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Published: 27 April 2016
Fig. 6 Carbon-chromium-iron isopleth showing single-phase boundary (SPB) lines and zero-phase boundary (ZPB) lines. Source: Ref 2
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Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006231
EISBN: 978-1-62708-163-4
... Abstract This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs...
Abstract
This article describes the liquidus plots, isothermal plots, and isopleth plots used for a hypothetical ternary phase space diagram. It discusses the single-phase boundary (SPB) line and zero-phase fraction (ZPF) line for carbon-chromium-iron isopleth. The article illustrates the Gibbs triangle for plotting ternary composition and discusses the ternary three-phase phase diagrams by using tie triangles. It describes the peritectic system with three-phase equilibrium and ternary four-phase equilibrium. The article presents representative binary iron phase diagrams, showing ferrite stabilization (iron-chromium) and austenite stabilization (iron-nickel).
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006300
EISBN: 978-1-62708-179-5
... not apply to cast irons alloyed with chromium or molybdenum, which seem to affect the stable and metastable transformations in a different way than other additives, probably by strongly decreasing carbon diffusion in both austenite and ferrite. Fig. 10 Transformation of austenite to a fully pearlitic...
Abstract
This article discusses the stable and metastable three-phase fields in the binary Fe-C phase diagram. It schematically illustrates that austenite decomposition requires accounting for nucleation and growth of ferrite and then nucleation and growth of pearlite in the remaining untransformed volume. The article describes the austenite decomposition to ferrite and pearlite in spheroidal graphite irons and lamellar graphite irons. It provides a discussion on modeling austenite decomposition to ferrite and pearlite.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006295
EISBN: 978-1-62708-179-5
... components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems...
Abstract
The control of the solidification process of cast iron requires understanding and control of the thermodynamics of the liquid and solid phases and of the kinetics of their solidification, including nucleation and growth. This article addresses issues that allow for the determination of probability of formation and relative stability of various phases. These include the influence of temperature and composition on solubility of various elements in iron-base alloys; calculation of solubility lines, relevant to the construction of phase diagrams; and calculation of activity of various components. It discusses the role of alloying elements in terms of their influence on the activity of carbon, which provides information on the stability of the main carbon-rich phases of iron-carbon alloys, that is, graphite and cementite. The article reviews the carbon solubility in multicomponent systems, along with saturation degree and carbon equivalent.
Book: Fractography
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.a0007035
EISBN: 978-1-62708-387-4
... (stable) and austenite-cementite (metastable) eutectic lines Sectioning the Fe-C-Si 3-D diagram at constant silicon content leads to a so-called iron-carbon isopleth section. Figure 3 illustrates the influence of 3% silicon on the stable and metastable versions of the iron-carbon phase diagram...
Abstract
The cast iron family includes several different groups, including gray iron, ductile iron, compacted graphite iron, malleable iron, white iron, and many different grades within each of these alloy groups. This article addresses issues specific to gray iron, but in many instances the discussion can be related to the other cast iron groups and the various grades within those groups. It discusses the usage of techniques and procedures in cast iron fractography. The article presents a list of common defects that can initiate failure.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006221
EISBN: 978-1-62708-163-4
.... age hardening allotropy alloying aluminum-copper system binary system Clausius-Clapeyron equation crystal structure Gibbs phase rule heat treatment iron-carbon phase diagram Lever rule phase diagram polymorphism solid-state transformation solidification ternary diagrams Theorem of Le...
Abstract
The application of phase diagrams is instrumental in solid-state transformations for the processing and heat treatment of alloys. A unary phase diagram plots the phase changes of one element as a function of temperature and pressure. This article discusses the unary system that can exist as a solid, liquid, and/or gas, depending on the specific combination of temperature and pressure. It describes the accomplishment of conversion between weight percentage and atomic percentage in a binary system by the use of formulas. The article analyzes the effects of alloying on melting/solidification and on solid-state transformations. It explains the construction of phase diagrams by the Gibbs phase rule and the Lever rule. The article also reviews the various types of alloy systems that involve solid-state transformations. It concludes with information on the sources of phase diagram.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003085
EISBN: 978-1-62708-199-3
... of the effects of conditions of state. By “isolated,” it is meant that there is no interchange of mass with its surroundings. The substances in alloy systems, for example, might be two metals such as copper and zinc; a metal and a nonmetal such as iron and carbon; a metal and an intermetallic compound...
Abstract
Alloy phase diagrams are useful for the development, fabrication, design and control of heat treatment procedures that will produce the required mechanical, physical, and chemical properties of new alloys. They are also useful in solving problems that arise in their performance in commercial applications, thus improving product predictability. This article describes different equilibrium phase diagrams (unary, binary, and ternary) and microstructures, description terms, and general principles of reading alloy phase diagrams. Further, the article discusses plotting schemes; areas in a phase diagram; and the position and shapes of the points, lines, surfaces, and intersections, which are controlled by thermodynamic principles and properties of all phases that comprise the system. It also illustrates the application of the stated principles with suitable phase diagrams.
Series: ASM Handbook
Volume: 22B
Publisher: ASM International
Published: 01 November 2010
DOI: 10.31399/asm.hb.v22b.a0005511
EISBN: 978-1-62708-197-9
... because they increase the β transus temperature, while vanadium, iron, molybdenum, chromium, niobium, nickel, copper, tantalum, and hydrogen are β stabilizers because they decrease the β transus. Technical multicomponent titanium alloys are classified as α, β, and α-β alloys, depending on the relative...
Abstract
This article focuses on the industrial applications of phase diagrams. It presents examples to illustrate how a multicomponent phase diagram calculation can be readily useful for industrial applications. The article demonstrates how the integration of a phase diagram calculation with kinetic and microstructural evolution models greatly enhances the power of the CALPHAD approach in materials design and processing development. It also discusses the limitations of the CALPHAD approach.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006566
EISBN: 978-1-62708-290-7
... to achieve the desired properties, such as martensitic precipitation-hardening stainless steels and maraging steels. In a study of as-built 17-4 PH, Cheruvathur et al. ( Ref 26 ) reported that iron and chromium are enriched in the dendritic cores, and niobium and carbon are enriched in the interdendritic...
Abstract
This article provides a general overview of additively manufactured steels and focuses on specific challenges and opportunities associated with additive manufacturing (AM) stainless steels. It briefly reviews the classification of the different types of steels, the most common AM processes used for steel, and available powder feedstock characteristics. The article emphasizes the characteristics of the as-built microstructure, including porosity, inclusions, and residual stresses. It also reviews the material properties of AM steel parts, including hardness, tensile strength, and fatigue strength, as well as environmental properties with respect to corrosion resistance, highlighting the importance of postbuild thermal processing.
Book
Series: ASM Handbook
Volume: 12
Publisher: ASM International
Published: 01 June 2024
DOI: 10.31399/asm.hb.v12.9781627083874
EISBN: 978-1-62708-387-4