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carbide segregation
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in Metallography and Microstructures of Stainless Steels and Maraging Steels[1]
> Metallography and Microstructures
Published: 01 December 2004
Fig. 49 Carbide segregation in a segregation streak in 422 martensitic stainless steel. (a) and (b) Etched with glyceregia. (c) Etched 30 s with Murakami's at room temperature to darken the carbides
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Published: 01 January 2005
Fig. 4 Carbide segregation in austenitic solid-solution matrix of Fe-Ni superalloy 16-25-6 (AISI 650) alloy after forging between 650 and 705 °C (1200 and 1300 °F) and stress relieving. (a) Banding because of carbide segregation (Marble's reagent, 100×). (b) Carbide banding (same forging
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Image
Published: 01 December 2004
Fig. 3 AISI M2 round bars. Carbide segregation at the center of round bars of different diameters. (a) 27 mm (1 1 16 in.) diam. (b) 67 mm (2 5 8 in.) diam. (c) 105 mm (4 1 8 in.) diam. 10% nital. 100×
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Image
Published: 01 December 2004
Fig. 4 AISI T1 round bars. Carbide segregation at the center of round bars of different diameters. (a) 35 mm (1 3 8 in.) diam. (b) 64 mm (2 1 2 in.) diam. (c) 83 mm (3 1 4 in.) diam. 10% nital. 100×
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Published: 15 December 2019
Fig. 37 Phosphorus segregation was investigated from mating areas of carbide precipitates on grain-boundary facets of 30 HRC NiCrMoV steel. Source: Ref 107
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Series: ASM Handbook Archive
Volume: 11
Publisher: ASM International
Published: 01 January 2002
DOI: 10.31399/asm.hb.v11.a0001814
EISBN: 978-1-62708-180-1
..., unconsolidated interiors, and carbide segregation and poor carbide morphology are reviewed with illustrations. brittle fracture carbide segregation die failure dies electrical discharge machining failure mechanisms finish grinding heat treatment hot working laps machining mechanical testing...
Abstract
This article describes the characteristics of tools and dies and the causes of their failures. It discusses the failure mechanisms in tool and die materials that are important to nearly all manufacturing processes, but is primarily devoted to failures of tool steels used in cold-working and hot-working applications. It reviews problems introduced during mechanical design, materials selection, machining, heat treating, finish grinding, and tool and die operation. The brittle fracture of rehardened high-speed steels is also considered. Finally, failures due to seams or laps, unconsolidated interiors, and carbide segregation and poor carbide morphology are reviewed with illustrations.
Image
Published: 01 December 2004
Fig. 34 Alloy HW, as-cast, showing pattern of interdentritic eutectic carbide segregation. (a) 5 mL conc HCl and 1 mL conc HNO 3 . Original magnification 50×. (b) Higher magnification. Austenite matrix containing massive interdendritic eutectic carbide and some small precipitated carbide
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Published: 01 January 1989
Fig. 2 Comparison of microstructures of conventional high-speed tool steel and P/M high-speed tool steel. (a) Conventional high-speed tool steel microstructure showing carbide segregation. (b) Microstructure of P/M processed ASP steel showing small, uniformly distributed carbide particles
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Published: 01 December 2004
Fig. 20 Carbides in light-etching segregation band of AISI H13 hot work die steel (Fe-0.40%C-0.8%Si-5.25%Cr-1%V-1.35%Mo). 2% nital. 500×
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Published: 31 August 2017
Fig. 4 Irregular graphite particles, segregation carbides, and microshrinkage in a low-nodule-count area. Etched with 4% nital. Source: Ref 30
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Published: 31 August 2017
Fig. 5 Segregation carbides and microshrinkage in a low-nodule-count area. Etched with 4% nital. Source: Ref 30
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Published: 01 January 1990
Fig. 4 Microstructures of high-speed tool steels. Left: CPM T15. Right: Conventional T15. Carbide segregation and its detrimental effects are eliminated with the CPM process, regardless of the size of the products. Courtesy of Crucible Materials Corporation
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Published: 01 January 1989
Fig. 10 Microstructures of high-speed tool steels. Left: CPM T15. Right: Conventional T15. Carbide segregation and its detrimental effects are eliminated with the CPM process, regardless of the size of the products. Courtesy of Crucible Materials Corporation
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Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006129
EISBN: 978-1-62708-175-7
... Abstract This article describes the effects of undissolved carbides formed by segregation of alloying elements on the hardness of the powder-metallurgical (PM) high-alloy tool steels (HATS). It explains the calculation of exact stoichiometric carbon content that depends on the required...
Abstract
This article describes the effects of undissolved carbides formed by segregation of alloying elements on the hardness of the powder-metallurgical (PM) high-alloy tool steels (HATS). It explains the calculation of exact stoichiometric carbon content that depends on the required martensite hardness, amount of carbon forming alloying elements, types of undissolved carbides during austenitizing, and the densities of the carbides. Microhardness values for carbides in HATS are also listed.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002122
EISBN: 978-1-62708-188-7
... (wrought) processed high-speed tool and P/M processed ASP high-speed tool steel This processing results in a fine-grain material with a uniform distribution of small carbides. The homogeneous material, free from segregation, has a uniform structure, regardless of bar size and alloy content. Figure...
Abstract
This article describes procedures for producing powder metallurgy high-speed tool steel powder by inert-gas atomization, followed by compaction by hot isostatic pressing. These include the anti-segregation process (ASP) and the crucible particle metallurgy (CPM) process. The article reviews the properties of ASP and CPM and summarizes the procedures to heat treat ASP high-speed tool steels. It discusses the processing steps, advantages, and applications of the FULDENS process that uses water-atomized powders compacted by vacuum sintering. The article also provides information on the applications of tool steels.
Series: ASM Handbook
Volume: 1A
Publisher: ASM International
Published: 31 August 2017
DOI: 10.31399/asm.hb.v01a.a0006327
EISBN: 978-1-62708-179-5
.... Defects A variety of defects may appear during the production of TWDI castings, such as casting skin anomalies (e.g., flake graphite, graphite segregation), graphite clusters, exploded graphite, slag inclusions, shrinkage porosity, eutectic chill and secondary carbides, and cold shuts ( Ref 13 , 19...
Abstract
From the point of view of economics and ecology, thin-wall ductile iron (TWDI) castings can compete in terms of mechanical properties with the light castings made of aluminum alloys. This article discusses the effect of technological factors on the cooling rate and physicochemical state of the liquid metal for preparing thin-wall castings with good mechanical properties and performance while avoiding casting defects. It describes a variety of defects that may appear during the production of TWDI castings, such as casting skin anomalies (e.g., flake graphite, graphite segregation), graphite clusters, exploded graphite, slag inclusions, shrinkage porosity, eutectic chill and secondary carbides, and cold shuts. The article reviews the tensile, fatigue, impact, and wear properties of TWDI castings. It provides information on the production and applications of TWDI castings.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001423
EISBN: 978-1-62708-173-3
... and carbides (heat-affected zone grain boundaries cracking), are also discussed. The article examines the parameters that affect heat-affected zone liquation cracking and presents a solution for each problem. carbides hardening nonferrous high-temperature materials physical metallurgy segregation...
Abstract
This article focuses on the physical metallurgy of nonferrous high-temperature materials that affects weldability on the precipitates used for age hardening (strain-age cracking). Those precipitates associated with solidification and solidification segregation, primarily Laves and carbides (heat-affected zone grain boundaries cracking), are also discussed. The article examines the parameters that affect heat-affected zone liquation cracking and presents a solution for each problem.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003766
EISBN: 978-1-62708-177-1
... planes of M2 and T1 high-speed steels revealed by macroetching discs of varying diameter with 10% nital. Figure 3 and Figure 4 show the carbide segregation by light microscopy examination in three of the sizes for the M2 and T1 discs. Fig. 2 Carbide distribution on longitudinal planes of high...
Abstract
Tool steels are prepared for metallographic examination in the same way as carbon steels with a few variations owing to hardness and alloying differences. This article explains what makes tool steels different and how to compensate for it when sectioning, mounting, grinding, polishing, and etching. It provides information and data on composition, hot working, austenitizing, tempering, and powder metal manufacturing and explains how it affects tool steel microstructure, using more than 100 detailed images.
Image
Published: 31 August 2017
Fig. 15 Examples of embrittling segregated phases at cell boundaries in heavy-section ductile irons. (a) Manganese-rich carbides. (b) Molybdenum-rich carbides. (c) Steadite. (d) Zirconium-rich carbides. (e) Vanadium-rich carbides. Source: Ref 46
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Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002182
EISBN: 978-1-62708-188-7
... in both the annealed and hardened conditions. Further, the large size and the uneven distribution of the carbides (caused by ingot segregation in conventionally produced tool steels) are often unfavorable for optimum machinability. Rapid solidification of the atomized powders used in the production...
Abstract
Wrought powder metallurgy (P/M) high-speed tool steels exhibit better machinability, dimensional control and safety in heat treatment, grindability, and edge toughness during cutting. This article discusses the two stages of machining of P/M tool steels: rough machining, in annealed condition, and finish machining, in hardened-and-tempered condition. It tabulates the composition of commercial crucible particle metallurgy and anti-segregation process tool steels and their typical machining conditions.
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