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D. Klarstrom, P. Crook, J. Wu
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George F. Vander Voort, Gabriel M. Lucas, Elena P. Manilova
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John Marcin, Matthew Donachie
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Joseph R. Stephens
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Lin Li
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S.J. Matthews
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Darrell Manente
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cast cobalt-base superalloys
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Cast dendritic structure of MAR-M 509 cobalt-base superalloy revealed using...
Available to PurchasePublished: 01 December 2004
Fig. 6 Cast dendritic structure of MAR-M 509 cobalt-base superalloy revealed using (a) 15 mL HCl, 10 mL acetic acid, and 10 mL HNO 3 , (b) the Lucas electrolytic reagent (2 V dc, 20 s), and (c) Beraha's tint etch (50 mL HCl, 50 mL water, 0.8 g K 2 S 2 O 5 , 4 g NH 4 F·HF
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Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001050
EISBN: 978-1-62708-161-0
... Abstract The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength...
Abstract
The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.
Series: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006267
EISBN: 978-1-62708-169-6
.... Strengthening of cobalt-base alloys is accomplished by solid-solution alloying (e.g., molybdenum, tungsten, tantalum, and niobium) in combination with carbon to promote carbide precipitation. Compared to the wrought alloys, cast cobalt-base superalloys are characterized by higher contents of high-melting metals...
Abstract
Cobalt is used as an alloying element in alloys for various applications. This article provides a detailed account of the metallurgy of cobalt-base alloys. It focuses on the compositions, properties, and applications of cobalt-base alloys, which include wear-resistant cobalt alloys, heat-resistant cobalt alloys, and cobalt-base corrosion-resistant alloys. The article also describes the heat treatments such as annealing and aging, for these alloys.
Book Chapter
Metallography and Microstructures of Cobalt and Cobalt Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003771
EISBN: 978-1-62708-177-1
... in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys. cobalt alloys Hastelloy Haynes alloys metallographic preparation metallography metallurgy microstructure COBALT is used as an alloying element in alloys for various applications...
Abstract
This article describes the metallurgy and microstructure of high-performance cobalt-base alloys. It discusses metallographic preparation procedures, including sectioning, mounting, grinding, polishing, etching, staining, and heat tinting. It examines the microstructure of cobalt alloys in cast, wrought, and powder metal forms, including magnetic alloys as well as several cobalt-base superalloys.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003120
EISBN: 978-1-62708-199-3
... on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms. chemical composition cobalt-base superalloys environmental factors high-temperature applications iron-base superalloys mechanical properties metal processing...
Abstract
Superalloys are nickel, iron-nickel, and cobalt-base alloys generally used for high-temperature applications. Superalloys are used in aircraft, industrial, marine gas turbines, nuclear reactors, spacecraft structures, petrochemical production, orthopedic and dental prostheses, and environmental protection applications. This article discusses the material characteristics, phases, structures, and systems of superalloys. It describes the processing of superalloys, including primary and secondary melting, deformation processing (conversion), powder processing, investment casting, and joining methods. The article also describes the properties, microstructure, and thermal exposure of superalloys. It further discusses the effects of environmental factors on superalloys, including oxidation and hot corrosion. Protective coatings are also discussed. The article provides information on the mechanical properties and chemical composition of nickel, iron, and cobalt-base superalloys in both the cast and wrought forms.
Book Chapter
Metallography and Microstructures of Heat-Resistant Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003737
EISBN: 978-1-62708-177-1
... CNK7 revealed using (a) glyceregia, (b) Kalling's No. 2, (c) the Lucas electrolytic reagent (2 V dc, 10 s), and (d) Beraha's tint etch (50 mL HCl, 50 mL water, 0.8 g K 2 S 2 O 5 , 4 g NH 4 F·HF, 1 g FeCl 3 Fig. 6 Cast dendritic structure of MAR-M 509 cobalt-base superalloy revealed using...
Abstract
This article discusses the specimen preparation of three types of cast and wrought heat-resistant alloys: iron-base, nickel-base, and cobalt-base. Specimen preparation involves sectioning, mounting, grinding, polishing, and etching. The article illustrates the microstructural constituents of cast and wrought heat-resistant alloys. It describes the identification of ferrite by magnetic etching. The transmission electron microscopy examination of the fine strengthening phases in wrought alloys and bulk extraction in heat-resistant alloys are included. The article also reviews the gamma prime phase, gamma double prime phase, eta phase, laves phase, sigma phase, mu phase, and chi phase in wrought heat-resistant alloys.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001049
EISBN: 978-1-62708-161-0
... Abstract This article focuses on the properties of conventional wrought superalloys based on nickel, iron, and cobalt, as well as on the properties of alloys produced from powder. The powder metallurgy (P/M) category includes alloys that were originally developed as casting alloys; new alloy...
Abstract
This article focuses on the properties of conventional wrought superalloys based on nickel, iron, and cobalt, as well as on the properties of alloys produced from powder. The powder metallurgy (P/M) category includes alloys that were originally developed as casting alloys; new alloy compositions developed specifically to benefit from powder processing; and oxide dispersion strengthened alloys (particularly those produced by mechanical alloying). The article discusses some of the applications of superalloys and emphazises the interplay between chemical composition, microstructure, consolidation method, mechanical properties and surface stability of wrought nickel alloys. Vacuum melting processes are a necessity for many nickel- and iron-nickel-base alloys because of the presence of aluminum and titanium as solutes. Cobalt-base alloys do not usually contain these elements and may be melted in air. An appendix to this article presents the property data and corresponding information on a family of cobalt-chromium-tungsten-carbon alloys that use P/M processing.
Book Chapter
Cobalt and Cobalt Alloys
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003148
EISBN: 978-1-62708-199-3
... In nickel-base superalloys, cobalt (which is presently typically in the range 10 to 15 wt%) provides solid-solution strengthening and decreases the solubility of aluminum and titanium, thereby increasing the volume fracture of γ′ precipitate. Cobalt in nickel-base superalloys also reduces the tendency...
Abstract
Cobalt finds its use in various applications owing to its magnetic properties, corrosion resistance, wear resistance, and its strength at elevated temperatures. This article discusses the mining and processing of cobalt and cobalt alloys. It describes the types of cobalt alloys, including wear-resistant alloys, high-temperature alloys, corrosion-resistant alloys, and special-purpose alloys. The article provides data on the chemical composition, mechanical properties, and physical properties of these alloys. Further, it provides information on the uses of cobalt in superalloys, cemented carbides, magnetic materials, low-expansion alloys, and high-speed tool steels.
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Typical operating microstructures of representative superalloys. (a) Cast c...
Available to PurchasePublished: 01 December 1998
Fig. 2 Typical operating microstructures of representative superalloys. (a) Cast cobalt-base alloy. 250×. (b) Cast nickel-base alloy. 100×. (c) Wrought (left, 3300×) and cast (right, 5000×) nickel-base alloys. (d) Two wrought iron-nickel-base alloys (left, 17,000×; right, 3300×). Note script
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Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005335
EISBN: 978-1-62708-187-0
... coatings continuous casting gas turbines heat treatment hot isostatic pressing microstructure orthopedic implants phases physical metallurgy crystallography foundry methods argon-oxygen decarburization cobalt alloy castings wear-resistant alloys corrosion-resistant alloys COBALT-BASE...
Abstract
This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.
Book Chapter
Heat Treatment of Cast Nickel-Base Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 4E
Publisher: ASM International
Published: 01 June 2016
DOI: 10.31399/asm.hb.v04e.a0006266
EISBN: 978-1-62708-169-6
... 48.0–52.0 … … … … … … … … … 50Ni-50Cr-Nb (ASTM A560) 0.10 bal 47.0–52.0 … … … … … … … … 1.4–1.7 Nb (a) Alloy Casting Institute designation Cast Nickel-Base Superalloys Superalloys are nickel-, iron-nickel-, and cobalt-base alloys generally used at temperatures...
Abstract
Cast nickel-base alloys are used extensively in corrosive-media and high-temperature applications. This article briefly reviews the common types of heat treatments of nickel alloy castings: homogenization, stress relieving, in-process annealing, full annealing, solution annealing, quenching, coating diffusion, and precipitation. It describes the three general strengthening mechanisms, namely, solid-solution hardening, age hardening, and carbide precipitation. The article summarizes the typical heat treatment of the general families of nickel-base castings used in industrial applications. It focuses on the solution treatment and age hardening of cast nickel-base superalloys and the heat treatment of cast solid-solution alloys for corrosion-resisting applications. The article also discusses the typical types of atmospheres used in annealing or solution treating: exothermic, endothermic, dry hydrogen, dry argon, and vacuum.
Book Chapter
Strategic Materials Availability and Supply
Available to PurchaseSeries: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001052
EISBN: 978-1-62708-161-0
... Superalloys are the major materials of construction for today's high-temperature gas turbine engines used for both commercial and military aircraft. Nickel-base superalloys, along with iron-base and cobalt-base superalloys, are used throughout the engines in wrought, cast, powder metallurgy (P/M), and cast...
Abstract
This article reviews some of the trends in superalloy development as they relate to U.S. strategic materials availability and the aerospace industry. It discusses the supply sources and availability of strategic materials and summarizes the status of U.S. resources and reserves. The article presents a list of several superalloys that have been used in gas turbine engines or that are emerging as replacements because of the promise of increased operating temperatures and higher efficiencies for the aircraft of the future. It concentrates on the objectives, results, and methodology of the NASA Conservation of Strategic Aerospace Materials (COSAM) program.
Book Chapter
Heat Treating of Precipitation-Hardenable Stainless Steels and Iron-Base Superalloys
Available to PurchaseSeries: ASM Handbook
Volume: 4D
Publisher: ASM International
Published: 01 October 2014
DOI: 10.31399/asm.hb.v04d.a0005961
EISBN: 978-1-62708-168-9
... 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys. annealing austenitic precipitation-hardenable stainless steel heat treatment iron-base superalloys martensitic precipitation-hardenable...
Abstract
Precipitation hardening is a hardening mechanism found in various steels and alloy systems, such as nickel-, cobalt-, titanium-, copper-, and iron-base alloys. This article provides a brief description of precipitation hardening process, furnace equipment, surface-related problems, and protective atmospheres used in heat treatment of iron-base precipitation-hardenable (PH) superalloys. It focuses on various factors to be considered in heat treating of PH stainless steels: cleaning prior to heat treatment, furnace atmospheres, time-temperature cycles, variations in cycles, and scale removal after heat treatment. The article describes the mechanical properties, solution treatment, and aging treatment for many martensitic PH alloys, including: Alloy 17-4 PH, Alloy 13-8 Mo, Alloy 15-5 PH, Custom 450, and Custom 455; as well as semiaustenitic PH stainless steels such as Alloy 17-7 PH, Alloy PH 15-7 Mo, AM-350, Pyromet 350, AM-355, and Pyromet 355; austenitic PH stainless steel, A-286; cast PH stainless steels; and iron-nickel PH superalloys.
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001073
EISBN: 978-1-62708-162-7
...-Performance Alloys , Volume 1 of ASM Handbook , formerly 10th Edition Metals Handbook. Nickel-base and cobalt-base castings for high-temperature service are also covered in the article “Polycrystalline Cast Superalloys” in Properties and Selection: Irons, Steels, and High-Performance Alloys , Volume 1...
Abstract
This article provides a general overview of physical and mechanical properties, alloy compositions, applications, and product forms of cobalt-base alloys as wear-resistant, corrosion-resistant, and/or heat-resistant materials. The discussion is largely focused on cobalt-base alloys for wear resistance, as this is the single largest application area of cobalt-base alloys.
Book Chapter
Cutting Tool Materials
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003188
EISBN: 978-1-62708-199-3
... Associates, Inc. Cobalt-Base Cutting Tools Cobalt-base cutting tools have been available since about 1920. These materials are generally cast cobalt-chromium-tungsten alloys with carbon and other alloy additions. They are not heat treatable, and the maximum hardness (55 to 65 HRC) occurs near...
Abstract
Selecting the proper cutting tool material for a specific machining application can provide substantial advantages, including increased productivity, improved quality, and reduced costs. This article begins with a description of the factors affecting the selection of a cutting tool material. This is followed by a schematic representation of their relative application ranges in terms of machining speeds and feed rates. The article provides a detailed account of chemical compositions of various tool materials, including high-speed tool steels, cobalt-base alloys, cemented carbides, cermets, ceramics, cubic boron nitride, and polycrystalline diamond. It compares the toughness, and wear resistance for these cutting tool materials. Finally, the article explains the steps for selecting tool material grades for specific application.
Book Chapter
Pack Cementation Processes
Available to PurchaseSeries: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005775
EISBN: 978-1-62708-165-8
... ) are those based on aluminum (aluminizing), chromium (chromizing), and silicon (siliconizing). Substrate materials include nickel- and cobalt-base superalloys, steels (including carbon, alloy, and stainless steels), and refractory metals and alloys. Multicomponent pack cementation coatings have been...
Abstract
Pack cementation is the most widely employed method of diffusion coating. This article briefly reviews pack cementation processes of aluminizing, chromizing, and siliconizing. It contains tables that list typical characteristics of pack cementation processes and commercial applications of pack cementation aluminizing, which is used to improve the performance of steels in high-temperature corrosive environments.
Book Chapter
Property Comparison Tables: Hardness and Tensile Properties
Available to PurchaseSeries: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003331
EISBN: 978-1-62708-176-4
... (nodular) irons, cast 1034 150 276 40 Copper casting alloys (a) 965 140 62 9 Stainless steels, standard austenitic grades; wrought, cold worked 965 140 517 75 Niobium and its alloys 931 135 241 35 Iron-base superalloys; cast, wrought 924 134 276 40 Cobalt-base...
Abstract
This article is a comprehensive collection of tables that list the values for hardness of plastics, rubber, elastomers, and metals. The tables also list the tensile yield strength and tensile modulus of metals and plastics at room temperature. A comparison of various engineering materials, on the basis of tensile strength, is also provided.
Book Chapter
Selection of Cobalt-, Titanium-, Zirconium-, and Tantalum-Base Corrosion-Resistant Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001430
EISBN: 978-1-62708-173-3
... the ductility of a welded structure. A postweld heat treatment is recommended, especially if the cold forming of a weldment after welding is a required part of the fabrication sequence. Tensile properties of welded cobalt-base corrosion-resistant alloy UNS R31233 relative to wrought and cast products at room...
Abstract
This article discusses the weldability characteristics of cobalt-base corrosion-resistant (CR) alloys, titanium-base CR alloys, zirconium-base CR alloys, and tantalum-base CR alloys that assist in the selection of suitable alloy and welding method for producing high-quality welds.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006094
EISBN: 978-1-62708-175-7
... Abstract Superalloys are predominantly nickel-base alloys that are strengthened by solid-solution elements including molybdenum, tungsten, cobalt, and by precipitation of a Ni 3 (Al, Ti) type compound designated as gamma prime and/or a metastable Ni 3 Nb precipitate designated as gamma double...
Abstract
Superalloys are predominantly nickel-base alloys that are strengthened by solid-solution elements including molybdenum, tungsten, cobalt, and by precipitation of a Ni 3 (Al, Ti) type compound designated as gamma prime and/or a metastable Ni 3 Nb precipitate designated as gamma double prime. This article provides a discussion on the conventional processing, compositions, characteristics, mechanical properties, and applications of powder metallurgy (PM) superalloys. The conventional processing of PM superalloys involves production of spherical prealloyed powder, screening to a suitable maximum particle size, blending the powder to homogenize powder size distribution, loading powder into containers, vacuum outgassing and sealing the containers, and consolidating the powder to full density. PM superalloys include Rene 95, IN-100, LC Astroloy, Udimet 720, N18, ME16, RR1000, Rene 88DT, PA101, MERL 76, AF2-1DA, Inconel 706, AF115, and KM4. The article reviews specialized PM superalloy processes and technical issues in the usage of PM superalloys.
Book Chapter
Brazing of Heat-Resistant Alloys, Low-Alloy Steels, and Tool Steels
Available to PurchaseSeries: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001453
EISBN: 978-1-62708-173-3
... discusses primarily nickel- and cobalt-base alloys. Superalloys can also be subdivided (according to manufacturing technology) into two categories: conventional cast and wrought alloys and powder metallurgy (P/M) products. Powder metallurgy products may be produced in conventional alloy compositions...
Abstract
This article focuses primarily on the various steps involved in the brazing of heat-resistant alloys (nickel- and cobalt-base alloys). The major steps include the selection of brazing filler metals, surface cleaning and preparation, brazing processes and their corresponding atmospheres, and fixturing. The article also provides an overview of the brazing of blow-alloy steels and tool steels and oxide dispersion-strengthened alloys.
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