Nickel and nickel-base alloys are vitally important to modern industry because of their ability to withstand a wide variety of severe operating conditions involving corrosive environments, high temperatures, high stresses, and combinations of these factors. This article discusses the mining and extraction of nickel and describes the uses of nickel. It discusses the categories of nickel-base alloys, including wrought corrosion-resistant alloys, cast corrosion-resistant alloys, heat-resistant alloys (superalloys), and special-purpose alloys. The article covers the corrosion resistance of nickel with the inclusion of varying alloying elements. It provides useful information on the behavior of nickel and nickel alloys in specific environments describes its corrosion resistance in certain acids, alkalis, and salts.

This article provides a detailed discussion on the most commonly employed tests and specific examples of the use of these tests in evaluating the corrosion resistance of powder metallurgy (P/M) stainless steels. It describes the influence of various processing parameters on the corrosion resistance of P/M stainless steels. The approaches used to improve the corrosion resistance of sintered stainless steels are discussed briefly. The article also presents a discussion on the manufacturing and corrosion characteristics of P/M superalloys.

Cast nickel-base alloys are used extensively in corrosive-media and high-temperature applications. This article briefly reviews the common types of heat treatments of nickel alloy castings: homogenization, stress relieving, in-process annealing, full annealing, solution annealing, quenching, coating diffusion, and precipitation. It describes the three general strengthening mechanisms, namely, solid-solution hardening, age hardening, and carbide precipitation. The article summarizes the typical heat treatment of the general families of nickel-base castings used in industrial applications. It focuses on the solution treatment and age hardening of cast nickel-base superalloys and the heat treatment of cast solid-solution alloys for corrosion-resisting applications. The article also discusses the typical types of atmospheres used in annealing or solution treating: exothermic, endothermic, dry hydrogen, dry argon, and vacuum.

Aluminum alloys are primarily used for nonferrous castings because of their light weight and corrosion resistance. This article discusses at length the melting and metal treatment, structure control, sand casting, permanent mold casting, and die casting of aluminum alloys. It also covers the types and melting and casting practices of copper alloys, zinc alloys, magnesium alloys, titanium alloys, and superalloys, and provides a brief account on the casting technique of metal-matrix composites.

Grain refinement in aluminum casting alloys tends to reduce the amount of porosity and the size of the pores and to improve mechanical properties, especially fatigue strength. This article provides information on measurement of grain size in alloys and describes the mechanisms of grain refinement in aluminum casting alloys. It reviews the use of boron and titanium as a grain refiner for aluminum casting alloys. The article discusses the best practices for grain refinement in various aluminum casting alloys. These include aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-silicon-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article also discusses benefits of grain refinement in aluminum casting alloys.

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

This article describes the control of alloy composition and impurity levels in die casting of zinc alloys based on agitation, use of foundry scrap, and melt temperature and fluxing. It reviews the process considerations for the melt processing of the zinc alloys. The process considerations include the usage of furnaces and launder system, scrap return, inclusions in zinc alloys, fluxing of zinc alloys, and galvanizing fluxes. The article discusses the materials and lubricant selection, casting and die temperature control, and trimming process used in hot chamber die casting for zinc alloys. It also reviews other casting processes for zinc alloys, such as sand casting, permanent mold casting, plaster mold casting, squeeze casting, and semisolid casting.

This article discusses the five basic matrix structures in cast irons: ferrite, pearlite, bainite, martensite, and austenite. The alloying elements, used to enhance the corrosion resistance of cast irons, including silicon, nickel, chromium, copper, molybdenum, vanadium, and titanium, are reviewed. The article provides information on classes of the cast irons based on corrosion resistance. It describes the various forms of corrosion in cast irons, including graphitic corrosion, fretting corrosion, pitting and crevice corrosion, intergranular attack, erosion-corrosion, microbiologically induced corrosion, and stress-corrosion cracking. The cast irons suitable for the common corrosive environments are also discussed. The article reviews the coatings used on cast irons to enhance corrosion resistance, such as metallic, organic, conversion, and enamel coatings. It explains the basic parameters to be considered before selecting the cast irons for corrosion services.

Cast stainless steels are usually specified on the basis of composition by using the alloy designation system established by the Alloy Casting Institute. This article discusses the corrosion behavior of heat-resistant alloys due to oxidation, sulfidation, and carburization. It describes the influence of the metallurgy of corrosion-resistant stainless steels on general corrosion, intergranular corrosion, localized corrosion, corrosion fatigue, and stress corrosion.

This article focuses on the variety of alloys, furnaces, and associated melting equipment and on the casting methods available for manufacturing magnesium castings. The casting methods include sand casting, permanent mold casting, die casting, thixomolding, and direct chill casting. The article discusses the flux process and fluxless process for the melting and pouring of magnesium alloys. It describes the advantages and disadvantages of green sand molding and tabulates typical compositions and properties of magnesium molding sands. The article provides information on the machining characteristics of magnesium and the applications of magnesium alloys.

Carbon and low-alloy steels are considered resistant only to very mild corrosives, while the various high-alloy grades are applicable for varying situations from mild to severe services, depending on the particular conditions involved. This article describes the factors that must be considered, by alloy casting users, in material selection. It presents compositions of cast steels tested in atmospheric corrosion in a tabular form. The rate of corrosion of a material in an environment can generally be estimated with confidence only from long-term tests. The article graphically presents the results of a research program that compared the corrosion resistance of nine cast steels in marine and industrial atmospheres. It illustrates the comparison of corrosion rates of cast steels, malleable cast iron, and wrought steel after 3 years of exposure in two atmospheres and provides the conclusions drawn from these tests.

This article provides information on the properties, compositions, designations, and applications of zinc and zinc alloys. It discusses the principal areas of application of zinc: in coatings and anodes for corrosion protection of irons and steels; in zinc casting alloys; as an alloying element in copper, aluminum, magnesium, and other alloys; in wrought zinc alloys; and in zinc chemicals. The zinc coating applications of hot dip galvanizing, electrogalvanizing, plating, and thermal spray are presented. The use of zinc alloys in both gravity and pressure die castings is discussed as well as the three main types of wrought products: flat-rolled products, wire-drawn products, and extruded and forged products. The article also provides a section on the corrosion resistance of zinc and zinc coatings in various atmospheres.

Alloy cast irons are casting alloys based on the Fe-C-Si system that contain one or more alloying elements added to enhance one or more useful properties. This article discusses the composition of different types of alloy cast iron, including white cast irons, corrosion-resistant cast irons, heat-resistant cast irons, and abrasion-resistant cast irons. It provides information on the effect of the alloying element on their high-temperature properties. The article also discusses the microstructure and mechanical properties of alloy cast irons.

This article describes the casting characteristics and practices of copper and copper alloys. It discusses the melting and melt control of copper alloys, including various melt treatments to improve melt quality. These melt treatments include fluxing and metal refining, degassing, deoxidation, grain refining, and filtration. The article provides a discussion on these melt treatments for group I to III alloys. It describes the three categories of furnaces for melting copper casting alloys: crucible furnaces, open-flame furnaces, and induction furnaces. The article explains the important factors that influence the selection of a casting method. It also describes the production of copper alloy castings. The article concludes with a discussion on the gating and feeding systems used in production of copper alloy castings.

This article focuses on the various forms of corrosion occurred in the passive range of aluminum and its alloys, namely, pitting corrosion, galvanic corrosion, deposition corrosion, intergranular corrosion, stress-corrosion cracking, exfoliation corrosion, corrosion fatigue, erosion-corrosion, atmospheric corrosion, filiform corrosion, and corrosion in water and soils. It discusses the effects of composition, microstructure, stress-intensity factor, and nonmetallic building materials on the corrosion behavior of aluminum and its alloys. The article also describes the corrosion resistance of anodized aluminum in contact with foods, pharmaceuticals, and chemicals.

This article discusses the corrosion resistance of aluminum and aluminum alloys in various environments, such as in natural atmospheres, fresh waters, seawater, and soils, and when exposed to chemicals and their solutions and foods. It describes the forms of corrosion of aluminum and aluminum alloys, including pitting corrosion, intergranular corrosion, exfoliation corrosion, galvanic corrosion, stray-current corrosion, deposition corrosion, crevice corrosion, filiform corrosion, stress-corrosion cracking, corrosion fatigue, and hydrogen embrittlement. The article also presents a short note on aluminum clad products and corrosion at joints.

This article discusses the properties, primary and secondary production, product forms and applications of various grades of lead and lead-base alloys with the aid of several tables and illustrations. It lists the Unified Numbering System (UNS) designations for various pure lead grades and lead-base alloys grouped according to nominal chemical composition. The properties of lead that make it useful in a wide variety of applications are also discussed. The largest use of lead is in lead-acid storage batteries. Other applications include ammunition, cable sheathing, cast products such as type metals, terneplate, foils, and building construction materials. Lead is also used as an alloying element in steel and in copper alloys to improve machinability. The article concludes with information on the principles of lead corrosion, corrosion resistance of lead in water, atmospheres, underground ducts, soil and chemicals.

This article provides a description of the classification, industrial applications, microstructures, physical, chemical, corrosion, and mechanical properties of zirconium and its alloys. It discusses the formation of oxide films and the effects of water, temperature, and pH on zirconium. The delayed hydride cracking of zirconium is also described. The article provides information on the resistance of zirconium to various types of corrosion, including pitting corrosion, crevice corrosion, intergranular corrosion, galvanic corrosion, microbiologically induced corrosion, erosion-corrosion, and fretting corrosion. The article explains the effects of tin content in zirconium and effects of fabrication on corrosion. Corrosion control measures for all types of corrosion are also highlighted. The article concludes with information on the safety precautions associated with handling of zirconium.

Copper and copper alloys are widely used in many environments and applications because of their excellent corrosion resistance, which is coupled with combinations of other desirable properties. This article lists the identifying characteristics of the forms of corrosion that commonly attack copper metals as well as the most effective means of combating each. General corrosion, galvanic corrosion, pitting, impingement, fretting, intergranular corrosion, dealloying, corrosion fatigue, and stress-corrosion cracking (SCC) are some forms of corrosion. The article also lists a galvanic series of metals and alloys valid for dilute aqueous solutions, such as seawater and weak acids. It provides useful information on the effects of alloy compositions, selection for specific environments, and atmospheric corrosion of selected copper alloys. The article also tabulates the corrosion ratings of wrought copper alloys in various corrosive media.

Tantalum is one of the most versatile corrosion-resistant metals known. The outstanding corrosion resistance and inertness of tantalum are attributed to a very thin, impervious, protective oxide film that forms on exposure of the metal to slightly anodic or oxidizing conditions. This article provides a discussion on the mechanism of corrosion resistance and on the behavior of tantalum in different corrosive environments, namely, acids; salts; organic compounds; reagents, foods, and pharmaceuticals; body fluids and tissues; and gases. It contains several tables that summarize the effects of acids, salts, and miscellaneous corrosive reagents on tantalum and applications for tantalum equipment in chemical, pharmaceutical, and other industries. Finally, the article presents a discussion on hydrogen embrittlement, the galvanic effects, and cathodic protection of tantalum and describes the corrosion resistance of different types of tantalum-base alloys.