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Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003218
EISBN: 978-1-62708-199-3
...–12.5 μm (0.1–0.5 mil) >70 (a) Alloy steels, tools steels Produces a thin carbide (TiC) case for high resistance wear; temperature may cause distortion Boriding Diffused boron, boron compounds 400–1150 (750–2100) 12.5–50 μm (0.5–2 mils) 40–70 Alloy steels, tool steels Produces a hard...
Abstract
Chemical vapor deposition (CVD) involves the formation of a coating by the reaction of the coating substance with the substrate. Serving as an introduction to CVD, the article provides information on metals, ceramics, and diamond films formed by the CVD process. It further discusses the characteristics of different pack cementation processes, including aluminizing, siliconizing, chromizing, boronizing, and multicomponent coating.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001305
EISBN: 978-1-62708-170-2
... implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed. acid cleaning acid descaling alkaline cleaning boriding buffing carburizing...
Abstract
Passivation; pickling, that is, acid descaling; electropolishing; and mechanical cleaning are important surface treatments for the successful performance of stainless steel used for piping, pressure vessels, tanks, and machined parts in a wide variety of applications. This article provides an overview of the various types of stainless steels and describes the commonly used cleaning methods, namely, alkaline cleaning, emulsion cleaning, solvent cleaning, vapor degreasing, ultrasonic cleaning, and acid cleaning. Finishing operations of stainless steels, such as grinding, polishing, and buffing, are reviewed. The article also explains the procedures of electrocleaning, electropolishing, electroplating, painting, surface blackening, coloring, terne coatings, and thermal spraying. It includes useful information on the surface modification of stainless steels, namely, ion implantation and laser surface processing. Surface hardening techniques, namely, nitriding, carburizing, boriding, and flame hardening, performed to improve the resistance of stainless steel alloys are also reviewed.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005207
EISBN: 978-1-62708-187-0
.... Nucleation during solidification is a thermally activated process involving a fluctuational growth in the sizes of clusters of solids. The article describes nucleation phenomenon such as homogeneous nucleation and heterogeneous nucleation. It discusses various grain refinement models, such as carbide-boride...
Abstract
This article discusses selected highlights of thermodynamic relationships during solidification and nucleation kinetics behavior in connection with the basis of nucleation treatments, such as grain refinement and inoculation, to provide a summary of nucleation phenomena during casting. Nucleation during solidification is a thermally activated process involving a fluctuational growth in the sizes of clusters of solids. The article describes nucleation phenomenon such as homogeneous nucleation and heterogeneous nucleation. It discusses various grain refinement models, such as carbide-boride model, free growth model, and constitutional undercooling model. The article concludes with a section on thermal analysis techniques for assessing grain-refining characteristics during master alloy processing.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003059
EISBN: 978-1-62708-200-6
... Abstract This article provides crystallographic and engineering data for single oxide ceramics, zirconia, silicates, mullite, spinels, perovskites, borides, carbides, silicon carbide, boron carbide, tungsten carbide, silicon-nitride ceramics, diamond, and graphite. It includes data on crystal...
Abstract
This article provides crystallographic and engineering data for single oxide ceramics, zirconia, silicates, mullite, spinels, perovskites, borides, carbides, silicon carbide, boron carbide, tungsten carbide, silicon-nitride ceramics, diamond, and graphite. It includes data on crystal structure, density, mechanical properties, physical properties, electrical properties, thermal properties, and magnetic properties.
Book Chapter
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003842
EISBN: 978-1-62708-183-2
..., oxide ceramics, non-silica forming nitrides, carbides, and borides. The performance of environmental barrier coatings by material type is also discussed. The article also explains the effects of oxidation and corrosion on the mechanical properties of ceramic-matrix composites. It concludes with...
Abstract
This article examines the high-temperature oxidation of silica-forming ceramics under constant temperature and cyclic conditions. The effects of water vapor, impurities, and molten salts are discussed. The article describes the oxidation and corrosion of silica-forming composites, oxide ceramics, non-silica forming nitrides, carbides, and borides. The performance of environmental barrier coatings by material type is also discussed. The article also explains the effects of oxidation and corrosion on the mechanical properties of ceramic-matrix composites. It concludes with information on high-temperature applications, wear properties, and the microscopic analyses of advanced ceramics.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003162
EISBN: 978-1-62708-199-3
... hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type...
Abstract
Hardfacing is defined as the application of a wear-resistant material, in depth, to the vulnerable surfaces of a component by a weld overlay or thermal spray process Hardfacing materials include a wide variety of alloys, carbides, and combinations of these materials. Iron-base hardfacing alloys can be divided into pearlitic steels, austenitic (manganese) steels, martensitic steels, high-alloy irons, and austenitic stainless steel. The types of nonferrous hardfacing alloys include cobalt-base/carbide-type alloys, laves phase alloys, nickel-base/boride-type alloys, and bronze type alloys. Hardfacing applications for wear control vary widely, ranging from very severe abrasive wear service, such as rock crushing and pulverizing to applications to minimize metal-to-metal wear. This article discusses the types of hardfacing alloys, namely iron-base alloys, nonferrous alloys, and tungsten carbides, and their applications and advantages.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001318
EISBN: 978-1-62708-170-2
... temperature range, 1700 to 2200 °C (3092 to 3992 °F), refractory carbides and borides have been used for short time periods. Coating deposition techniques that have been used include pack cementation, CVD, and slurry processes. Coating architectures are normally built using combinations of these techniques...
Abstract
Coating technology for carbon-carbon has been driven primarily by the aerospace and defense industries, in applications where the composite is exposed to high-temperature oxidizing environments. The most notable application of coated carbon-carbon is for the nose cap and wing leading edges of the Shuttle Orbiter vehicle. This article details the fundamentals of protecting carbon-carbon composites. It explains various coating deposition techniques: pack cementation, chemical vapor deposition, and slurry coatings. The article discusses typical coating architectures in accordance with the process used to deposit the primary oxygen barrier. It also provides information on the practical limitations of coatings for the composites.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005302
EISBN: 978-1-62708-187-0
.... The second key is to realize that boron (boride particles) is an extremely powerful nucleant in all casting alloys. Boron is much more effective than titanium. Thus, it makes more sense to say that grain refinement is accomplished with boron. It then becomes a question of which combination of...
Abstract
Grain refinement in aluminum casting alloys tends to reduce the amount of porosity and the size of the pores and to improve mechanical properties, especially fatigue strength. This article provides information on measurement of grain size in alloys and describes the mechanisms of grain refinement in aluminum casting alloys. It reviews the use of boron and titanium as a grain refiner for aluminum casting alloys. The article discusses the best practices for grain refinement in various aluminum casting alloys. These include aluminum-silicon casting alloys, aluminum-silicon-copper casting alloys, aluminum-silicon-copper casting alloys, aluminum-zinc-magnesium casting alloys, and aluminum-magnesium casting alloys. The article also discusses benefits of grain refinement in aluminum casting alloys.
Series: ASM Handbook
Volume: 14A
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v14a.a0003976
EISBN: 978-1-62708-185-6
... can be accomplished using a gaseous, liquid, or plasma medium. The plasma technique (ion nitriding) appears very attractive because the formation of brittle white layers, which are unavoidable in other nitriding processes, can be eliminated or at least minimized. Boriding of die surfaces can also be...
Abstract
This article describes die wear and failure mechanisms, including thermal fatigue, abrasive wear, and plastic deformation. It summarizes the important attributes required for dies and the properties of the various die materials that make them suitable for particular applications. Recommendations on the selection of the materials for hot forging, hot extrusion, cold heading, and cold extrusion are presented. The article discusses the methods of characterizing abrasive wear and factors affecting abrasive wear. It discusses various die coatings and surface treatments used to extend the lives of dies: alloying surface treatments, micropeening, and electroplating.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003219
EISBN: 978-1-62708-199-3
... temperature; ARE, activated reactive evaporation; T m , absolute melting temperature. (a) Compounds: oxides, nitrides, carbides, silicides, and borides of Al, B, Cr, Hf, Mo, Nb, Ni, Re, Si, Ta, Ti, V, W, Zr Originally PVD was used to deposit single metal elements by transport of a vapor in a...
Abstract
Physical vapor deposition (PVD) coatings are harder than any metal and are used in applications that cannot tolerate even microscopic wear losses. This article describes the three most common PVD processes: thermal evaporation, sputtering, and ion plating. It also discusses ion implantation in the context of research and development applications.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003839
EISBN: 978-1-62708-183-2
... currents could not be measured between virgin boron monofilaments and 2024 Al or 6061 Al in 3.5 wt% NaCl solutions but were measurable between the aluminum alloys and B MF S that were extracted from the matrix. The extracted boron monofilaments were enveloped by a 4 μm thick layer of aluminum boride...
Abstract
This article begins with the discussion on the background of metal-matrix composites (MMC) and moves into a broad description of the general parameters affecting the corrosion of MMC. It discusses the primary sources of MMC corrosion that include galvanic corrosion between MMC constituents, chemical degradation of interphases and reinforcements, microstructure-influenced corrosion, and processing-induced corrosion. The article elaborates on the corrosion behavior of specific aluminum, magnesium, titanium, copper, stainless steel, lead, depleted uranium, and zinc MMCs systems. It concludes with a description on the corrosion control of MMCs using protective coatings and inhibitors.
Book Chapter
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003064
EISBN: 978-1-62708-200-6
... strength decreased at lower test temperatures, and at ambient temperature the average joint shear strength was 15.4 MPa (2.2 ksi) ( Ref 126 ). Another study investigated the solid-state diffusion bonding of CCCs by using boride and carbide interlayers ( Ref 127 ). The maximum joint strength was achieved...
Abstract
Carbon-carbon composites (CCCs) are introduced in fields that require their high specific strength and stiffness, in combination with their thermoshock resistance, chemical resistance, and fracture toughness, especially at high temperatures. The use of CCCs has expanded as the price of carbon fibers has dropped and their mechanical properties have increased. This article begins with an overview of the carbon conversion processes, fiber properties and microstructures, and interfacial bonding and environmental interaction of carbon fibers, followed by a detailed discussion on the various techniques available for processing CCCs for specific applications, including preform fabrication (fiber weaving), densification, application of protective coatings, and joining. The article closes with a description of the mechanical and physical properties and applications of CCCs. The main applications of CCCs, in terms of money and mass, are in the military, space, and aircraft industries.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005351
EISBN: 978-1-62708-187-0
... types of solid-phase inclusions in molten aluminum alloys include: Oxides (Al 2 O 3 , MgO) Spinels (Mg 2 AlO 4 ) Borides (TiB 2 , VB 2 , ZrB 2 ) Carbides (Al 3 C 4 , TiC) Intermetallics (MnAl 3 , FeAl 3 ) Nitrides (AlN) Exogenous refractory inclusions (oxides and/or carbides of...
Abstract
In the handling of molten aluminum, it is fairly common to use filters as a part of the melting unit and in the gating and/or riser system. This article describes the methods of in-furnace and in-mold filtration, with emphasis on the filtration of molten aluminum. It discusses the factors that influence the formation of inclusions. The article describes the three basic methods of mechanically removing or separating inclusions from molten metal. The methods include sedimentation, flotation, and positive filtration. The article provides a discussion on the types of molten-metal filters, including bonded-particle filters, cartridge filters, and ceramic foam filters. It lists the factors that are important in achieving optimum performance of any in-furnace filtering application. The article concludes with information on filtered metal quality.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005331
EISBN: 978-1-62708-187-0
... at concentrations greater than 0.1%. It is also known to increase shrinkage tendencies in aluminum-silicon alloys at concentrations greater than 30ppm. Boron combines with other metals to form borides present as solid particles in liquid aluminum, such as AlB 2 and TiB 2 . The titanium diboride...
Abstract
This article begins with a discussion on the effects of alloying and impurity elements on the properties of aluminum cast alloys and their chemical compositions. It describes various means of structural control, namely, chemistry control, control of element ratios based on the stoichiometry of intermetallic phases, and control of solidification conditions. The article discusses the modification and grain refinement of aluminum-silicon alloys by the use of modifiers and refiners to influence eutectic and hypereutectic structures in aluminum-silicon alloys. It provides information on the foundry alloys for specific casting applications. The article concludes with a discussion on the heat treatment practices and properties of aluminum casting alloys.
Book: Corrosion: Materials
Series: ASM Handbook
Volume: 13B
Publisher: ASM International
Published: 01 January 2005
DOI: 10.31399/asm.hb.v13b.a0003831
EISBN: 978-1-62708-183-2
... boundaries into the Inconel 617 base metal. This boron combines with nickel to form nickel boride along the grain boundaries. This second phase can deteriorate the corrosion resistance in some alloys. Fig. 2 UNS N06617 (Inconel 617) brazed with UNS N99620 (AMS 4777) under vacuum at 1038 °C (1900 °F...
Abstract
Corrosion is often thought of as rusting, the process of deterioration undergone by a metal when it is exposed to air or water. This article provides the fundamentals of joints corrosion and primarily addresses the various forms of corrosion observed in brazed and soldered joints and their causes. It describes the role of proper brazing procedures in controlling corrosion. The article concludes with information on the corrosion resistance of various brazing alloy systems.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006638
EISBN: 978-1-62708-213-6
... known materials, demonstrated accuracy is generally within ±5% relative in 95% of analyses for major and minor constituents. Low-atomic-number elements (e.g., F, O, N, C, and B) can be measured with useful accuracy as major constituents in fluorides, oxides, nitrides, carbides, and borides. Quantitative...
Abstract
This article is a detailed account of the principles of electron-excited X-ray microanalysis. It begins by discussing the physical basis of electron-excited X-ray microanalysis and the advantages and limitations of energy dispersive spectrometry (EDS) and wavelength dispersive spectrometry for electron probe microanalysis. Key concepts for performing qualitative analysis and quantitative analysis by electron-excited X-ray spectrometry are then presented. Several sources that lead to measurement uncertainties in the k-ratio/matrix corrections protocol are provided, along with the significance of the raw analytical total. Sections on accuracy of the standards-based k-ratio/matrix corrections protocol with EDS and processes of analysis when severe peak overlap occurs are also included. The article provides information on low-atomic-number elements, iterative qualitative-quantitative analysis for complex compositions, and significance of standardless analysis in the EDS software. It ends with a section on the processes involved in elemental mapping for major and minor constituents.
Series: ASM Handbook
Volume: 23
Publisher: ASM International
Published: 01 June 2012
DOI: 10.31399/asm.hb.v23.a0005682
EISBN: 978-1-62708-198-6
Abstract
This article outlines some of the selection criteria for choosing an implant material for biomedical devices in orthopedic, dental, soft-tissue, and cardiovascular applications. It details the development of implants based on materials, such as metallic implants, ceramic implants, and polymeric implants. The article discusses the specific problems associated with implant manufacturing processes and the consequent compromises in properties of functionally graded implants. It describes the manufacturing of the functionally-graded hip implant by using the LENS process. It reviews the four different types of tissue responses to the biomaterial. The article discusses the testing of implant failure, such as in vitro and in vivo assessment of tissue compatibility.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001306
EISBN: 978-1-62708-170-2
Abstract
Specialty steels encompass a broad range of ferrous alloys noted for their special processing characteristics (powder metallurgy alloys), corrosion resistance (stainless steels), wear resistance and toughness (tool steels), high strength (maraging steels), or magnetic properties (electrical steels). This article provides a detailed discussion on the various surface treatments, including cleaning, nitriding, carburizing, coating, and plating, performed on specialty steels.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001264
EISBN: 978-1-62708-170-2
... precipitate throughout the solution. This precipitate consists of nickel and either nickel phosphide or nickel boride. Spontaneous decomposition can be controlled by adding trace amounts of catalytic inhibitors to the solution. These inhibitors are absorbed on any colloidal particles present in the solution...
Abstract
Electroless nickel plating is used to deposit nickel without the use of an electric current. This article provides an overview of the solution composition and characteristics of the electroless nickel bath. It focuses on the metallurgical, mechanical and physical properties of electroless nickel-phosphorus coatings and electroless nickel-boron coatings. The effect of electroless nickel coatings on the fatigue strength of steel is also described. The article includes information on the recommended pretreatment procedures for different ferrous alloys, aluminum alloys, and copper alloys. It presents a detailed account of the equipment and various processes—including bulk and barrel plating—involved in electroless nickel plating, and discusses hydrogen relief methods. The article includes a comprehensive table on nickel plating applications, and concludes with information on electroless nickel coatings on composites and plastics.
Book Chapter
Book: Alloy Phase Diagrams
Series: ASM Handbook
Volume: 3
Publisher: ASM International
Published: 27 April 2016
DOI: 10.31399/asm.hb.v03.a0006222
EISBN: 978-1-62708-163-4
... borides. Examples include TiH 2 , TiN, TaC, WC, and Fe 3 C. All of these compounds are extremely hard, and he carbides find application in tool steels and cemented carbide cutting materials. The compound Fe 3 C (cementite) is important in steels. These compounds have a composition of AB 2 that forms...
Abstract
This article begins with the one-component, or unary, diagram for magnesium. The diagram shows what phases are present as a function of the temperature and pressure. When two metals are mixed in the liquid state to produce a solution, the resulting alloy is called a binary alloy. The article describes the various types of solid solutions such as interstitial solid solutions and substitutional solid solutions. Free energy is important because it determines whether or not a phase transformation is thermodynamically possible. The article discusses the thermodynamics of phase transformations and free energy, as well as kinetics of phase transformations. It concludes with a description of solid-state phase transformations that occur when one or more parent phases, usually on cooling, produces a phase or phases.