Carburization is the process of intentionally increasing the carbon content of a steel surface so that a hardened case can be produced by martensitic transformation during quenching. Like carburizing, carbonitriding involves heating above the upper critical temperature to austenitize the steel. This article introduces the fundamentals, types, advantages and limitations, and the complications of various forms of carburizing, namely, pack carburizing, liquid carburizing or salt bath carburizing, gas carburizing, and low-pressure (vacuum) carburizing. The related process of carbonitriding is also briefly described in the article.

Carbonitriding is a modified form of carburizing that involves the introduction and diffusion of atomic nitrogen into the surface steel during carburization. This article discusses the composition, depth, and hardenability of a carburized case, and demonstrates how to control atmosphere in batch and continuous furnaces. It discusses the most important considerations in the selection of carbonitriding temperature. The article also describes the processing factors for minimizing retained austenite in the carbonitrided case. Hardness testing and carbonitriding of powder metallurgy parts, quenching and tempering of carbonitrided steel parts, and applications of carbonitriding are also covered in the article.

This article discusses the important characteristics of fluidized beds. The total space occupied by a fluidized bed can be divided into three zones: grid zone, main zone, and above-bed zone. The article discusses the various types of atmospheres of fluidized beds, such as oxidizing and decarburizing atmosphere; nitrocarburizing and nitriding atmosphere; carburizing and carbonitriding atmosphere; and chemical vapor deposition atmosphere. External resistance heating, external combustion heating, internal resistance heating, direct resistance heating, submerged combustion heating, and internal combustion heating can be used to achieve the heat input for a fluidized bed. The article also describes the operations, design considerations, and applications of fluidized-bed furnaces in heat treating. Thermochemical surface treatments, such as carburizing, carbonitriding, nitriding, and nitrocarburizing, are also discussed. Finally, the article reviews the principles and applications of fluidized-bed heat treatment.

Surface treatments are used in a variety of ways to improve the material properties of a component. This article provides information on surface treatments that improve service performance so that the design engineer may consider surface-engineered components as an alternative to more costly materials. It describes solidification surface treatments such as hot dip coatings, weld overlays, and thermal spray coatings. The article discusses deposition surface treatments such as electrochemical plating, chemical vapor deposition, and physical vapor deposition processes. It explains surface hardening and diffusion coatings such as carburizing, nitriding, and carbonitriding. The article also tabulates typical characteristics of carburizing, nitriding, and carbonitriding diffusion treatments.

The choice of heat treatment depends on the service requirements of a given bearing and how the bearing will be made. This article describes the design parameters, material characteristics required to sustain performance characteristics, metallurgical properties, and dimensional stability. It also provides a description of various extensively-used heat treatment processes, namely, carburizing, carbonitriding, induction surface hardening, and nitriding associated with various bearings. In addition, the article explores the factors to be considered in selecting a process and explains why it is optimum for a specific application.

Case hardening involves various methods and each method has unique characteristics and different considerations in the selection of steels This article reviews the various grades of carburizing steels, carbonitriding steels, nitriding steels, and steels for induction, or flame hardening. This review is based on their process characteristics, compositions, applications, and mechanical properties, which help in selecting steels for case hardening.

A wide variety of stop-off technologies for heat treatment are used to selectively prevent the diffusion of carbon and/or nitrogen during atmosphere carburizing, carbonitriding, vacuum carburizing, and various forms of nitriding. In addition to selective stop-off, technologies are also available for scale prevention in open-fired furnaces. This article describes two stop-off technologies, mechanical masking and copper plating, along with stop-off paints/compounds. Prior to the application of stop-off paints, the part surface of the furnaces should be properly cleaned and dried. The article also describes the usage of stop-off paints in different heat treating processes, namely, carburizing and carbonitriding, deep carburizing, vacuum carburizing, nitriding and nitrocarburizing, and plasma nitriding. The article concludes by reviewing the application methods of stop-off paints: brushing, dipping, dispensing, spraying and stamping.

Cermets are a group of powder metallurgy products consisting of ceramic particles bonded with a metal. This article describes the composition and microstructure of titanium carbide and titanium carbonitride cermets. It tabulates typical properties of titanium carbonitride cermets and compares the properties of cermets and cemented carbides. The article also summarizes the applications of cermet cutting tools.

Surface hardening improves the wear resistance of steel parts. This article focuses exclusively on the methods that involve surface and subsurface modification without any intentional buildup or increase in part dimensions. These include diffusion methods, such as carburizing, nitriding, carbonitriding, and austenitic and ferritic nitrocarburizing, as well as selective-hardening methods, such as laser transformation hardening, electron beam hardening, ion implantation, selective carburizing, and surface hardening with arc lamps. The article also discusses the factors affecting the choice of these surface-hardening methods.

The selection of material for a drawing die is aimed at the production of the desired quality and quantity of parts with the least possible tooling cost per part. This article discusses the performance of a drawing die. It contains tables that list the lubricants used for deep drawing, and the typical materials for punches and blank holders. The article describes the typical causes of wear (galling) of deep-drawing tooling. It analyzes the selection of a harder and more wear-resistant material, the application of a surface coating such as chromium plating to the finished tools, and surface treatments such as carburizing or carbonitriding for low-alloy steels or nitriding or physical vapor deposition coating for tool steels.

This article discusses the metallography and microstructures of carburized, carbonitrided, and nitrided steels, with illustrations. It provides information on the widely used metallographic techniques including sectioning, mounting, grinding and polishing, and etching.

Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.

This article discusses the fracture and fatigue properties of powder metallurgy (P/M) materials depending on the microstructure. It describes the effects of porosity on the P/M processes relevant to fatigue and fracture resistance. The article details the factors determining fatigue and fracture resistance of P/M materials. It reviews the methods employed to improve fatigue and fracture resistance, including carbonitriding, surface strengthening and sealing treatments, shot-peening, case hardening, repressing and resintering, coining, sizing, and postsintering heat treatments. Safety factors for P/M materials are also detailed.

Ceramic-metal composites, or cermets, combine the heat and wear resistance of ceramics with the formability of metals, filling an application niche that includes cutting tools, brake pads, heat shields, and turbine components. This article examines a wide range of cermets, including oxide cermets, carbide and carbonitride cermets, boride cermets, and other refractory types. It describes the powder metallurgy process by which cermets are produced, examining each step from powder preparation to post treatment. It discusses forming and compacting, injection molding, extrusion, rolling, pressing, slip casting, and sintering. It also discusses fundamental concepts such as chemical bonding, chemical composition, microstructure, and the development of physical and mechanical properties.

The thermoreactive deposition and diffusion process is a heat-treatment-based method to form coatings with compacted layers of carbides, nitrides, or carbonitrides, onto some carbon/nitrogen-containing materials, including steels. The amount of active carbide forming elements/nitride forming elements, coating temperatures and time, and thickness of substrates influence the growth rate of coatings. This article lists carbide and nitride coatings that are formed on carbon/nitrogen-containing metallic materials, and describes the coating process and mechanism of coating reagents. It details the growth process and nucleation process of carbide and nitride coatings formed on the metal surface. The article discusses the advantages, disadvantages, and characteristics of the various coating processes, including high-temperature salt bath carbide coating, high-temperature fluidized-bed carbide coating, and low-temperature salt bath nitride coating.

The process of case hardening of steel includes three consecutive steps of heat treatment: heating; the thermochemical process with the enrichment of the surface area during the carburizing or carbonitriding stage with carbon and nitrogen; and the subsequent quenching process for hardening. This article provides a model-based description of the development of residual stresses during case hardening. It also describes the influence and effects of residual stresses and distortion in hardening, carburizing, and nitriding processes of the steel.

High-temperature corrosion can occur in numerous environments and is affected by various parameters such as temperature, alloy and protective coating compositions, stress, time, and gas composition. This article discusses the primary mechanisms of high-temperature corrosion, namely oxidation, carburization, metal dusting, nitridation, carbonitridation, sulfidation, and chloridation. Several other potential degradation processes, namely hot corrosion, hydrogen interactions, molten salts, aging, molten sand, erosion-corrosion, and environmental cracking, are discussed under boiler tube failures, molten salts for energy storage, and degradation and failures in gas turbines. The article describes the effects of environment on aero gas turbine engines and provides an overview of aging, diffusion, and interdiffusion phenomena. It also discusses the processes involved in high-temperature coatings that improve performance of superalloy.

This article describes the uses of the liquid carburizing process carried out in low and high temperature cyanide-containing baths, and details the noncyanide liquid carburizing process which can be accomplished in a bath containing a special grade of carbon. It presents a simple formula for estimating total case depth, and illustrates the influence of carburizing temperature, duration of carburizing, quenching temperature, and quenching medium with the aid of typical hardness gradients. The article provides information on controlling of cyaniding time and temperature, bath composition, and case depth, and presents examples that relate dimensional change to several shapes that vary in complexity. It also provides information on the quenchant removal and salt removal processes, lists the applications of liquid carburizing in cyanide baths, and discusses the process and importance of cyanide waste disposal in detail.

The surface of irons and steels can be hardened by introducing nitrogen (nitriding), nitrogen and carbon (nitrocarburizing), or nitrogen and sulfur (sulfonitriding) into the surface. This article lists the principal reasons for nitriding and nitrocarburizing, and summarizes the typical characteristics of nitriding processes along with a general comparison of carburizing processes in a table. It describes the two most common nitriding methods: gas nitriding and ion (plasma) nitriding. The article discusses the wear behavior of nitrided layers and the wear resistance of selected steels. Rolling-contact fatigue (RCF) occurs in rolling contacts such as bearings, rolls, and gears. The article provides a discussion on rolling-contact fatigue of nitrided steels for aerospace bearing components.

Nitriding is a general term for all processes based on the addition of nitrogen to the surface of steel. When carbon is added along with the nitrogen, the process is called nitrocarburizing. This article provides a detailed discussion on the functional and structural properties of nitrided layers. It describes the structural changes on the surface of carbon steels, alloy steels, and austenitic stainless steels. The article explains the effects of the various nitriding processes, namely, gaseous nitriding, plasma nitriding, gaseous nitrocarburizing, and salt bath nitrocarburizing, on the structure and properties of nitrided layers.