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Book Chapter
Dross, Melt Loss, and Fluxing of Light Alloy Melts
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005285
EISBN: 978-1-62708-187-0
... discusses the in-furnace treatment with chemical fluxes. dross melt loss fluxing melt treating methods in-furnace treatment chemical fluxes light alloy melts dross formation furnace fluxing metal transfer economic implication in-plant enhancement DROSS, which is the oxide-rich surface...
Abstract
Dross, which is the oxide-rich surface that forms on melts due to exposure to air, is a term that is usually applied to nonferrous melts, specifically the lighter alloys such as aluminum or magnesium. This article describes dross formation and ways to reduce it, the economic implications of dross, and in-plant enhancement or recovery of dross. It discusses the influence of the melter type on dross generation and the influence of charge materials and operating practices on melt loss. Fluxing is a word applied in a broad sense to a number of melt-treating methods. The article also discusses the in-furnace treatment with chemical fluxes.
Image
Published: 01 January 1993
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001346
EISBN: 978-1-62708-173-3
... is their chemical and mechanical stability. Because the passivation layer that forms on solder is chemically weak, it can be reduced by weak fluxes. Nickel, on the other hand, forms a passivation film that is strong both chemically and mechanically. It is adherent to the base metal and requires much stronger fluxes...
Abstract
Soldering is defined as a joining process by which two substrates are bonded together using a filler metal with a liquidus temperature. This article provides an overview of fundamentals of soldering and presents guidelines for flux selection. Types of fluxes, including rosin-base fluxes, organic fluxes, inorganic fluxes, and synthetically activated fluxes, are reviewed. The article describes the joint design and precleaning and surface preparation for soldering. It addresses some general considerations in the soldering of electronic devices. Soldering process parameters, affecting wetting and spreading phenomena, such as temperature, time, vapor pressure, metallurgical and chemical nature of the surfaces, and surface geometry, are discussed. The article also describes the applications of furnace soldering, resistance soldering, infrared soldering, and ultrasonic soldering. It contains a table that lists tests commonly used to evaluate the solderability properties of selected soldered components.
Book Chapter
Nature and Behavior of Fluxes Used for Welding
Available to PurchaseSeries: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005571
EISBN: 978-1-62708-174-0
... Abstract Fluxes are added to the welding environment to improve arc stability, provide a slag, add alloying elements, and refine the weld pool. This article discusses the effect of oxygen, which is an important chemical reagent to control the weld metal composition, microstructure...
Abstract
Fluxes are added to the welding environment to improve arc stability, provide a slag, add alloying elements, and refine the weld pool. This article discusses the effect of oxygen, which is an important chemical reagent to control the weld metal composition, microstructure, and properties. It provides information on the inclusions that form as a result of reactions between metallic alloy elements and nonmetallic tramp elements, or by mechanical entrapment of nonmetallic slag or refractory particles. The article reviews the considerations of flux formulation during shielded metal arc welding and flux cored arc welding (FCAW). It describes the types of fluxes used for submerged arc welding and FCAW as well as five essential groups of flux ingredients and their interactions.
Book Chapter
Nonferrous Casting—An Introduction
Available to PurchaseBook: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005306
EISBN: 978-1-62708-187-0
... procedures and refining processes are used in the smelting and refining of primary and secondary lead production. Several of these involve chemical flux-refining techniques somewhat analogous to those used with other nonferrous metals. Figure 1 is a flow chart showing a number of important sequential...
Abstract
This article reviews the melt processing and casting of non-ferrous alloys, such as nickel alloys, titanium alloys, and lead alloys. It describes the lead refining steps, namely, copper drossing, softening, desilvering, zinc removal, bismuth removal, and final refining.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001455
EISBN: 978-1-62708-173-3
... the assembly operation. Brazing sheet is an excellent aid in assemblies where many joints need to be brazed simultaneously. Fluxes Brazing that is performed in air or other oxygen-containing atmospheres requires the use of a chemical flux. These fluxes, whether used in torch, furnace, or dip brazing...
Abstract
Aluminum, a commonly used base material for brazing, can be easily fabricated by most manufacturing methods, such as machining, forming, and stamping. This article outlines non-heat-treatable wrought alloys typically used as base metals for the brazing process. It highlights chloride-active and fluoride-active types of fluxes that are used for torch, furnace, or dip brazing processes. The article explains the steps to be performed, including the designing of joints, preblaze cleaning, assembling, brazing techniques (dip brazing, furnace and torch brazing, fluxless vacuum brazing), flux removal techniques, and postbraze heat treatment processes. It concludes with information on the safety precautions to be followed during the brazing process.
Image
Diffusive fluxes of nitrogen and carbon at the surface of the ϵ/γ′ compound...
Available to PurchasePublished: 01 August 2013
Fig. 16 Diffusive fluxes of nitrogen and carbon at the surface of the ϵ/γ′ compound layer for a nitrocarburizing time of 4 h at 550 °C (823 K) as a function of the chemical potential of carbon in the gaseous nitrocarburizing atmosphere (here represented as the carbon activity, see Sections 6
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001386
EISBN: 978-1-62708-173-3
... as the bonding material and a furnace as the heat source ( Fig. 1 ). Furnace brazing technology was initiated in the 1920s and was first used commercially circa 1930, primarily to provide a brazing process that did not require a chemical flux, thereby eliminating the flux entrapment problem. Currently, furnace...
Abstract
Furnace brazing is a mass production process for joining the components of small assemblies with a metallurgical bond, using a nonferrous filler metal as the bonding material and a furnace as the heat source. This article presents the advantages and limitations of the furnace brazing and reviews three types of furnaces: continuous, semi-continuous, and batch. It presents three examples of the industrial applications of the furnace brazing: vacuum devices, jet engines, and automotive industries. The health and safety guidelines to be followed during the furnace brazing are also discussed.
Book Chapter
Electroslag and Electrogas Welding
Available to PurchaseSeries: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005591
EISBN: 978-1-62708-174-0
..., quality control, and process applications of ESW and EGW are also discussed. aluminum carbon steel chemical reactions dissimilar metal joining electrogas welding electroslag welding flux cored arc welding gas metal arc welding heat-affected zone low-alloy steel magnetic field mechanical...
Abstract
Electroslag welding (ESW) involves high energy input relative to other welding processes, resulting generally in inferior mechanical properties and specifically in lower toughness of the heat-affected zone. Electrogas welding (EGW) is a method of gas metal or flux cored arc welding, wherein an external gas is supplied to shield the arc, and molding shoes are used to confine the molten weld metal for vertical-position welding. This article describes the fundamentals, temperature relations, consumables, metallurgical and chemical reactions, and process development of ESW. The problems, quality control, and process applications of ESW and EGW are also discussed.
Book Chapter
Ion-Beam-Assisted Deposition
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001290
EISBN: 978-1-62708-170-2
... of the ion beam. In plasma-based techniques, there is a larger spread of energies of the energetic flux components, with unknown ratios of the ion to thermal atom flux. The independent control of these parameters is more limited. Physical and Chemical Aspects The physical processes that occur...
Abstract
Ion-beam-assisted deposition (IBAD) refers to the process wherein evaporated atoms produced by physical vapor deposition are simultaneously struck by an independently generated flux of ions. This article discusses the energy utilization of this process. It describes the physical and chemical processes occurring at the film-vacuum interface during IBAD and dual-ion-beam sputtering with illustrations. The article also reviews the methods used for large-area, high-volume implementation of IBAD and the modes of film formation for IBAD. It contains a table that presents information on deposition and synthesis of inorganic compounds by IBAD and concludes with a discussion on the improved coating properties, advantages, limitations, and applications of IBAD.
Book Chapter
Surface Preparation for Continuously Applied Coatings
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001269
EISBN: 978-1-62708-170-2
...-atmosphere techniques, such as Sendzimir oxidation/reduction method; other specialized methods, namely, fluxes, mechanical cleaning, and ultrasonic methods; or a combination of these. alkaline cleaning chemical pickling contaminant removal continuously applied coatings electrolytic cleaning...
Abstract
This article focuses on the various techniques for removing contaminants in the surface preparation of steel for hot-dip coatings: wet cleaning methods, including alkaline cleaning, electrolytic cleaning, chemical pickling, and electrolytic pickling; flame cleaning and furnace-atmosphere techniques, such as Sendzimir oxidation/reduction method; other specialized methods, namely, fluxes, mechanical cleaning, and ultrasonic methods; or a combination of these.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001273
EISBN: 978-1-62708-170-2
... casting cleaning fluxing metal spray babbitting sliding shaft soft metals static babbitting stiffener tinning workpiece preparation BABBITTING is a process by which relatively soft metals are bonded chemically or mechanically to a stronger shell or stiffener, which supports the weight...
Abstract
Babbitting is a process by which relatively soft metals are bonded chemically or mechanically to a stronger shell or stiffener which supports the weight and torsion of a rotating, oscillating, or sliding shaft. This article focuses on workpiece preparation and babbitting methods. Prior to casting, the workpiece must be scrupulously prepared by various cleaning, fluxing, and tinning steps. Babbitting of bearing shells can be accomplished by three methods, namely, static babbitting, centrifugal casting, and metal spray babbitting.
Book Chapter
Nature and Behavior of Fluxes Used for Welding
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001339
EISBN: 978-1-62708-173-3
... been used to make equilibrium calculations and thus achieve a better understanding of the chemical reactions involved in welding ( Ref 8 ). Investigators have also quantified elemental transfer by measuring similar neutral points (null delta quantity) for various flux systems and have developed...
Abstract
Fluxes are added to the welding environment to improve arc stability, to provide a slag, to add alloying elements, and to refine the weld pool. This article describes the effect of oxygen that directly reacts with alloying elements to alter their effective role by reducing hardenability, promoting porosity, and producing inclusions. It proposes basicity index for welding as a measure of expected weld metal cleanliness and mechanical properties. The article discusses alloy modification in terms of slipping and binding agents, slag formation, and slag detachability. It reviews the types of fluxes for different arc welding processes, such as shielded metal arc welding (SMAW), flux-cored arc welding (FCAW), and submerged arc welding (SAW).
Book Chapter
Melting and Melt Treatment of Aluminum Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006535
EISBN: 978-1-62708-207-5
...,</xref><xref rid="a0006535-ref4" ref-type="bibr">4)</xref> Fluxing is a term commonly used in foundries, especially within the melting department workforce, to refer only to the addition of inorganic chemical compounds to clean molten aluminum alloy baths in either the furnaces (melting or holding) or the transfer ladles. Fluxing...
Abstract
There are a wide variety of furnace types and designs for melting aluminum. This article discusses the various types of furnaces, including gas reverberatory furnaces, crucible furnaces, and induction melting furnaces. It describes the classification of solid fluxes: cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article reviews the basic considerations in proper flux selection and fluxing practices. It explains the basic principles of degassing and discusses the degassing of wrought aluminum alloys. The article describes filtration in wrought aluminum production and in shape casting. It also reviews grain refinement in aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article concludes with a discussion on aluminum-silicon modification.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006529
EISBN: 978-1-62708-207-5
... of chemical additives (i.e., fluxes). The chemical reaction between the oxide layer and the flux disrupts the micron/submicron layer of aluminum oxide formed on the aluminum mating surfaces. Moreover, flux prevents the oxide from redeveloping on aluminum during heating and molten metal pool formation without...
Abstract
Brazing technology is continually advancing for a variety of metals including aluminum and its alloys and nonmetals. This article discusses the key physical phenomena in aluminum brazing and the materials for aluminum brazing, including base metals, filler metals, brazing sheet, and brazing flux. It describes various aluminum brazing methods, such as furnace, vacuum, dip, and torch brazing. Friction, flow, induction, resistance, and diffusion brazing are some alternate brazing methods discussed. The article reviews the brazing of aluminum to ferrous alloys, aluminum to copper, and aluminum to other nonferrous metals. It also discusses post-braze processes in terms of post-braze heat treatment and finishing. The article concludes with information on the safety precautions considered in brazing aluminum alloys.
Book Chapter
Brazing
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003210
EISBN: 978-1-62708-199-3
... be molten brazing filler metal, molten chemical flux, or molten chemical salts. The dip brazing method generally causes less distortion than torch brazing, because of its uniform heating. However, it may require relatively complex tooling and is therefore best used in medium- to high-production runs...
Abstract
This article provides information about the selection of brazing processes and filler metals and describes the brazing (heating) methods, including manual torch brazing, furnace brazing, induction brazing, dip brazing, resistance brazing and specialized brazing processes such as diffusion and exothermic brazing. The article explains joint design, filler materials, fuel gases, equipment, and fluxes in the brazing methods. The article also describes the brazing of steels, stainless steels, cast irons, heat-resistant alloys, aluminum alloys, copper and copper alloys, and titanium and titanium alloys.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005300
EISBN: 978-1-62708-187-0
... Castings” in this Volume) Aluminum Fluxing Fluxing is a term commonly used in foundries, especially within the melting department work force, to refer only to the addition of chemical compounds to clean molten aluminum alloy baths in either the furnaces (melting or holding) or the transfer...
Abstract
Aluminum fluxing is a step in obtaining clean molten metal by preventing excessive oxide formation, removing nonmetallic inclusions from the melt, and preventing and/or removing oxide buildup on furnace walls. This article discusses the solid fluxes and gas fluxes used in foundries. It reviews the classification of solid fluxes depending on their use and function at the foundry operation. These include cover fluxes, drossing fluxes, cleaning fluxes, and furnace wall cleaner fluxes. The article also examines the operational practices and applications of the flux injection in the foundries. It describes the applications of the aluminum fluxing such as crucible furnaces, transfer ladles, reverberatory furnaces, and holding/casting furnaces.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001355
EISBN: 978-1-62708-173-3
... to weld carbon, low-alloy steel, and stainless steels in the construction of pressure vessels and piping for the chemical processing, petroleum refining, and power-generation industries. In addition, flux-cored electrodes are used to weld some nickel-base alloys. Flux-cored electrodes are also used...
Abstract
In the flux-cored arc welding (FCAW) process, the heat for welding is produced by an electric arc between a continuous filler metal electrode and a workpiece. This article discusses the advantages and disadvantages and applications of the FCAW process. It schematically illustrates the semiautomatic FCAW equipment used in the gas-shielded FCAW process. The article discusses the manufacture of flux-cored electrodes and the classification of electrodes, such as carbon and low-alloy steel electrodes, stainless steel electrodes, and nickel-base electrodes. The functions of common core ingredients in FCAW electrodes are listed in a table.
Book Chapter
Soldering
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003211
EISBN: 978-1-62708-199-3
... be a selection factor. Both flux selection and surface preparation will be affected by the solderability of the base materials to be joined. The solderability of metals and alloys is not simply a matter of chemical nobility, as might be supposed when regarding the good solderability of the noble metals...
Abstract
Soldering involves heating a joint to a suitable temperature and using a filler metal (solder) that melts below 450 deg C (840 deg F). Beginning with an overview of the specification and standards and applications, this article discusses the principal levels and effects of the most common impurity elements in tin-lead solders. It describes the various processes involved in the successful soldering of joints, including shaping the parts to fit closely together; cleaning and preparing the surfaces to be joined; applying a flux; assembling the parts; and applying the heat and solder.
Book Chapter
Brazeability and Solderability of Engineering Materials
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001492
EISBN: 978-1-62708-173-3
... considerations: Joining process characteristics (type and characteristics of heat source) Chemical composition of base metal Cleaning preparation and after-process cleaning Chemical composition of filler metal Joint protection against oxidation (flux, bath composition, protective atmospheres...
Abstract
This article describes the factors considered in the analysis of brazeability and solderability of engineering materials. These are the wetting and spreading behavior, joint mechanical properties, corrosion resistance, metallurgical considerations, and residual stress levels. It discusses the application of brazed and soldered joints in sophisticated mechanical assemblies, such as aerospace equipment, chemical reactors, electronic packaging, nuclear applications, and heat exchangers. The article also provides a detailed discussion on the joining process characteristics of different types of engineering materials considered in the selection of a brazing process. The engineering materials include low-carbon steels, low-alloy steels, and tool steels; cast irons; aluminum alloys; copper and copper alloys; nickel-base alloys; heat-resistant alloys; titanium and titanium alloys; refractory metals; cobalt-base alloys; and ceramic materials.
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