This article discusses the important characteristics of fluidized beds. The total space occupied by a fluidized bed can be divided into three zones: grid zone, main zone, and above-bed zone. The article discusses the various types of atmospheres of fluidized beds, such as oxidizing and decarburizing atmosphere; nitrocarburizing and nitriding atmosphere; carburizing and carbonitriding atmosphere; and chemical vapor deposition atmosphere. External resistance heating, external combustion heating, internal resistance heating, direct resistance heating, submerged combustion heating, and internal combustion heating can be used to achieve the heat input for a fluidized bed. The article also describes the operations, design considerations, and applications of fluidized-bed furnaces in heat treating. Thermochemical surface treatments, such as carburizing, carbonitriding, nitriding, and nitrocarburizing, are also discussed. Finally, the article reviews the principles and applications of fluidized-bed heat treatment.

Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.

The process of case hardening of steel includes three consecutive steps of heat treatment: heating; the thermochemical process with the enrichment of the surface area during the carburizing or carbonitriding stage with carbon and nitrogen; and the subsequent quenching process for hardening. This article provides a model-based description of the development of residual stresses during case hardening. It also describes the influence and effects of residual stresses and distortion in hardening, carburizing, and nitriding processes of the steel.

Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.

This article reviews high-temperature corrosion of furnace parts used in heat-treating furnaces. It provides a comparison of cast and wrought materials in the context of their general considerations, advantages, and applications. The article provides information on the heat-resistant alloys used for parts that go through the furnaces, including trays, fixtures, conveyor chains and belts, and quenching fixtures and parts, and the parts that remain in the furnace such as combustion tubes, radiant tubes, burners, thermowells, roller and skid rails, baskets, pots, retorts, muffles, and drive and idler drums. The article also reviews the material characteristics of silicon/silicon carbide composite and reaction-bonded silicon carbide as used in radiant tubes.

This article presents the principles of chemical vapor deposition (CVD) with illustrations. It discusses the types of CVD processes, namely, thermal CVD, plasma CVD, laser CVD, closed-reactor CVD, chemical vapor infiltration, and metal-organic CVD. The article reviews the CVD reactions of materials related to hard, tribological, and high-temperature coatings and to free-standing structures. It concludes by reviewing the advantages, disadvantages, and applications of CVD.

Thermomechanical processing (TMP) refers to various metal forming processes that involve careful control of thermal and deformation conditions to achieve products with required shape specifications and good properties. This article describes TMP methods in producing hot-rolled steel and reviews how improvements in the strength and toughness depend on the synergistic effect of microalloy additions and on carefully controlled thermomechanical conditions. It discusses TMP variables and the general distinctions between conventional hot rolling and common types of controlled-rolling schedules. The article describes the metallurgical processes in grain refinement of austenite steel by hot working, such as recovery and recrystallization and strain-induced transformation. The grain refinement in high strength low alloy steel by alloy addition is also discussed. The article provides an outline on the key stages of deformation, and the required metallurgical information at each of these stages.

Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.

This article focuses on the forging behavior and practices of carbon and alloy steels. It presents general guidelines for forging in terms of practices, steel selection, forgeability and mechanical properties, heat treatments of steel forgings, die design features, and machining. The article discusses the effect of forging on final component properties and presents special considerations for the design of hot upset forgings.

Furnaces are one of the most versatile types of industrial appliances that span many different areas of use. This article discusses the classification of various furnaces used in heat treating based on the mode of operation (batch-type furnaces and continuous-type furnaces), application, heating method, mode of heat transfer, type of materials handling system, and mode of waste heat recovery (recuperation and regeneration). It provides information on uniform temperature distribution, the general requirements and selection criteria for insulation materials, as well as the basic safety requirements of these furnaces.

Iron powders are the most widely used powder metallurgy (P/M) material for structural parts. This article reviews low to medium density iron and low-alloy steel parts produced by the pressing and sintering technology. It explains different powder production methods, including Hoeganaes process, Pyron process, atomization of liquid metal, thermal decomposition and the electrodeposition process for carbonyl and electrolytic iron powders. It describes the types of compaction and sintering, explaining their effects of processing with designations. Further, the article deals with the mechanical and physical properties of ferrous P/M materials, which may depend on certain factors, namely microstructure, porosity, density, infiltration, re-pressing, chemical composition, and heat treatment.

This article describes the fundamental concepts of heat treatment simulation, including the physical events and their interactions, the heat treatment simulation software, and the commonly used simulation strategies. It summarizes material data needed for heat treatment simulations and discusses reliable data sources as well as experimental and computational methods for material data acquisition. The article provides information on the process data needed for accurate heat treatment simulation and the methods for their determination. Methods for validating heat treatment simulations are also discussed with an emphasis on the underlying philosophy for the selection and design of validation tests. The article also discusses the applications, capabilities, and limitations of heat treatment simulations via selected industrial case studies for a better understanding of the effect of microstructure, distortion, residual stress, and cracking in gears, shafts, and bearing rings.

This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia-based atmospheres, industrial gas nitrogen-base atmospheres, argon atmospheres, and hydrogen atmospheres. Atmospheres for backfilling, partial pressure operation, and quenching in vacuum are also discussed. Furnace atmospheres constitute four major groups of safety hazards in heat treating: fire, explosion, toxicity, and asphyxiation. The article reviews the fundamentals of principal gases and vapors. It describes how the evaluation of the atmospheric requirements of heat treating furnaces is influenced by factors such as cost of operation and capital investment.

This article is an atlas of fractographs that helps in understanding the causes and mechanisms of fracture of high-carbon steels and in identifying and interpreting the morphology of fracture surfaces. The fractographs illustrate the following: torsional fatigue fracture, hydrogen-embrittlement fracture, fatigue crack propagation, and corrosion fatigue of components made from high-carbon steels. The high-carbon steel components include bull gear, drive shaft, power boiler stoker grate, steel wheel, spring wire, suspension spring, automotive engine valve spring, power spring, cantilever-type spring, railroad rail, and seamless drill pipe.

Zirconium and hafnium surfaces require cleaning and finishing prior to many processes including joining, heat treating, plating, forming, and final surface finishing. This article provides information on surface treatment processes, surface soil removal, blast cleaning, chemical descaling, pickling or etching, anodizing, autoclaving, polishing, buffing, vapor phase nitriding, and electroplating. It also provides several application examples.

Specialty steels encompass a broad range of ferrous alloys noted for their special processing characteristics (powder metallurgy alloys), corrosion resistance (stainless steels), wear resistance and toughness (tool steels), high strength (maraging steels), or magnetic properties (electrical steels). This article provides a detailed discussion on the various surface treatments, including cleaning, nitriding, carburizing, coating, and plating, performed on specialty steels.

Selecting the proper cutting tool material for a specific machining application can provide substantial advantages, including increased productivity, improved quality, and reduced costs. This article begins with a description of the factors affecting the selection of a cutting tool material. This is followed by a schematic representation of their relative application ranges in terms of machining speeds and feed rates. The article provides a detailed account of chemical compositions of various tool materials, including high-speed tool steels, cobalt-base alloys, cemented carbides, cermets, ceramics, cubic boron nitride, and polycrystalline diamond. It compares the toughness, and wear resistance for these cutting tool materials. Finally, the article explains the steps for selecting tool material grades for specific application.

Batch furnaces and continuous furnaces are commonly used in heat treating. This article provides a detailed account of various heat treating equipment and its furnace types, including salt bath equipment (externally heated, immersed-electrode and submerged-electrode furnaces), and fluidized-bed equipment (external-resistance-heated fluidized beds). It describes various auxiliary equipment used in cold-wall furnaces, namely, heating elements and pumping systems. Five types of heat-resistant alloys are used for furnace parts, trays, and fixtures: Fe-Cr alloys, Fe-Cr-Ni alloys, Fe-Ni-Cr alloys, nickel-base alloys and cobalt-base alloys. The article lists the recommended applications for alloys for parts and fixtures for various types of heat treating furnaces.

This article discusses the classifications, compositions, properties, advantages, disadvantages, limitations, and applications of the most commonly used methods for surface engineering of carbon and alloy steels. These include cleaning methods, finishing methods, conversion coatings, hot-dip coating processes, electrogalvanizing, electroplating, metal cladding, organic coatings, zinc-rich coatings, porcelain enameling, thermal spraying, hardfacing, vapor-deposited coatings, surface modification, and surface hardening via heat treatment.

Control of temperature and furnace atmospheres has become increasingly critical to successful heat treating. Temperature instrumentation and control systems used in heat treating include temperature sensors, controllers, final control elements, measurement instruments, and set-point programmers. This article describes these items and discusses the classifications and control of furnace atmospheres. The article also describes the surface carbon control devices available for the wide variety of furnace atmospheres and evaluation of carbon control. Finally, the article provides a set of guidelines for safety procedures that are common to all industrial heat treating furnace installations.