includes information on control of contamination, conservation and recovery of solvent, and disposal of solvent wastes.