Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a soft and ductile metal binder. The performance of cemented carbide as a cutting tool lies between that of tool steel and cermets. Almost 50% of the total production of cemented carbides is used for nonmetal cutting applications. Their properties also make them appropriate materials for structural components, including plungers, boring bars, powder compacting dies and punches, high-pressure dies and punches, and pulverizing hammers. This article discusses the manufacture, microstructure, composition, classifications, and physical and mechanical properties of cemented carbides, as well as their machining and nonmachining applications. It examines the relationship between the workpiece material, cutting tool and operational parameters, and provides suggestions to simplify the choice of cutting tool for a given machining application. It also examines new tool geometries, tailored substrates, and the application of thin, hard coatings to cemented carbides by chemical vapor deposition and physical vapor deposition. It discusses the tool wear mechanisms and the methods available for holding the carbide tool. The article is limited to tungsten carbide cobalt-base materials.

Cemented carbides belong to a class of hard, wear-resistant, refractory materials in which the hard carbide particles are bound together, or cemented, by a ductile metal binder. Cermet refers to a composite of a ceramic material with a metallic binder. This article discusses the manufacture, composition, classifications, and physical and mechanical properties of cemented carbides. It describes the application of hard coatings to cemented carbides by physical or chemical vapor deposition (PVD or CVD). Tungsten carbide-cobalt alloys, submicron tungsten carbide-cobalt alloys, and alloys containing tungsten carbide, titanium carbide, and cobalt are used for machining applications. The article also provides an overview of cermets used in machining applications.

Additive manufacturing is a collection of manufacturing processes, each of which builds a part additively based on a digital solid model. The solid model-to-additive manufacturing interface and material deposition are entirely computer-controlled. The traditional additive manufacturing applications have been used for low production runs of parts with complex shapes and geometric features. Additive manufacturing is also used for topology optimization and it impacts the process and supply chain. This article discusses processes, including vat photopolymerization, material jetting, powder bed fusion, directed energy deposition, material extrusion, binder jetting, and sheet lamination.

This article focuses on binder-jetting technologies in additive manufacturing (AM) that produce metal artifacts either directly or indirectly. The intent is to focus on the most strategic and widespread uses of the binder jetting technology and review some of the challenges and opportunities for that technology. The discussion includes a historical overview and covers the major steps involved and the advantages of using the binder jetting process. The major steps of the process covered include printing, curing, de-powdering, and sintering.

Submerged arc welding (SAW) is suited for applications involving long, continuous welds. This article describes the operating principle, application, advantages, limitations, power source, equipment, and fluxes in SAW. It reviews three different types of electrodes manufactured for SAW: solid, cored, and strip. The article highlights the factors to be considered for controlling the welding process, including fit-up of work, travel speed, and flux depth. It also evaluates the defects that occur in SAW: lack of fusion, slag entrapment, solidification cracking, and hydrogen cracking. Finally, the article provides information on the safety measures to be followed in this process.

This article describes eight stages of the atomistic film growth: vaporization of the material, transport of the material to the substrate, condensation and nucleation of the atoms, nuclei growth, interface formation, film growth, changes in structure during the deposition, and postdeposition changes. It also discusses the effects and causes of growth-related properties of films deposited by physical vapor deposition processes, including residual film stress, density, and adhesion.

Tungsten, molybdenum, and cemented carbide parts can be produced using several additive manufacturing technologies. This article classifies the most relevant technologies into two groups based on the raw materials used: powder-bed methods, such as selective laser melting, electron beam melting, and binder jet three-dimensional (3-D) printing, and feedstock methods, such as fused-filament fabrication and thermoplastic 3-D printing. It discusses the characteristics, processing steps, properties, advantages, limitations, and applications of these technologies.

Submerged arc welding (SAW) is an arc welding process in which the arc is concealed by a blanket of granular and fusible flux. This article provides a schematic illustration of a typical setup for automatic SAW and discusses the advantages and limitations and the process applications of SAW. The article discusses flux classification relative to production method, relative to effect on alloy content of weld deposit, and relative to basicity index. It describes the procedural variations and the effect of weld current, weld voltage, electrical stickout, travel speed, and flux layer depth on weld bead characteristics. The article concludes with information on weld defects, such as lack of fusion, slag entrapment, solidification cracking, hydrogen cracking, or porosity.

This article discusses the mechanical properties of soft-interlayer solid-state welds and the implications of these behaviors to service stress states and environments. It illustrates the microstructure of as-deposited coatings and solid-state-welded interlayers. The article reviews factors that affect the tensile loading of strength of soft-interlayer welds: the interlayer thickness, the interlayer strain, and the interlayer fabrication method. It also provides information on stress-corrosion cracking of interlayers and stress behavior of these interlayers during shear and multiaxial loading.

Soft-interlayer solid-state welds that join stronger base metals have unique mechanical properties that are of fundamental interest and may be of critical importance to designers. This article discusses the mechanical properties of soft-interlayer solid-state welds and the implications of these behaviors to service stress states and environments. It describes the tensile loading of soft-Interlayer welds in terms of the effect of interlayer thickness on stress, interlayer strain, time-dependent failure, effect of base-metal properties, and effect of interlayer fabrication method. The article concludes with a discussion on multiaxial loading.

Nanotechnology and smart-coating technologies have been reported to show great promise for improved performance in critical areas such as corrosion resistance, durability, and conductivity. This article exemplifies nanofilms and nanomaterials used in coatings applications, including carbon nanotubes, silica, metals/metal oxides, ceramics, clays, buckyballs, graphene, polymers, titanium dioxide, and waxes. These can be produced by a variety of methods, including chemical vapor deposition, plasma arcing, electrodeposition, sol-gel synthesis, and ball milling. The application of nanotechnology and the development of smart coatings have been dependent largely on the availability of analytical and imaging techniques such as Raman spectroscopy, scanning and transmission electron microscopy, atomic force microscopy, and scanning tunneling microscopy.

This article provides an overview of metal additive manufacturing (AM) processes and describes sources of failures in metal AM parts. It focuses on metal AM product failures and potential solutions related to design considerations, metallurgical characteristics, production considerations, and quality assurance. The emphasis is on the design and metallurgical aspects for the two main types of metal AM processes: powder-bed fusion (PBF) and directed-energy deposition (DED). The article also describes the processes involved in binder jet sintering, provides information on the design and fabrication sources of failure, addresses the key factors in production and quality control, and explains failure analysis of AM parts.

Carbon-carbon is a unique composite material in which a nonstructural carbonaceous matrix is reinforced by carbon fibers to create a heat-resistant structural material that finds application in the aerospace and defense industries. This article provides a detailed account of the fundamentals of protecting carbon-carbon composites and explains the various coating deposition techniques, namely, pack cementation, chemical vapor deposition, and slurry coatings. It includes information on the practical limitations of coatings for the carbon-carbon composites.

Additive manufacturing produces a change in the shape of a substrate by adding material progressively. This article discusses the simulation of laser deposition and three principal thermomechanical phenomena during the laser deposition process: absorption of laser radiation; heat conduction, convection, and phase change; and elastic-plastic deformation. It provides a description of four sets of data used for modeling and simulation of additive manufacturing processes, namely, material constitutive data, solid model, initial and boundary conditions, and laser deposition process parameters. The article considers three aspects of simulation of additive manufacturing: simulation for initial selection of process parameter setup, simulation for in situ process control, and simulation for ex situ process optimization. It also presents some examples of computational mechanics solutions for automating various components of additive manufacturing simulation.

Hardfacing is a form of surfacing that is applied for the purpose of reducing wear, abrasion, impact, erosion, galling, or cavitation. This article describes the deposition of hardfacing alloys by oxyfuel welding, various arc welding methods, laser welding, and thermal spray processes. It discusses the categories of hardfacing alloy, such as build-up alloys, metal-to-metal wear alloys, metal-to-earth abrasion alloys, tungsten carbides, and nonferrous alloys. A summary of the selection guide for hardfacing alloys is presented in a table. The article describes the procedures for stainless steel weld cladding and the factors influencing joint integrity in dissimilar metal joining. It concludes with a discussion on joining carbon and low-alloy steels to various dissimilar materials (both ferrous and nonferrous) by arc welding.

Hardfacing is defined as the application of a wear-resistant material, in depth, to the vulnerable surfaces of a component by a weld overlay or thermal spray process Hardfacing materials include a wide variety of alloys, carbides, and combinations of these materials. Iron-base hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type alloys. Hardfacing applications for wear control vary widely, ranging from very severe abrasive wear service, such as rock crushing and pulverizing to applications to minimize metal-to-metal wear. This article discusses the types of hardfacing alloys, namely iron-base alloys, nonferrous alloys, and tungsten carbides, and their applications and advantages.

This article addresses the effects of damage to equipment and structures due to explosions (blast), fire, and heat as well as the methodologies that are used by investigating teams to assess the damage and remaining life of the equipment. It discusses the steps involved in preliminary data collection and preparation. Before discussing the identification, evaluation, and use of explosion damage indicators, the article describes some of the more common events that are considered in incident investigations. The range of scenarios that can occur during explosions and the characteristics of each are also covered. In addition, the article primarily discusses level 1 and level 2 of fire and heat damage assessment and provides information on level 3 assessment.

This article describes the manufacture, post-processing, fabrication, and properties of carbon-carbon composites (CCCs). Manufacturing techniques with respect to the processibility of different geometries of two-directional and multiaxial carbon fibers are listed in a table. The article discusses matrix precursor impregnants, liquid impregnation, and chemical vapor infiltration (CVI) for densification of CCCs. It presents various coating approaches for protecting CCCs, including pack cementation, chemical vapor deposition, and slurry coating. Practical limitations of coatings are also discussed. The article concludes with information on the mechanical properties of CCCs.

Metals and alloy powders are used in welding, hardfacing, brazing, and soldering applications, which include hardface coatings, the manufacturing of welding stick electrodes and flux-cored wires, and additives in brazing pastes or creams. This article reviews these applications and the specific powder properties and characteristics they require.

Electroless, or autocatalytic, metal plating is a nonelectrolytic method of deposition from solution that can be plated uniformly over all surfaces, regardless of size and shape. The plating's ability to plate onto nonconductors is an advantage that contributes to the choice of electroless copper in various applications. This article provides information on the bath chemistry and deposit properties of electroless copper and discusses the applications of electroless copper plating, such as printed wiring boards, decorative plating-on-plastic, electromagnetic interference shielding, and hybrid and other advanced applications. It describes two commercial processes, pretreatment and post-treatment. The article reviews the solutions used, controls and control equipment, and performance criteria of electroless copper plating. It concludes with information on the environmental and safety issues associated with electroless copper plating.