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brittle intermetallics
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Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0009239
EISBN: 978-1-62708-173-3
... intermetallics, and low ductility. The article reviews induction and torch brazing, infrared brazing, diffusion brazing, and brazing by heating with ion bombardment. It concludes by describing the design criteria and limitations of brazing. alpha-beta alloys brazing brittle intermetallics carbon steel...
Abstract
This article discusses the effects of brazing temperature and thermal treatment on structure and mechanical behavior of different classes of titanium base metals such as commercially pure (CP) titanium, alpha or near-alpha alloys, alpha-beta alloys, and beta alloys. The classification, properties, and potential heat treatment of titanium base alloys are presented in tables. The article provides information on brazed joints of titanium with carbon steels, as well as ceramics and graphite. It discusses the risks involved in titanium brazing, including erosion of base metal, brittle intermetallics, and low ductility. The article reviews induction and torch brazing, infrared brazing, diffusion brazing, and brazing by heating with ion bombardment. It concludes by describing the design criteria and limitations of brazing.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005620
EISBN: 978-1-62708-174-0
... cannot be co-reduced to the extent necessary to achieve a metallurgical bond. Another characteristic that can cause problems is the tendency of some metals to form a tenacious oxide film that inhibits weld formation. Finally, some metals are thermally unstable; they form brittle intermetallic compounds...
Abstract
This article describes two methods based on rolling of sheet. The first is roll welding, where two or more sheets or plates are stacked together and then passed through rolls until sufficient deformation has occurred to produce solid-state welds. The other is laser roll welding, which is a hybrid process based on a thin-melting interface for a lap joint of dissimilar-metal sheets using a roller and one-sided laser heating. The article discusses the types, advantages, and applications of roll welding and laser roll welding. It also provides a detailed discussion on the laser roll welding of dissimilar metals.
Image
Published: 30 August 2021
Image
Published: 30 August 2021
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001450
EISBN: 978-1-62708-173-3
...). A smaller clearance also promotes improved retention of base-material properties, because of curtailed base-material erosion achieved by using a smaller volume of filler metal. The size of the grains and the extent of the brittle intermetallic phases in the parent filler metal directly affect the strength...
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0004007
EISBN: 978-1-62708-185-6
... the hydrostatic extrusion of structural alloys, composites, brittle materials, and intermetallics or intermetallic compounds, with examples. It concludes with a discussion on the attempts made to extend the hydrostatic extrusion to higher temperatures. brittle materials composites hot hydrostatic...
Abstract
This article begins with a general review of the effects of changes in stress state on processing of materials. It describes the fundamentals of hydrostatic extrusion and reviews the various issues and benefits associated with hydrostatic extrusion. The article discusses the hydrostatic extrusion of structural alloys, composites, brittle materials, and intermetallics or intermetallic compounds, with examples. It concludes with a discussion on the attempts made to extend the hydrostatic extrusion to higher temperatures.
Series: ASM Handbook
Volume: 20
Publisher: ASM International
Published: 01 January 1997
DOI: 10.31399/asm.hb.v20.a0002476
EISBN: 978-1-62708-194-8
... Abstract Brittle materials, such as ceramics, intermetallics, and graphites, are increasingly being used in the fabrication of lightweight components. This article focuses on the design methodologies and characterization of certain material properties. It describes the fundamental concepts...
Abstract
Brittle materials, such as ceramics, intermetallics, and graphites, are increasingly being used in the fabrication of lightweight components. This article focuses on the design methodologies and characterization of certain material properties. It describes the fundamental concepts and models associated with performing time-independent and time-dependent reliability analyses for brittle materials exhibiting scatter in ultimate strength. The article discusses the two-parameter and three-parameter Weibull distribution for representing the underlying probability density function for tensile strength. It reviews life prediction reliability models used for predicting the life of a component with complex geometry and loading. The article outlines reliability algorithms and presents several applications to illustrate the utilization of these reliability algorithms in structural applications.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001446
EISBN: 978-1-62708-173-3
... on the aluminum, which, being stoichiometric and highly stable, inhibits weld formation The formation of brittle intermetallics, such as the FeAl 3 and Fe 2 Al 5 types, at the joint interface These problems are generally overcome by using interlayers, both to promote welding and to prevent...
Abstract
Diffusion welding involves minimal pressurization, but relatively high temperatures and long periods of time. This article discusses the process variants of diffusion welding: solid-phase and liquid-phase processes. It describes the diffusion welding of carbon and low-alloy steels, high-strength steels, stainless steels, and aluminum-base alloys. The article provides a discussion on dissimilar metal combinations, such as ferrous-to-ferrous combinations, nonferrous-to-nonferrous combinations, ferrous-to-nonferrous combinations, and metal-ceramic joining.
Book: Fatigue and Fracture
Series: ASM Handbook
Volume: 19
Publisher: ASM International
Published: 01 January 1996
DOI: 10.31399/asm.hb.v19.a0002379
EISBN: 978-1-62708-193-1
... of aluminum alloys is related to the critical fracture strain as: (Eq 11) K Ic ≈ 2 C E ε c σ y n ( 1 − v 2 ) where C is a constant and v is the Poisson's ratio. As the volume fraction of brittle intermetallic particles is reduced, fracture toughness...
Abstract
Fracture mechanics is a multidisciplinary engineering topic that has foundations in both mechanics and materials science. This article summarizes the microstructural aspect of fracture resistance in structural materials. It provides a discussion on basic fracture principles and schematically illustrates the mechanism of crack propagation. The article describes the fracture resistance of high-strength steels, aluminum alloys, titanium alloys, and composites such as brittle matrix-ductile phase composites and metal-matrix composites. It also lists the effects of microstructural variables on fracture toughness of steels, aluminum alloys, and titanium alloys.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003155
EISBN: 978-1-62708-199-3
... high-energy plasma for thermonuclear fusion. A15 Superconductors A15 superconductors (A15 refers to a cubic crystal type in the Strukturbericht system) are brittle intermetallic compounds with the chemical formula A 3 B, where A is a transition metal and B can be either a transition metal...
Abstract
Superconductors are materials that exhibit a complete disappearance of electrical resistivity on lowering the temperature below the critical temperature. A superconducting material must exhibit perfect diamagnetism, that is, the complete exclusion of an applied magnetic field from the bulk of the superconductor. Superconducting materials that have received the most attention are niobium-titanium superconductors (the most widely used superconductor), A15 compounds (in which class the important ordered intermetallic Nb3Sn lies), ternary molybdenum chalcogenides (Chevrel phases), and high-temperature ceramic superconductors. This article provides an overview of basic principles of superconductors and the different classes of superconducting materials and their general characteristics.
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006502
EISBN: 978-1-62708-207-5
... process. The characteristic low specific energy input for this process results in a higher cooling rate. Higher cooling rates are often needed to suppress precipitation of harmful intermetallic compounds (which may promote brittle fracture) during the solidification of the weld pool. In many applications...
Abstract
Most welding lasers fall into the category of fiber, disc, or direct diode, all of which can be delivered by fiber optic. This article provides a comparison of the energy consumptions and efficiencies of laser beam welding (LBW) with other major welding processes. It discusses the two modes of laser welding: conduction-mode welding and deep-penetration mode welding. The article reviews the factors of process selection and procedure development for laser welding. The factors include power density, interaction time, laser beam power, laser beam diameter, laser beam spatial distribution, absorptivity, traverse speed, laser welding efficiency, and plasma suppression and shielding gas. The article concludes with a discussion on laser cutting, laser roll welding, and hybrid laser welding.
Series: ASM Handbook
Volume: 14B
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v14b.a0005164
EISBN: 978-1-62708-186-3
... as the thickness of the alloy layer increases. Steel producers strive to minimize the thickness and alter the phases present in the alloy layer to mitigate the effects that the brittle iron-zinc intermetallics have on the subsequent formability and coating adhesion of the material. Given proper tooling...
Abstract
This article provides an overview of some common sheet steel coatings available. It discusses the formability differences between coated and bare steel and provides some general guidelines on the forming of coated steels. Coated steels are classified according to the nature of the substrate, the type of coating, and the method used for its application. The article describes various coating types for steels such as zinc-coated steels, aluminum-coated steels, tin-coated steels, terne-coated steels, and organic-coated steels.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006828
EISBN: 978-1-62708-329-4
... can interact and form intermetallic compounds that are usually brittle. The formation of these intermetallic compounds depends on base-and filler-metal compositions, process time, and temperature. Intermetallic compounds are more likely to form when using nickel-base braze filler metals containing...
Abstract
The various methods of furnace, torch, induction, resistance, dip, and laser brazing are used to produce a wide range of highly reliable brazed assemblies. However, imperfections that can lead to braze failure may result if proper attention is not paid to the physical properties of the material, joint design, prebraze cleaning, brazing procedures, postbraze cleaning, and quality control. Factors that must be considered include brazeability of the base metals; joint design and fit-up; filler-metal selection; prebraze cleaning; brazing temperature, time, atmosphere, or flux; conditions of the faying surfaces; postbraze cleaning; and service conditions. This article focuses on the advantages, limitations, sources of failure, and anomalies resulting from the brazing process. It discusses the processes involved in the testing and inspection required of the braze joint or assembly.
Series: ASM Handbook
Volume: 11A
Publisher: ASM International
Published: 30 August 2021
DOI: 10.31399/asm.hb.v11A.a0006827
EISBN: 978-1-62708-329-4
... failure of solder joints ( Ref 36 – 38 ). Fig. 18 Intermetallic compound brittle failure of a solder joint. PCB, printed circuit board Fig. 19 Typical pad crater failure mode. Source: Ref 13 Both IMC brittle failure and pad cratering are affected by the thermal history. Thermal...
Abstract
Due to the recent requirement of higher integration density, solder joints are getting smaller in electronic product assemblies, which makes the joints more vulnerable to failure. Thus, the root-cause failure analysis for the solder joints becomes important to prevent failure at the assembly level. This article covers the properties of solder alloys and the corresponding intermetallic compounds. It includes the dominant failure modes introduced during the solder joint manufacturing process and in field-use applications. The corresponding failure mechanism and root-cause analysis are also presented. The article introduces several frequently used methods for solder joint failure detection, prevention, and isolation (identification for the failed location).
Series: ASM Handbook
Volume: 2
Publisher: ASM International
Published: 01 January 1990
DOI: 10.31399/asm.hb.v02.a0001102
EISBN: 978-1-62708-162-7
... terminated on an ordinary dislocation. Source: Ref 1 The interest in ordered intermetallics subsided in the latter part of the 1960s because of severe embrittlement problems encountered with the compounds. Most strongly ordered intermetallics are so brittle that they simply cannot be fabricated...
Abstract
Ordered intermetallic compounds based on aluminides and silicides constitute a unique class of metallic materials that have promising physical and mechanical properties for structural applications at elevated temperatures. This article provides useful information on mechanical and metallurgical properties, material processing and fabrication, structural applications, mechanical behavior, environmental embrittlement, alloying effects, and crystal structure of aluminides of nickel, iron, titanium, and silicides. It describes the cleavage and intergranular fracture in trialuminides.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003834
EISBN: 978-1-62708-183-2
..., aluminum alloys, and the refractory metals. However, there are exceptions, such as when the oxide film on the metal surface is very thin and dense and its hardness is much higher than that of the base metal. Finally, some combinations of metals are thermally unstable and form brittle intermetallic...
Abstract
This article describes the principal cladding processes and methods for calculating properties of clad metals. It reviews the designing processes of clad metals to achieve specific requirements. The article discusses six categories of clad metal systems designed for corrosion control: noble metal clad systems, corrosion barrier systems, sacrificial metal systems, transition metal systems, complex multilayer systems, and clad diffusion alloys.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001449
EISBN: 978-1-62708-173-3
... in this instance. In metallurgically incompatible systems, however, this upper boundary (4A) becomes very sharply defined because it corresponds to the energy level at which a brittle intermetallic compound begins to form. Welding at or above this limit produces a weld that is typically brittle and can fail...
Abstract
Explosion welding (EXW), like all other welding or joining processes, has a well defined set of input parameters or conditions that must fall within certain limits for the desired weld quality to be achieved. This article provides an overview of the important mechanistic aspects of EXW, the process-material interactions, and the critical aspects or parameters that must be controlled. The commercially used metals and alloys that can be joined with EXW are listed in a table. The article concludes with a discussion on parametric limits for EXW.
Series: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003776
EISBN: 978-1-62708-177-1
... for 2 h prior to quenching in water at room temperature. Precipitations of an interdendritic light-colored silver-rich, silicon-free phase and a dark-gray-colored brittle intermetallic (Cu,Au)5Si are noted. The intermetallic is a result of the increasing concentration of silicon in the residual liquid...
Abstract
This article explains how to prepare precious metal test samples for metallographic examination. It discusses cutting, mounting, grinding, polishing, and etching and addresses some of the challenges of working with small, relatively soft specimens. It includes dozens of example micrographs, comparing and contrasting the microstructural features of gold, platinum, iridium, palladium, and ruthenium-base alloys. It examines pure gold, intermetallic gold compounds, gold and platinum jewelry alloys, platinum-containing shape memory alloys, and alloys consisting of platinum, aluminum, and copper.
Series: ASM Handbook
Volume: 8
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.hb.v08.a0003255
EISBN: 978-1-62708-176-4
... ceramics and glasses brittle at ambient temperatures, resulting in little tolerance for stress concentrations (e.g., holes, cracks, and flaws) and usually in catastrophic failure during tensile or shear loading. Intermetallic Compounds In some cases, intermetallic compounds can form within alloys...
Abstract
This article reviews the fundamental relationships between microstructure and mechanical properties for major classes of nonmetallic engineering materials: metals, ceramics and glasses, intermetallic compounds, polymers, and composites. It details the structures of inorganic crystalline solids, inorganic noncrystalline solids, and polymers. The article describes the various strengthening mechanisms of crystalline solids, namely, work hardening, solid-solution hardening, particle/precipitation hardening, and grain size hardening. Deformation and strengthening of composite materials, polymers, and glasses are reviewed. The article concludes with information on the two important aspects of the mechanical behavior of any class of engineering material: fatigue response and fracture resistance.
Image
Published: 01 January 1993
Fig. 16 A crack propagated along the interface between carbon steel and BTi-5 joint metal due to formation of brittle (Ti,Zr)Fe 2 intermetallic layer. Original magnification: 100×
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