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Book Chapter
Corrosion in the Assembly of Semiconductor Integrated Circuits
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004172
EISBN: 978-1-62708-184-9
.... It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration...
Abstract
In a typical semiconductor integrated circuits (SICs) component, corrosion may be observed at the chip level and at the termination area of the lead frames that are plated with a solderable metal or alloy, such as tin and tin-lead alloys that are susceptible to corrosion. This article focuses on the key factors contributing to corrosion of electronic components, namely, chemicals (salts containing halides, sulfides, acids, and alkalis), temperature, air (polluted air), moisture, contact between dissimilar metals in a wet condition, applied potential differences, and stress. It discusses the chip corrosion and oxidation of tin and tin-lead alloys (solders) in SIC. The article also addresses the corrosion of the device terminations resulting in lead (termination) tarnishing that are caused by various factors, including galvanic corrosion, chemical residues, base metal migration and plating additives.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002438
EISBN: 978-1-62708-194-8
... and tanks Explosion, chemical residues Testing and laboratory equipment, hospital equipment, vials, bottles Radioactivity, chemical residues, medical and human wastes Gages and measuring devices Radioactivity Compressed gas cylinders Explosions, hazardous gases Turnings Oil, chemical...
Abstract
This article discusses Allenby's two streams for environmental aspects of design: generic and specific concerns. Generic concerns include guidelines that provide the structure in which specific techniques can be developed and used. Specific methods are environmentally responsible for design and specific information that engineers can use. These methods include life cycle assessment, environmental impact assessment, quality function deployment, design for “X”, failure modes and effects analysis, and design for disassembly.
Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003329
EISBN: 978-1-62708-176-4
... the stress reconstruction equations to be used for computational reconstruction of the stress fields from the measured strains for the destructive methods. It provides information on the sectioning, material removal, strain measurement, and chemical methods of residual stress measurement. The article reviews...
Abstract
This article discusses the need of and the strain basis for residual stress measurements and describes the nature of residual stress fields. A generic destructive stress relief procedure is described along with the issues generally involved in each procedural step. The article presents the stress reconstruction equations to be used for computational reconstruction of the stress fields from the measured strains for the destructive methods. It provides information on the sectioning, material removal, strain measurement, and chemical methods of residual stress measurement. The article reviews the semidestructive methods of residual stress measurement: blind hole drilling and ring coring, spot annealing, and X-ray diffraction techniques. Nondestructive methods such as neutron diffraction, ultrasonic velocity, and magnetic Barkhausen noise techniques, are also discussed.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001019
EISBN: 978-1-62708-161-0
...: compression springs (including die springs), extension springs, torsion springs, and wire forms. Chemical composition, mechanical properties, surface quality, availability, and cost are the principal factors to be considered in selecting steel for springs. Both carbon and alloy steels are used extensively...
Abstract
Steel springs are made in many types, shapes, and sizes, ranging from delicate hairsprings for instrument meters to massive buffer springs for railroad equipment. The primary focus of this article is small steel springs that are cold wound from wire. Wire springs are of four types: compression springs (including die springs), extension springs, torsion springs, and wire forms. Chemical composition, mechanical properties, surface quality, availability, and cost are the principal factors to be considered in selecting steel for springs. Both carbon and alloy steels are used extensively. The three types of wire used in the greatest number of applications of cold formed springs are hard-drawn spring wire, oil tempered wire and music wire. Residual stresses can increase or decrease the strength of a spring material, depending on their direction. Steel springs are often electroplated with zinc or cadmium to protect them from corrosion and abrasion. Although some hot-wound springs are made of steels that are also used for cold-wound springs, hot-wound springs are usually much larger, which results in significant metallurgical differences. All spring design is based on Hooke’s law; charts and formulas are available to aid in the design of springs.
Book Chapter
X-Ray Diffraction for Bulk Structural Analysis
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003251
EISBN: 978-1-62708-199-3
... inorganic chemical compounds. This article describes the operating principles and types of XRD analyses, along with information about the threshold sensitivity and precision, limitations, sample requirements, and capabilities of related techniques. The necessary instrumentation for XRD analyses include...
Abstract
X-ray diffraction (XRD) is the most extensively used method for identifying and characterizing various aspects of metals related to the arrangements and spacings of their atoms for bulk structural analysis. XRD techniques are also applicable to ceramics, geologic materials, and most inorganic chemical compounds. This article describes the operating principles and types of XRD analyses, along with information about the threshold sensitivity and precision, limitations, sample requirements, and capabilities of related techniques. The necessary instrumentation for XRD analyses include the Debye-Scherrer camera and the X-ray diffractometer. The article also describes the uses of XRD analyses, such as the identification of phases or compounds in metals and ceramics; detection of order and disorder transformation; determination of lattice parameters and changes in lattice parameters due to alloying and temperature effects; measurement of residual stresses; characterization of crystallite size and perfection; characterization of preferred orientations; and determination of single crystal orientations.
Book Chapter
Mechanical Properties of Carbon and Alloy Steels
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003093
EISBN: 978-1-62708-199-3
... Abstract The properties of carbon and alloy steels are dependent on the relationships between chemical composition, processing, and microstructure. This article discusses the effects of alloying and residual elements on the mechanical properties of carbon and alloy steels. Tables listing values...
Abstract
The properties of carbon and alloy steels are dependent on the relationships between chemical composition, processing, and microstructure. This article discusses the effects of alloying and residual elements on the mechanical properties of carbon and alloy steels. Tables listing values for the mechanical properties of selected carbon and alloy steels in the hot-rolled, normalized, annealed, and quenched-and tempered condition are provided.
Book Chapter
Brazeability and Solderability of Engineering Materials
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001492
EISBN: 978-1-62708-173-3
... Abstract This article describes the factors considered in the analysis of brazeability and solderability of engineering materials. These are the wetting and spreading behavior, joint mechanical properties, corrosion resistance, metallurgical considerations, and residual stress levels...
Abstract
This article describes the factors considered in the analysis of brazeability and solderability of engineering materials. These are the wetting and spreading behavior, joint mechanical properties, corrosion resistance, metallurgical considerations, and residual stress levels. It discusses the application of brazed and soldered joints in sophisticated mechanical assemblies, such as aerospace equipment, chemical reactors, electronic packaging, nuclear applications, and heat exchangers. The article also provides a detailed discussion on the joining process characteristics of different types of engineering materials considered in the selection of a brazing process. The engineering materials include low-carbon steels, low-alloy steels, and tool steels; cast irons; aluminum alloys; copper and copper alloys; nickel-base alloys; heat-resistant alloys; titanium and titanium alloys; refractory metals; cobalt-base alloys; and ceramic materials.
Book Chapter
Material Aspects of Additively Manufactured Orthopedic Implants of Titanium Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 23A
Publisher: ASM International
Published: 12 September 2022
DOI: 10.31399/asm.hb.v23A.a0006908
EISBN: 978-1-62708-392-8
..., printing characteristics and parameters as well as postprinting validation; removal of the many manufacturing material residues and sterilization; physical, chemical, and mechanical assessments of the final devices; and biological considerations of all the final devices including biocompatibility...
Abstract
Additive manufacturing, or three-dimensional printing technologies, for biomedical applications is rather different from other engineering components, particularly for biomedical implants that are intended to be used within the human body. This article contains two sections: "Design and Manufacturing Considerations of 3D-Printed, Commercially Pure Titanium and Titanium Alloy-Based Orthopedic Implants" and "Device Testing Considerations Following FDA Guidance" for additive-manufactured medical devices. These are further subdivided into five major focus areas: materials; design, printing, printing characteristics and parameters as well as postprinting validation; removal of the many manufacturing material residues and sterilization; physical, chemical, and mechanical assessments of the final devices; and biological considerations of all the final devices including biocompatibility.
Book Chapter
Environmental Stress Cracking
Available to PurchaseSeries: ASM Handbook
Volume: 11B
Publisher: ASM International
Published: 15 May 2022
DOI: 10.31399/asm.hb.v11B.a0006917
EISBN: 978-1-62708-395-9
... involve multiple sources, including mechanical stress, assembly stresses, or even residual stresses from molding. The chemical sits over the surface, and surface tension controls its displacement over the polymer. In reality, no surface is perfectly smooth and defect-free. As a result, the chemical...
Abstract
While there are many fracture mechanisms that can lead to the failure of a plastic component, environmental stress cracking (ESC) is recognized as one of the leading causes of plastic failure. This article focuses on unpacking the basic concepts of ESC to provide the engineer with a better understanding of how to evaluate and prevent it. It then presents factors that affect and contribute to the susceptibility of plastic to ESC: material factors, chemical factors, stress, and environmental factors. The article includes the collection of background information to understand the circumstances surrounding the failure, a fractographic evaluation to assess the cracking, and analytical testing to evaluate the material, design, manufacturing, and environmental factors.
Book Chapter
Material and Chemical Characterization as a Part of the Biological Evaluation of Medical Devices
Available to PurchaseSeries: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005686
EISBN: 978-1-62708-198-6
... of the device and possible residual process aids or additives used in its manufacture ( Ref 3 ). The identity and quantity of novel materials and chemicals present should be established or measured. Infrared (IR) analysis is used extensively to fingerprint polymeric materials and should be a part of all...
Abstract
This article provides a background to the biological evaluation of medical devices. It discusses what the ISO 10993 standards require for polymeric biomaterials and presents examples of qualitative and quantitative tests that can be used to satisfy these requirements. The article describes infrared (IR) and thermal analyses that are used extensively to fingerprint polymeric materials. It also presents a discussion on the chemical characterization and risk assessment of extracts. Background information on risk assessments of extracts is also included. The four basic steps that are commonly used in the risk assessment process are discussed. These include hazard identification, dose-response assessment, and exposure assessment, and risk characterization.
Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0003529
EISBN: 978-1-62708-180-1
... containers can contain residual chemical contaminant that could be a confusing factor in the failure analysis. For example, mold release agents in new plastic bags can be transferred to a sample and detected later by chemical surface analysis. In addition, specimens should be stored in a cool dry environment...
Abstract
This article describes some of the common elemental composition analysis methods and explains the concept of referee and economy test methods in failure analysis. It discusses different types of microchemical analyses, including backscattered electron imaging, energy-dispersive spectrometry, and wavelength-dispersive spectrometry. The article concludes with information on specimen handling.
Image
Differential interference contrast light micrograph showing recrystallized ...
Available to Purchase
in Metallography and Microstructures of Refractory Metals and Alloys
> Metallography and Microstructures
Published: 01 December 2004
Fig. 19 Differential interference contrast light micrograph showing recrystallized grains and residual chemical banding in a longitudinal section of rolled Ta-10 wt% W. Chemically polished (solution A, Table 2 ) for ∼90 s and etched (solution B, Table 2 ) for ∼60 s. Source: Ref 3
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Image
Scanning electron micrograph showing the initiation of multiple individual ...
Available to PurchasePublished: 15 May 2022
Fig. 16 Scanning electron micrograph showing the initiation of multiple individual cracks. The discrete cracks are separated by ridgelike features representing crack unions. Residual chemical is present within the crack origin zone.
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Image
The Fourier transform infrared spectra representing the fracture-surface re...
Available to PurchasePublished: 15 May 2022
Fig. 26 The Fourier transform infrared spectra representing the fracture-surface residue and the steel plate from a failed part produced an excellent match. The results were characteristic of glycol methacrylate chemical agent.
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001238
EISBN: 978-1-62708-170-2
..., and chemical etching. New techniques have also been developed for better quantification. For example, the percentage of retained austenite present at the surface of material can be measured by x-ray diffraction on the same diffractometer used for residual stress measurements. Reference 47 describes...
Abstract
The concept of surface integrity for grinding operations can be extended to encompass six different groups of key factors: visual, dimensional, residual stress, tribological, metallurgical, and others. This article discusses the importance of these factors in the performance and behavior of finishing methods in various manufactured parts. Special emphasis is given to residual stresses and their influence on the final mechanical properties of a manufactured part.
Image
Continuous cooling behavior and residual stress patterns in different diame...
Available to PurchasePublished: 09 June 2014
Fig. 8 Continuous cooling behavior and residual stress patterns in different diameter bars of an alloy steel (similar to German DIN 22CrMo44 with the chemical composition: 0.22% C, 0.65% Mn, 0.25% Si, 0.035% P, 0.035% S, 1.05% Cr, 0.45% Mo, ≤0.60% Ni)
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Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001225
EISBN: 978-1-62708-170-2
... Abstract Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal...
Abstract
Molten salt baths are anhydrous, fused chemical baths used at elevated temperatures for a variety of industrial cleaning applications. This article discusses their applications in paint stripping, polymer removal, casting cleaning, glass removal, and plasma/flame spray removal. It provides an overview of the basic design and safety considerations of the salt bath equipment and describes the environmental impact of molten salt bath cleaning.
Book Chapter
Introduction to Corrosion Resistance of Bulk Materials
Available to PurchaseSeries: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003673
EISBN: 978-1-62708-182-5
... important alloy systems. Alloying Chemical composition is a primary factor in determining corrosion behavior of metals. Alloying has been the major means used to change the properties of metals (including corrosion). Alloys with varying degrees of corrosion resistance have been developed in response...
Abstract
This article discusses factors that influence the effect of alloying, metallurgical treatments, and mechanical treatments on the corrosion resistance of metallic materials, with schematic illustrations.
Image
Residual copper layer from a UNS C71500 feedwater pressure tube that underw...
Available to PurchasePublished: 01 January 2002
Fig. 44 Residual copper layer from a UNS C71500 feedwater pressure tube that underwent denickelification. The tube was subject to 205 °C (400 °F) steam on the external surface and boiling water on the internal surface 175 °C (350 °F), at pH 8.6 to 9.2). Courtesy of James J. Dillion. Permission
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Image
Residual copper layer from a UNS C71500 feedwater pressure tube that underw...
Available to PurchasePublished: 15 January 2021
Fig. 44 Residual copper layer from a UNS C71500 feedwater pressure tube that underwent denickelification. The tube was subject to 205 °C (400 °F) steam on the external surface and 175 °C (350 °F) boiling water on the internal surface at pH 8.6 to 9.2. Courtesy of J.J. Dillion. Permission
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