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Image
Published: 01 August 2013
Fig. 5 Equilibrium percentages of carbon monoxide and carbon dioxide required to maintain various carbon concentrations at 975 °C (1790 °F) in plain carbon and certain low-alloy steels. K = 89.67. Source: Ref 7
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Published: 01 August 2013
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Published: 09 June 2014
Fig. 1 Approximate carbon monoxide and hydrogen contents of the generated atmosphere vs. the air-to-gas ratio of the feed mixture. Source: Ref 2
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Published: 09 June 2014
Fig. 19 Coil flashover caused by penetrations of carbon monoxide and vaporous sulfur. Source: Ref 24
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Published: 31 August 2017
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Published: 15 December 2019
Fig. 2 Simulated peaks for nitrogen (N 2 ) and carbon monoxide (CO) at instrument mass resolving powers of 1000, 2500, and 5000. m/z , mass-to-charge ratio
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Book Chapter
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005765
EISBN: 978-1-62708-165-8
... Abstract Pack carburizing is a process in which carbon monoxide derived from a solid compound decomposes at the metal surface into nascent carbon and carbon dioxide. In addition to discussing the pros and cons of pack carburizing, this article provides information on the carburizing medium...
Abstract
Pack carburizing is a process in which carbon monoxide derived from a solid compound decomposes at the metal surface into nascent carbon and carbon dioxide. In addition to discussing the pros and cons of pack carburizing, this article provides information on the carburizing medium, compounds, furnaces, and containers used in pack carburizing. The successful operation of the pack carburizing process depends on the control of principal variables such as carbon potential, temperature, time, case depth, and steel composition. The three types of furnaces most commonly used for pack carburizing are the box, car-bottom, and pit types. Carburizing containers are made of carbon steel, aluminum-coated carbon steel, or iron-nickel-chromium heat-resisting alloys. The article also provides information on the packing procedure of workpieces.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005799
EISBN: 978-1-62708-165-8
... process based on the control of three principal variables: temperature, atmosphere composition or carbon potential, and time. The article also describes the selection criteria for alloy, carbon sources, atmosphere types, and carbon monoxide level for endothermic carburizing atmospheres. It provides...
Abstract
This article describes the thermodynamics and kinetics of gas carburizing reactions, and details the mass transfer mechanism during gas carburizing. It discusses the various considerations involved in carburizing process planning, and reviews successful operation of the gas carburizing process based on the control of three principal variables: temperature, atmosphere composition or carbon potential, and time. The article also describes the selection criteria for alloy, carbon sources, atmosphere types, and carbon monoxide level for endothermic carburizing atmospheres. It provides information on carburizing modeling, case depth prediction, case depth measurement, and case depth evaluation as well as on carburizing equipment, and also covers the factors affecting distortion after carburizing.
Series: ASM Handbook
Volume: 1
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v01.a0001050
EISBN: 978-1-62708-161-0
... in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy...
Abstract
The initial cast superalloy developments in the United States centered on cobalt-base materials. Nickel-base and nickel-iron-base superalloys owe their high-temperature strength potential to their gamma prime content. For polycrystalline superalloy components, high-temperature strength is affected by the condition of the grain boundaries and, in particular, the grain-boundary carbide morphology and distribution. Vacuum induction melting offers more control over alloy composition and homogeneity than all other vacuum melting processes. The primary purification reaction occurring in the process is the removal of melt contained oxygen by means of a reaction with carbon to form carbon monoxide. A number of casting processes can provide near-net shape superalloy cast parts, but essentially all components are produced by investment casting. The solidification of investment cast superalloy components is precisely controlled so that the microstructure, which ultimately determines mechanical properties, remains consistent. Heat treating cast superalloys involves homogenization and solution heat treatments or aging heat treatments.
Series: ASM Handbook
Volume: 4C
Publisher: ASM International
Published: 09 June 2014
DOI: 10.31399/asm.hb.v04c.a0005893
EISBN: 978-1-62708-167-2
... Abstract This article describes the effects of furnace atmospheric elements, including air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide, on steels. It provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas...
Abstract
This article describes the effects of furnace atmospheric elements, including air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide, on steels. It provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas Association on the basis of the method of preparation or on the original constituents employed. These groups are designated and defined as follows: Class 100, exothermic base; Class 200, prepared nitrogen base; Class 300, endothermic base; Class 400, charcoal base; Class 500, exothermic-endothermic base; and Class 600, ammonia base. These are subclassified and numerically designated to indicate variations in the method by which they are prepared. The article also contains a table that lists significant furnace atmospheres and typical applications.
Book Chapter
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005983
EISBN: 978-1-62708-166-5
... Abstract This article describes the effects of furnace atmospheric elements on steels. These elements are air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide. The article provides useful information on six groups of commercially important prepared atmospheres classified...
Abstract
This article describes the effects of furnace atmospheric elements on steels. These elements are air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide. The article provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas Association on the basis of method of preparation or on the original constituents employed. These groups are designated and defined as follows: Class 100, exothermic base; Class 200, prepared nitrogen base; Class 300, endothermic base; Class 400, charcoal base; Class 500, exothermic-endothermic base; and Class 600, ammonia base. These are subclassified and numerically designated to indicate variations in the method by which they are prepared. The article also contains a table that lists significant furnace atmospheres and their typical applications.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003050
EISBN: 978-1-62708-200-6
... and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide. ceramic environmental regulations glass in-process scrap industrial waste recycling LIKE MOST OTHER...
Abstract
Ceramic and glass manufacturers take environmental regulations into consideration during all stages of the product cycle, from research and development to purchasing, processing, end use, and disposal. Ceramic and glass products are finding application in the construction industry and as raw materials for other processes. This article describes the recycling of in-process scrap and industrial wastes (fly ash, red mud, metallurgical waste, and other waste products), and applications of these recycled products. It focuses on environmental regulations such as Resource Conservation and Recovery Act and Clean Air Act. The Clean Air Act requires all states to meet minimum emissions standards for nitrogen-oxygen compounds, volatile organic compounds, and carbon monoxide.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006137
EISBN: 978-1-62708-175-7
... out of control. Poisoning: Personnel can be poisoned by carbon monoxide, ammonia, methanol, and other toxic components in the atmosphere. Asphyxiation: “Simple” asphyxiation is possible when asphyxiants are present in high concentrations, causing the O 2 content to drop below 18% (air...
Abstract
This article discusses the requirements for safe design, installation, operation, inspection, testing, and maintenance of sintering atmosphere generators and atmosphere supply systems for both personal and environment safety. The four intrinsic dangers associated with producing and using common sintering atmosphere gases are explosion, fire, toxicity, and asphyxiation.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006135
EISBN: 978-1-62708-175-7
... equilibrium in endothermic gas at different dew points. Endo gas composition: 40% hydrogen, 20% carbon monoxide, and 40% nitrogen The degree and depth of decarburization depend on the dew point, the processing time and temperature in the hot zone, and the porosity of the steel part. Higher values...
Abstract
Sintering atmosphere protects metal parts from the effects of contact with air and provides sufficient conduction and convection for uniform heat transfer to ensure even heating or cooling within various furnace sections, such as preparation, sintering, initial cooling, and final cooling sections. This article provides information on the different zones of these furnace sections. It describes the types of atmospheres used in sintering, namely, endothermic gas, exothermic gas, dissociated ammonia, hydrogen, and vacuum. The article concludes with a discussion on the furnace zoning concept and the problems that arise when these atmospheres are not controlled.
Series: ASM Handbook
Volume: 4B
Publisher: ASM International
Published: 30 September 2014
DOI: 10.31399/asm.hb.v04b.a0005926
EISBN: 978-1-62708-166-5
... 0.1228 1.520 Carbon monoxide CO 28.01 1.250 0.0780 0.967 Helium He 4.00 0.179 0.0112 0.138 Hydrogen H 2 2.02 0.090 0.0056 0.070 Methane CH 4 16.04 0.716 0.0447 0.552 Nitrogen N 2 28.01 1.250 0.0780 0.968 Oxygen O 2 32.00 1.429 0.0892 1.105 Propane...
Abstract
This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia-based atmospheres, industrial gas nitrogen-base atmospheres, argon atmospheres, and hydrogen atmospheres. Atmospheres for backfilling, partial pressure operation, and quenching in vacuum are also discussed. Furnace atmospheres constitute four major groups of safety hazards in heat treating: fire, explosion, toxicity, and asphyxiation. The article reviews the fundamentals of principal gases and vapors. It describes how the evaluation of the atmospheric requirements of heat treating furnaces is influenced by factors such as cost of operation and capital investment.
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Published: 30 September 2014
Fig. 3 Calculated equilibrium relationship between carbon dioxide concentration and carbon content in an endothermic-based atmosphere. Carbon monoxide content is assumed to be 20%.
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Published: 30 September 2014
Fig. 12 Components of a positive-filtering infrared analyzer for measuring carbon monoxide, carbon dioxide, and methane contents of an atmosphere
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Published: 30 September 2014
Fig. 13 Components of a negative-filtering infrared analyzer for measuring carbon monoxide, carbon dioxide, and methane contents of an atmosphere
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Published: 30 September 2014
Fig. 14 Components of a solid-state detector infrared analyzer for measuring carbon monoxide, carbon dioxide, and methane contents of an atmosphere
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Published: 30 September 2015
Fig. 4 Carbon equilibrium in endothermic gas at different dew points. Endo gas composition: 40% hydrogen, 20% carbon monoxide, and 40% nitrogen
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