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Published: 01 December 2004
Fig. 13 Outlining of grains using chemical etching. Etchant: modified Poulton reagent (60% HCl, 30% HNO 3 5% HF, 5% H 2 O)
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Published: 01 December 2004
Fig. 10 After chemical etching, another phase can be observed in the matrix. (a) Reflected light, phase contrast, 25× objective. (b) Reflected light, phase contrast, 50× objective
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Image
Published: 15 June 2020
Fig. 30 Effect of ultrasonic agitation on material removal rate in chemical etching of SLM Ti6Al4V. Source: Ref 28
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in Preparation and Microstructural Analysis of High-Performance Ceramics
> Metallography and Microstructures
Published: 01 December 2004
Fig. 15 Light micrograph of the same sample shown in Fig. 14 but chemically etched in phosphoric acid at 270 °C (520 °F) for 3 min. The spinel phase is dissolved, and grain boundaries look broader.
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in Preparation and Microstructural Analysis of High-Performance Ceramics
> Metallography and Microstructures
Published: 01 December 2004
Fig. 18 Light micrograph of a chemically etched surface of a BaTiO 3 ceramic showing the grains and domain patterns within the grains
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Published: 15 June 2020
Fig. 29 Surface of chemically etched SLM Ti6Al4V with smoothed out rough surface and partially welded powder particles: (a) before etching and (b) after etching. Source: Ref 28
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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006489
EISBN: 978-1-62708-207-5
... Abstract Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline...
Abstract
Etching aluminum can be a pretreatment step for anodizing, chemical conversion coating, metal-to-rubber bonding, and a host of other processes. Chemical etching, using either alkaline or acid solutions, produces a matte finish on aluminum products. This article describes the alkaline etching and acid etching of aluminum. Alkaline etching reduces or eliminates surface scratches, nicks, extrusion die lines, and other imperfections. Acid etching can be done without heavy smut problems, particularly on aluminum die castings. Hydrochloric, hydrofluoric, nitric, phosphoric, chromic, and sulfuric acids are used in acid etching. The article presents a flow chart of the operations used in acid etching.
Book Chapter
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
..., and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating...
Abstract
Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003752
EISBN: 978-1-62708-177-1
... formation and interference techniques such as anodizing, chemical etching, and tint etching. It provides a description of reagents that deposit sulfide films and molybdate films. The article concludes with a discussion on the thermal and vapor deposition methods to produce color. anodizing chemical...
Abstract
This article is a compilation of color etchants that have been developed for a limited number of metals and alloys. It describes the optical methods for producing color, such as polarized light and differential interference contrast, with illustrations. The article discusses film formation and interference techniques such as anodizing, chemical etching, and tint etching. It provides a description of reagents that deposit sulfide films and molybdate films. The article concludes with a discussion on the thermal and vapor deposition methods to produce color.
Book Chapter
Series: ASM Handbook
Volume: 13A
Publisher: ASM International
Published: 01 January 2003
DOI: 10.31399/asm.hb.v13a.a0003600
EISBN: 978-1-62708-182-5
... current potentiodynamic polarization and alternating current impedance measurements. It concludes with information on chemically induced defects such as pitting corrosion, galvanic corrosion, and chemical etching. chemical-mechanical planarization mechanically accelerated corrosion erosion...
Abstract
Chemical-mechanical planarization (CMP) of metals is described as mechanically accelerated corrosion, erosion corrosion, or metallic corrosion enhanced by wear. This article reviews the history, process, chemistry, electrochemistry, and defect issues for CMP. It provides an overview of CMP through a schematic illustration of CMP process equipment. The applications of CMP to tungsten and copper alloys are of prime interest in the semiconductor industry. The article discusses copper CMP and tungsten CMP in detail and analyzes polishing mechanism during CMP by application of direct current potentiodynamic polarization and alternating current impedance measurements. It concludes with information on chemically induced defects such as pitting corrosion, galvanic corrosion, and chemical etching.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006116
EISBN: 978-1-62708-175-7
... on carefully prepared planar (two-dimensional) surfaces. This article discusses the preparation sequence of ferrous powders, which is normally separated into several well-defined steps: sample selection, sectioning, mounting, grinding, polishing, drying, and chemical etching and/or coating. It provides several...
Abstract
Metallographic analysis is primarily a collection of visual and imaging techniques that provide an insight into the background of a material or part and its behavior. Metallic specimens, both porous and pore-free, are opaque, and as a result, an optical examination must be performed on carefully prepared planar (two-dimensional) surfaces. This article discusses the preparation sequence of ferrous powders, which is normally separated into several well-defined steps: sample selection, sectioning, mounting, grinding, polishing, drying, and chemical etching and/or coating. It provides several suggestions to promote and encourage the safety of those performing metallographic preparation and analysis.
Book: Fractography
Series: ASM Handbook Archive
Volume: 12
Publisher: ASM International
Published: 01 January 1987
DOI: 10.31399/asm.hb.v12.a0001832
EISBN: 978-1-62708-181-8
... stripping, organic-solvent cleaning, water-base detergent cleaning, cathodic cleaning, and chemical-etch cleaning. cleaning cracks fractography nondestructive inspection specimen preparation specimen preservation specimen sectioning steel fracture FRACTURE SURFACES are fragile and subject...
Abstract
Fracture surfaces are fragile and subject to mechanical and environmental damage that can destroy microstructural features. This article discusses the importance of care and handling of fractures and the factors that need to be considered during the preliminary visual examination. It describes the procedures for sectioning a fracture and opening secondary cracks as well as the effect of nondestructive inspection on subsequent evaluation. The article provides information on the most common techniques for cleaning fracture surfaces. These techniques are dry air blast cleaning, replica stripping, organic-solvent cleaning, water-base detergent cleaning, cathodic cleaning, and chemical-etch cleaning.
Image
Published: 01 February 2024
Fig. 40 (a) Representative view of the chemical segregation (banding). Etched with 2% nital. Original magnification: 50×. (b) Higher magnification of the microstructure showing tempered martensite and bainite. Etched with 2% nital. Original magnification: 400×
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Book Chapter
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003749
EISBN: 978-1-62708-177-1
..., macroetching, electropolishing, chemical polishing, and other similar operations. anodizing chemical polishing color etching contrast enhancement electropolishing film deposition film formation heat tinting light microscopy macroetching microetching potentiostatic etching safety precautions...
Abstract
Metallographic contrasting methods include various electrochemical, optical, and physical etching techniques, which in turn are enhanced by the formation of a thin transparent film on the specimen surface. This article primarily discusses etching in conjunction with light microscopy and describes several methods for film formation, namely, heat tinting, color etching, anodizing, potentiostatic etching, vapor deposition, and film deposition by sputtering. It provides information on the general procedures and precautions for etchants and reagents used in metallographic microetching, macroetching, electropolishing, chemical polishing, and other similar operations.
Image
Published: 15 January 2021
Fig. 32 (a) Lighter and darker etching areas of 4340 alloy steel show nonuniform distribution of alloying elements. Nital etch. (b) Chemically etched 304 stainless steel shows wavy alloy segregation. Marble’s etch
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Image
Published: 01 June 2024
aircraft. (a) Etch pit with ion vapor deposition (IVD) layer. (b) Inclusion. (c) Corrosion. The etch pit was caused by chemical etching before applying an IVD aluminum coating for corrosion protection. This coating filled the etch pit. All the fractographs are from in-service FCG followed by testing using
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Image
Published: 01 December 2004
Fig. 1 Corroded Pb-3Sb battery grid. To preserve oxides and sulfate layers, the grid was embedded in resin prior to polishing. Classical etching would reveal the metal structure but destroy corrosion. A very long final mechanical polish, with 0.05 μm alumina and chemical etching for just 1 s
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Image
in Preparation and Microstructural Analysis of High-Performance Ceramics
> Metallography and Microstructures
Published: 01 December 2004
Fig. 20 Scanning electron micrograph of a lanthanum-doped PZT ceramic. The grain boundaries as well as the domain structure are visible after chemical etching.
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Image
Published: 30 September 2015
Fig. 6 Graphic illustrating the phase composition of a typical LPS WHA. Phase contrast provided by relief polishing and selective focus in brightfield, eliminating the need for chemical etching
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Image
Published: 01 June 2024
Fig. 6 Effect of increasing the ultrasonic cleaning time in a heated Alconox solution. (a) 30 min. (b) 3.5 h. Note the dislodging of the inclusion (left side of fractograph) and chemical etching of the fracture surface.
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