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Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006511
EISBN: 978-1-62708-207-5
... Abstract Chemical brightening (bright dipping) and electrolytic brightening (electropolishing) are essentially selective-dissolution processes, in which the high points of a rough surface of aluminum are attacked more rapidly than the depressions, and the peaks and valleys are smoothed...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001308
EISBN: 978-1-62708-170-2
..., and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001314
EISBN: 978-1-62708-170-2
... of a layer of reduced oxide, sometimes followed by a flash pickle to brighten; and black or dark-colored surface requiring removal of adherent oxide film or scale. The article also reviews specialized pickling operations of nickel alloys and various cleaning and finishing operations, including grinding...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001247
EISBN: 978-1-62708-170-2
... Abstract Electrodeposits of cadmium are used to protect steel and cast iron against corrosion. This article provides an overview of the surface preparation of, and brighteners used in, cyanide baths. It focuses on the anode system, current density, deposition rates, and bath temperature...
Book Chapter

By A. Sato
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001248
EISBN: 978-1-62708-170-2
... Sodium cyanide 42 5.6 30–41 4.0–5.5 20 2.7 15–28 2.0–3.7 Sodium hydroxide 79 10.5 68–105 9.0–14.0 75 10.0 60–90 8.0–12.0 Sodium carbonate 15 2.0 15–60 2.0–8.0 15 2.0 15–60 2.0–8.0 Sodium polysulfide 2 0.3 2–3 0.3–0.4 2 0.3 2–3 0.3–0.4 Brightener (g) (g...
Image
Published: 01 January 1994
Fig. 8 Effect of anodizing conditions on specular reflectance of chemically brightened aluminum. Data are for a 5 μm (0.2 mil) anodic coating on 5457 alloy. (a) 17 wt% H 2 SO 4 . (b) 8.8 wt% H 2 SO 4 More
Image
Published: 01 January 1987
Fig. 615 Higher-magnification view of fracture surface in Fig. 614 . This bloom fractured during rolling, splitting apart and wrapping itself around the roll. Note lack of deformation of grains. The fracture surface was cleaned with H 2 SO 4 and was brightened with a solution containing HNO More
Image
Published: 01 January 1994
Fig. 6 Operations sequence in sulfuric acid anodizing of automotive bright trim Solution No. Type of solution Composition Operating temperature Cycle time, min °C °F 1 Alkaline cleaning Alkali, inhibited 60–71 140–160 2–4 2 Chemical brightening H 3 PO 4 and HNO 3 More
Image
Published: 01 December 1998
Fig. 2 Operations sequence in sulfuric acid anodizing of automotive bright trim Solution No. Type of solution Composition Operating temperature Cycle time, min °C °F 1 Alkaline cleaning Alkali, inhibited 60–71 140–160 2–4 2 Chemical brightening H 3 PO 4 and HNO 3 More
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001245
EISBN: 978-1-62708-170-2
... be described by the following three terms: carriers , auxiliary brighteners , and brighteners. The terminology is not standardized, however, and alternative terms mentioned in the literature are shown in parentheses. Carriers (Brighteners of the First Class, Secondary Brighteners, Control Agents...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001250
EISBN: 978-1-62708-170-2
... deposit on a cathode. Therefore, a grain-refining addition agent (such as gelatin or peptone) must be used. Usually, such materials are not directly soluble in a water solution, and a wetting-agent type of material (such as β-naphthol) is also necessary. Organic brighteners can be added if a bright...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001281
EISBN: 978-1-62708-170-2
... of anodic coatings depends on the condition of the base metal before anodizing. Dull etching decreases luster; bright etching, chemical or electrolytic brightening, and buffing increase luster, either diffuse or specular. Most of the aluminum used in architectural applications is anodized. Increase...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001253
EISBN: 978-1-62708-170-2
.... For minimum porosity and subtle color matches, even a 30 s plate may be duplex plated from two different solutions. For flash barrel plating the gold concentration can be as low as 0.8 g/L, the free cyanide is 7.5 g/L, the dipotassium phosphate should be 75 g/L or above, and nickel, as a brightener, should...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001242
EISBN: 978-1-62708-170-2
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003215
EISBN: 978-1-62708-199-3
..., especially when higher plating rates are used. Bright Nickel Plating and Multilayer Plating Bright Nickel Plating Baths Bright nickel plating baths are modifications of the Watts nickel solution and contain organic or combined organic and inorganic brightening agents; these additions serve...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001258
EISBN: 978-1-62708-170-2
... using a high iron concentration in the solution. A typical solution is given in Table 1 ( Ref 4 ). Addition agents include stabilizers for the ferrous iron, organic brighteners, leveling agents, and wetting agents. Total iron includes ferrous and ferric ions, and it is important to control the ratio...
Series: ASM Handbook
Volume: 2A
Publisher: ASM International
Published: 30 November 2018
DOI: 10.31399/asm.hb.v02a.a0006489
EISBN: 978-1-62708-207-5
... on aluminum products. The process may be used for final finishing, but it is more often used as an intermediate step prior to anodizing, conversion coating, lacquering, or other finishing treatments. Chemical etching also is used in conjunction with buffing or chemical brightening. The advantage...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001262
EISBN: 978-1-62708-170-2
... do not respond as they do under conventional power; in a high-frequency pulse field, their molecular size is a disadvantage. Small-molecule organics or inorganics will generally function well as additives. In many cases, the use of brighteners can be reduced as much as 90% without diminishing...
Book Chapter

By Alan Blair
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001252
EISBN: 978-1-62708-170-2
...., on a rack or in a barrel). It is possible to produce fully bright deposits that require no further buffing or polishing. This is achieved by including a brightening agent in the solution formula, (one of several sulfur-bearing organic compounds, or selenium or antimony added as soluble salts). Antimony...
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001255
EISBN: 978-1-62708-170-2
...-pH brass plating solutions. Ammonia serves as a brightener and improves the appearance of plating accomplished at both high and low current densities. Ammonia is formed during plating by the decomposition of cyanide and is usually stable at temperatures up to 30 °C (86 °F). Higher temperatures...