True alkaline chemicals include caustic soda or sodium hydroxide (NaOH), caustic potash or potassium hydroxide (KOH), and soda ash or sodium carbonate (Na2CO3). This article reviews alkaline chemicals and provides a basis for a general discussion on various alkaline exposures. It describes the corrosion effects of caustic soda on aluminum and aluminum alloys, iron and steel, carbon and low-alloy steels, stainless steels, high-performance austenitic alloys, nickel and nickel alloys, copper and copper alloys, titanium and titanium alloys, and zirconium and zirconium alloys. The article discusses the corrosion effects of caustic soda on nonmetallic materials: plastics, thermoplastics, thermosetting resin materials, carbon and graphite, and ceramics. It concludes with information on the effects of contamination of and by caustic and of admixtures of caustic with other chemicals, including chlorates, chlorides, chlorine/hypochlorite, mercury, sulfur, and iron.

This article reviews the melt processing and casting of non-ferrous alloys, such as nickel alloys, titanium alloys, and lead alloys. It describes the lead refining steps, namely, copper drossing, softening, desilvering, zinc removal, bismuth removal, and final refining.

Nonferrous metals and alloys are widely used to resist corrosion. This article describes the corrosion behavior of the most widely used nonferrous metals, such as aluminum, copper, nickel, and titanium. It also provides information on several specialty nonferrous products that cannot easily be categorized by elemental base.

This article describes the formation of residual stresses and distortion, providing information on the techniques for measuring residual stresses. It presents a detailed discussion on the magnitude and distribution analysis of the residual stresses and distortion in weldments. The article briefly explains the effects of residual stresses and distortion on the brittle fracture and fatigue fracture of welded structures. It also provides information on the thermal treatments of weldments.

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.

This article describes the formation of residual stresses and distortion and the techniques for measuring residual stresses. It provides a discussion on the magnitude and distribution analysis of residual stresses and distortion in weldments. The article considers the effects of residual stresses and distortion on the brittle fracture and fatigue fracture of welded structures. The thermal treatments of weldments are also discussed.

This article focuses on the use of indium and bismuth in low-melting-temperature solders and fusible alloys. It describes how the two elements typically occur in nature and how they are recovered and processed for commercial use. It also provides information on designations, classification, composition, properties (including temperatures ranges), and some of the other ways in which indium and bismuth alloys are used.

Stress-corrosion cracking (SCC) is a form of corrosion and produces wastage in that the stress-corrosion cracks penetrate the cross-sectional thickness of a component over time and deteriorate its mechanical strength. Although there are factors common among the different forms of environmentally induced cracking, this article deals only with SCC of metallic components. It begins by presenting terminology and background of SCC. Then, the general characteristics of SCC and the development of conditions for SCC as well as the stages of SCC are covered. The article provides a brief overview of proposed SCC propagation mechanisms. It discusses the processes involved in diagnosing SCC and the prevention and mitigation of SCC. Several engineering alloys are discussed with respect to their susceptibility to SCC. This includes a description of some of the environmental and metallurgical conditions commonly associated with the development of SCC, although not all, and numerous case studies.

Nickel-base alloy castings are widely used in corrosive-media and high-temperature applications. This article begins with a discussion on the compositions of corrosion-resistant nickel-base casting alloys and heat-resistant nickel-base casting alloys. It describes the effects of aluminum and titanium on the structure and properties of nickel-base alloys. The article provides information on the melting, foundry, and pouring practices for nickel-base alloys. It explains the welding and heat treatment of the nickel-base casting alloys. The article concludes with an overview of the numerous applications of cast heat-resistant nickel-base alloys.

Carbon steels have wider usage than any other metal because of their versatility and low cost. Required hardenability is the most important factor influencing a choice between carbon- and alloy steel. By increasing hardenability, alloying elements extend the potential for enhanced properties to the large sections required for many applications. Alloy steels are ordinarily quench hardened and tempered to the level of strength desired for the application. Distortion during heat treatment may occur with almost any hardenable carbon or alloy steel, although distortion is usually more severe for carbon grades than for alloy grades of equivalent carbon content. The relatively low hardenability of carbon steels is a primary reason for choosing them in preference to alloy steels for parts that are to be locally heat treated by flame or induction hardening. Fabrication processes are performed on hardenable carbon and alloy steels in the unhardened condition, that is, prior to heat treating.

This article discusses pressure vessels, piping, and associated pressure-boundary items of the types used in nuclear and conventional power plants, refineries, and chemical-processing plants. It begins by explaining the necessity of conducting a failure analysis, followed by the objectives of a failure analysis. Then, the article discusses the processes involved in failure analysis, including codes and standards. Next, fabrication flaws that can develop into failures of in-service pressure vessels and piping are covered. This is followed by sections discussing in-service mechanical and metallurgical failures, environment-assisted cracking failures, and other damage mechanisms that induce cracking failures. Finally, the article provides information on inspection practices.