Tungsten, molybdenum, and cemented carbide parts can be produced using several additive manufacturing technologies. This article classifies the most relevant technologies into two groups based on the raw materials used: powder-bed methods, such as selective laser melting, electron beam melting, and binder jet three-dimensional (3-D) printing, and feedstock methods, such as fused-filament fabrication and thermoplastic 3-D printing. It discusses the characteristics, processing steps, properties, advantages, limitations, and applications of these technologies.

Cemented carbides, best known for their superior wear resistance, have a range of industrial uses more diverse than that of any other powder metallurgy product including metalworking and mining tools and wear-resistant components. This article discusses raw materials and manufacturing methods used in the production of cemented carbides, the physical and mechanical properties of carbides, and wear mechanisms encountered in service. Emphasis is placed on tungsten carbide-cobalt (WC-Co) or tungsten carbide-nickel (WC-Ni) materials as used in nonmachining applications. Nominal composition and properties of representative cemented carbide grades and their applications are listed in a table.

Cemented carbide is, in its simplest form, a metal-matrix composite of tungsten carbide particles in a cobalt matrix. This article describes the microstructure, physical, and mechanical properties of cemented carbides. The properties discussed include thermal conductivity, magnetic properties, corrosion resistance, hardness, fracture toughness, wear resistance, and thermal shock resistance. The article concludes with information on the applications, grade classification, and selection of grades.

Cemented carbides are extremely important in corrosion conditions in which high hardness, wear resistance, or abrasion resistance is required. This article describes the effect of binder composition and carbide addition on corrosion behavior of cemented carbides. It lists the examples of their uses in corrosion applications. The article provides information on the selection of cemented carbides for corrosion applications and tabulates the corrosion resistance of cemented carbides in various media. It expounds the oxidation resistance of cemented carbides and presents some tips to improve the properties of tungsten carbide cutting tools. The article also details the coating materials and coating processes of cemented carbides.

Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.

Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a soft and ductile metal binder. The performance of cemented carbide as a cutting tool lies between that of tool steel and cermets. Almost 50% of the total production of cemented carbides is used for nonmetal cutting applications. Their properties also make them appropriate materials for structural components, including plungers, boring bars, powder compacting dies and punches, high-pressure dies and punches, and pulverizing hammers. This article discusses the manufacture, microstructure, composition, classifications, and physical and mechanical properties of cemented carbides, as well as their machining and nonmachining applications. It examines the relationship between the workpiece material, cutting tool and operational parameters, and provides suggestions to simplify the choice of cutting tool for a given machining application. It also examines new tool geometries, tailored substrates, and the application of thin, hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. It discusses the tool wear mechanisms and the methods available for holding the carbide tool. The article is limited to tungsten carbide cobalt-base materials.

This article discusses the manufacturing steps and compositions of cemented carbides, as well as their microstructure, classifications, applications, and physical and mechanical properties. It provides information on new tool geometries, tailored substrates, and the application of thin and hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. The article also discusses tool wear mechanisms and the methods available for holding the carbide tool.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of one specific type of cemented carbide, tungsten carbide. It also assists in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the brittle fracture, transgranular fracture, intergranular fracture, and crack propagation of the tungsten carbide.

This article contains tables that list standard reduction potentials for electrochemical reactions. The first table lists reactions alphabetically by element of interest. The second table is ranked by potential value. Potential is measured versus the Standard Hydrogen Electrode which has a value of 0.0000 V. Reactions with more than one voltage indicate that results have not been reconciled. Parenthetical materials not needed to balance reactions are catalysts.

This article describes the secondary operations for cemented carbide parts, namely, diamond grinding, honing, electrical discharge machining, and brazing after sintering to achieve desired results, such as specified size, shape, edge condition, and surface finish.

Quality control of cemented carbides includes the evaluation of physical and chemical properties of constituent raw material powders, powder blends/formulations, green compacts, and fully dense finished product. This article provides a summary of the underlying principles and size ranges for the American Society for Testing and Materials (ASTM) standard methods of particle sizing and distribution. It presents the methods used to analyze the chemical composition of cemented carbide materials in a tabular form. The article also presents information on microstructural evaluation and physical and mechanical property evaluation of cemented carbides.

This article provides a brief introduction to abrasive wear-resistant coating materials that contain a large amount of hard phases, such as borides, carbides, or carboborides. It describes some of the commonly used methods of producing thick wear-resistant coatings. The article also provides information on metal-matrix composites and cemented carbides. The three base-alloying concepts, including cobalt-, iron-, and nickel-base alloys used for wear-protection applications, are also described. The article compares the tribomechanical properties of the materials in a qualitative manner, thus allowing a rough materials selection for practitioners. It presents a brief discussion on hot isostatic pressing (HIP) cladding, sinter cladding, and manufacturing of thick wear-resistant coatings by extrusion or ring rolling. The article also discusses the processing sequence of thick wear-resistant coatings, namely, compound casting, deposition welding, and thermal spraying.

Cermets are a group of powder metallurgy products consisting of ceramic particles bonded with a metal. This article describes the composition and microstructure of titanium carbide and titanium carbonitride cermets. It tabulates typical properties of titanium carbonitride cermets and compares the properties of cermets and cemented carbides. The article also summarizes the applications of cermet cutting tools.

Hardness conversions are empirical relationships that are defined by conversion tables limited to specific categories of materials. This article tabulates examples of the published hardness conversion equations for various materials including steels, cement carbides, and white cast irons. It informs that when making hardness correlations, it is best to consult ASTM E 140. The article tabulates the approximate Rockwell B hardness and Rockwell C hardness conversion numbers for nonaustenitic steels according to ASTM E 140. It also tabulates the approximate equivalent hardness numbers for Brinell hardness numbers and Vickers (diamond pyramid) hardness numbers for steel.

Selecting the proper cutting tool material for a specific machining application can provide substantial advantages, including increased productivity, improved quality, and reduced costs. This article begins with a description of the factors affecting the selection of a cutting tool material. This is followed by a schematic representation of their relative application ranges in terms of machining speeds and feed rates. The article provides a detailed account of chemical compositions of various tool materials, including high-speed tool steels, cobalt-base alloys, cemented carbides, cermets, ceramics, cubic boron nitride, and polycrystalline diamond. It compares the toughness, and wear resistance for these cutting tool materials. Finally, the article explains the steps for selecting tool material grades for specific application.

The selection of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This article classifies various engineered materials, including ferrous alloys, nonferrous alloys, ceramics, cermets and cemented carbides, engineering plastics, polymer-matrix composites, metal-matrix composites, ceramic-matrix and carbon-carbon composites, and reviews their general property characteristics and applications. It describes the synergy between the elements of the materials selection process and presents a general comparison of material properties. Finally, the article provides a short note on computer aided materials selection systems, which help in proper archiving of materials selection decisions for future reference.

A sliding bearing (plain bearing) is a machine element designed to transmit loads or reaction forces to a shaft that rotates relative to the bearing. This article explains the role of wear damage mechanisms in the design and selection of bearing materials, and its relationship with bearing material properties. Sliding bearings are commonly classified by terms that describe their application; they also are classified according to material construction, as single-metal, bimetal, or trimetal sliding bearings. The article further provides detailed tabular data on the designation and composition of the following types of bearing materials: tin-base alloys, lead-base alloys, copper-base alloys, and aluminum-base alloys. It also briefly discusses the following types of bearing materials: zinc-base alloys, silver-base alloys, gray cast irons, cemented carbides, and nonmetallic bearing materials.

Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.

The classes of tool materials for machining operations are high-speed tool steels, carbides, cermets, ceramics, polycrystalline cubic boron nitrides, and polycrystalline diamonds. This article discusses the expanding role of surface engineering in increasing the manufacturing productivity of carbide, cermet, and ceramic cutting tool materials used in machining operations. The useful life of cutting tools may be limited by a variety of wear processes, such as crater wear, flank wear or abrasive wear, builtup edge, depth-of-cut notching, and thermal cracks. The article provides information on the applicable methods for surface engineering of cutting tools, namely, chemical vapor deposited (CVD) coatings, physical vapor deposited coatings, plasma-assisted CVD coatings, diamond coatings, and ion implantation.

This article discusses two major sintering methods: pressureless and pressure-assisted sintering. Pressureless sintering techniques include vacuum and partial-pressure, hydrogen, and microwave sintering. Pressure-assisted consolidation techniques include overpressure sintering, sintering followed by postsinter hot isostatic pressing, hot pressing, and several rapid hot consolidation techniques. The article describes nitrogen sintering and the sintering of cermets. It reviews the furnaces used for sintering and presents the lubrication removal techniques. The article also outlines the need to control carbon and oxygen to obtain optimal properties and explains microstructure development and grain size control.