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carbonyl iron powders
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Published: 01 December 1998
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006081
EISBN: 978-1-62708-175-7
... Abstract This article briefly reviews the production methods and characteristics of plain carbon and low-alloy water-atomized iron and steel powders, high-porosity iron powder, carbonyl iron powder, and electrolytic iron powder. It emphasizes on atomized powders, because they are the most...
Abstract
This article briefly reviews the production methods and characteristics of plain carbon and low-alloy water-atomized iron and steel powders, high-porosity iron powder, carbonyl iron powder, and electrolytic iron powder. It emphasizes on atomized powders, because they are the most widely used materials for ferrous powder metallurgy. The article provides information on the properties and applications of these powders. It also includes an overview of diffusion alloying, basics of admixing, and bonded premixes.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006102
EISBN: 978-1-62708-175-7
... Particles Commercial iron powders are generally manufactured using either mechanical or chemical methods. Water atomization of molten iron or alloys is a primary mechanical manufacturing method today. Chemical methods include reduction and electrolytic and carbonyl processes, with chemical reduction...
Image
Published: 30 September 2015
Fig. 14 Scanning electron micrographs of powder morphology and internal microstructure of BASF carbonyl iron powder. Source: Ref 13
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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006122
EISBN: 978-1-62708-175-7
... oxide coating, blending for uniformity, screening, and packaging. The iron carbonyl at the bottom of the distillation column, mentioned above, is transferred, along with some nickel carbonyl to a recirculating pellet making reactor where 70Fe-30Ni pellets are produced. Combined nickel pellet and powder...
Abstract
This article discusses the methods for producing powder metallurgy (PM) nickel powders, including carbonyl process, hydrometallurgical process, hydrogen reduction process, and atomization process, as well as their applications. It describes three processes for producing nickel alloy powders: water atomization, high-pressure water atomization, and gas atomization. The article also provides information on the applications of PM hot isostatic pressing in the oil and gas industry.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003112
EISBN: 978-1-62708-199-3
... process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals...
Abstract
Iron powders are the most widely used powder metallurgy (P/M) material for structural parts. This article reviews low to medium density iron and low-alloy steel parts produced by the pressing and sintering technology. It explains different powder production methods, including Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals with the mechanical and physical properties of ferrous P/M materials, which may depend on certain factors, namely microstructure, porosity, density, infiltration, re-pressing, chemical composition, and heat treatment.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006649
EISBN: 978-1-62708-213-6
...) are then ground into the required particle size, so that the final milling techniques often determine the particle morphology and powder quality that relate to certain specific performances. For example, one of the electrolytic iron powders is produced into layered solid particles with a flake shape. Carbonyl...
Abstract
This article uses metal and alloy powders as examples to briefly discuss how to perform the characterization of powders. It begins by reviewing some of the techniques involved in the sampling of powders to ensure accurate characterization. This is followed by a discussion on the important properties to characterize powders, namely the particle size, surface area, density, porosity, particle hardness, compressibility, green strength, and flowability. For characterization of powders, both individual particles and bulk powders are used to evaluate their physical and chemical properties. The article also discusses the important characteristics and compositions of powder as well as impurities that directly affect powder properties. It ends with a description of the ignition and dust-explosion characteristics of organic and metal powders.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006092
EISBN: 978-1-62708-175-7
..., namely, elemental irons and iron compounds, used as fortificants. Common elemental iron powders such as plain pure iron powders, and common iron compounds such as ferrous sulfate used in food fortifications, are reviewed. The article contains tables that list the food chemical codex requirements...
Abstract
The food-based approaches are considered important sustainable strategies for preventing iron deficiency. The success of a food fortification program depends on the choice of food vehicles and the choice of iron fortificants, that is, iron sources. This article discusses iron sources, namely, elemental irons and iron compounds, used as fortificants. Common elemental iron powders such as plain pure iron powders, and common iron compounds such as ferrous sulfate used in food fortifications, are reviewed. The article contains tables that list the food chemical codex requirements and the physical and chemical properties of commercial food-grade elemental irons.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006087
EISBN: 978-1-62708-175-7
... powders, those produced by thermal decomposition of carbonyls are the most important. Both iron and nickel are produced by decomposition of the respective carbonyls. Processing Conditions Carbonyls are obtained by passing carbon monoxide over spongy metal at specific temperatures and pressures...
Abstract
This article provides a discussion on the process descriptions, processing conditions, and processing variables of the most common chemical methods for metal powder production. These methods include oxide reduction, precipitation from solution, and thermal decomposition. Methods such as precipitation from salt solution and gas, chemical embrittlement, hydride decomposition, and thermite reactions are also discussed. The article also discusses the methods used to produce powders electrolytically and the types of metal powders produced. The physical and chemical characteristics of these powders are also reviewed.
Image
Published: 30 September 2015
Fig. 2 Images of iron powders (95% <45 μm, or 1.8 mils) produced from different manufacturing processes. (a) Atomized iron. (b) Reduced iron. (c) Electrolytic iron. (d) Carbonyl iron. Top row: SEM images; bottom row: cross section optical microscope images
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Image
Published: 15 December 2019
Fig. 2 Images of elemental iron powders (95% <325 mesh, or 45 μm) produced from different manufacturing processes. (a) Atomized iron. (b) Hydrogen-reduced iron. (c) Electrolytic iron. (d) Carbonyl iron. Top row: scanning electron microscopy images; bottom row: cross-sectional optical
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Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003185
EISBN: 978-1-62708-199-3
... powders can be produced. Thermal Decomposition Of the group of thermally decomposed powders, those produced by thermal decomposition of carbonyls are the most important. Both iron and nickel are produced by decomposition of their carbonyls. Carbonyls are obtained by passing carbon monoxide over...
Abstract
This article focuses on the significant fundamental powder characteristics, which include particle size, particle size distribution, particle shape, and powder purity, followed by an overview of general and individual powder production processes such as mechanical, chemical, electrochemical, atomizing, oxide reduction, and thermal decomposition processes. It also covers the consolidation of powders by pressing and sintering, as well as by high density methods. Further emphasis is provided on the distinguishing features of powders, their manufacturing processes, compacting processes, and consolidated part properties. In addition, a glossary of powder metallurgy terms is included.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003789
EISBN: 978-1-62708-177-1
... metal powders and production methods are: Iron: sponge, atomized, electrolytic, and carbonyl powder Steel: atomization Copper: by reduction of oxides, atomization, electrolysis, and hydrometallurgical processing Tin: by atomization Aluminum: by atomization Magnesium...
Abstract
This article provides information on the microstructure of powder metal alloys and the special handling requirements of porous materials. It covers selection, sectioning, mounting, grinding, and polishing, and describes procedures, such as washing, liquid removal, and impregnation, meant to preserve pore structures and keep them open for analysis. The article compares and contrasts the microstructures of nearly 50 powder metal alloys, using them to illustrate the effect of consolidation and compaction methods as well as particle size, composition, and shape. It discusses imaging equipment and techniques and provides data on etchants and etching procedures.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006141
EISBN: 978-1-62708-175-7
... better shape retention during debinding. Numerous powders with widely varying powder characteristics have been used in MIM products. Predominantly, MIM products are made from ferrous alloys. During the early commercial growth of MIM (mid-1980s), the wide availability of carbonyl iron and nickel...
Abstract
This article describes part selection, feedstock (powders and binders) characteristics and properties, tool design, and material and tooling for fabrication of metal powder injection molding (MIM) machines. It discusses the process parameters, operation sequence, molding machines, debinding techniques, consolidation (sintering) techniques, advantages, and limitations of MIM.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006088
EISBN: 978-1-62708-175-7
... Type of iron powder, wt% Carbonyl Electrolytic Reduced 0–10 2.0 6.6 1.8 10–15 59.0 9.2 17.0 15–30 36.0 53.0 41.0 30–44 3.0 31.2 40.2 Apparent density, g/cm 3 3.42 2.56 1.89 Tap density, g/cm 3 4.09 3.42 2.12 d f : d a 1.20 1.34 1.12...
Abstract
Blending of powders is defined as the thorough intermingling of powders of the same nominal composition. Premixing is the preparation of a uniform mixture of two or more components. This article provides information on the blending and premixing variables required to produce adequate results in the powder mixture. It describes the effects of metal powder characteristics on blending and mixing: particle size, shape, density, and surface features. The article also provides information on the equipment, tumble-type blenders, and low-shear agitated-type blenders used for blending and premixing solids.
Series: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004140
EISBN: 978-1-62708-184-9
... provides a list of pollutants and their sources in museums and collections. It discusses the sources of corrosion, including plastic and wood, sulfur, and carbonyl compounds. The article describes the preservation steps for materials in museum to eliminate the corrosive sources acting on the objects...
Abstract
This article presents a general survey of corrosive agents and processes that exist within what are usually considered the protective environments of museums and historic collections. It reviews the corrosion influencing factors, such as humidity, temperature, and light. The article provides a list of pollutants and their sources in museums and collections. It discusses the sources of corrosion, including plastic and wood, sulfur, and carbonyl compounds. The article describes the preservation steps for materials in museum to eliminate the corrosive sources acting on the objects and to avoid other potentially damaging materials.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006052
EISBN: 978-1-62708-175-7
... for more uniform shrinkage, while ultrafine powders have a spherical particle shape with a rough surface. Nickel and iron powders are also obtained by the reduction of hydrometallurgically produced oxides and by the decomposition of the carbonyl complexes ( Ref 1 ). Carbide Additives Titanium...
Abstract
This article discusses the methods and procedures used to extract, purify, and synthesize tungsten carbide powder, metal, and other refractory carbide/nitride powders used in hard metal production. Selection of powders, additives, equipment, and processes for making ready-to-press hard metal powders is also discussed. The article also provides information on the emerging technologies for tungsten carbide synthesis and binders in hard metal production, such as cobalt, iron, and nickel.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006109
EISBN: 978-1-62708-175-7
... such as calcium, lithium, or zinc stearates can cause a cohesive powder to flow more easily. It can eliminate rat hole formation. Particularly at elevated processing temperatures, a nanoparticle metal or metal oxide flow agent can be added for enhancing the flow characteristics of iron-base metallurgical powder...
Abstract
This article describes the methods for determining the flow rate of metal powders. It examines the factors affecting flow rate, apparent density, and angle of repose of metal powders. The article reviews the frictional properties, cohesive strength, frictional properties, tap density, and compressibility of metal powders. It explains the mechanisms of powder segregation. The article provides information on green strength and springback value of rectangular test bar. It concludes with a discussion on the chemical composition of metal powders.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006057
EISBN: 978-1-62708-175-7
... , 14 Metal Injection Molding Metal injection molding (MIM) was developed to produce parts having complex geometry. Gas-atomized powders are used because they are purer and finer. Iron and nickel powders produced by the carbonyl process are also used. Gas-atomized and carbonyl powders...
Abstract
Powder metallurgy (PM) techniques are effective in making magnetically soft components for use in magnetic part applications. This article provides an account of the factors affecting magnetism, permeability, and hysteresis losses. It includes information on the magnetic properties of PM materials that are used in the magnetic part applications, namely, pure iron, phosphorus irons, ferritic stainless steels, 50 nickel-50 iron, and silicon irons. The article describes the factors that affect and optimize magnetic properties. It contains a table that lists the magnetic properties possible in metal injection molding parts. The article also discusses ferromagnetic cores used in alternating current applications and some permanent magnets, such as rare earth-cobalt magnets and neodymium-iron-boron (neo) magnets.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006134
EISBN: 978-1-62708-175-7
... shapes. In addition, irregularly shaped powders and powders with binders can be processed using gravity sintering to obtain low-density products. Carbonyl- and water-atomized nickel powders are rapidly growing in acceptance for use as porous PM products. The thermal decomposition of nickel carbonyl...
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