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Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006223

EISBN: 978-1-62708-163-4

... of eutectic and

**binary****phase****diagrams**from Gibbs free-energy curves.**binary**solution eutectic**phase****diagram**Gibbs free energy Gibbs free-energy curves**phase****diagram**single-component unary system thermodynamics IN RECENT YEARS, the application of**phase****diagram**information obtained from...
Abstract

Thermodynamic descriptions have become available for a large number of alloy systems and allow the calculation of the phase diagrams of multicomponent alloys. This article begins with a discussion on three laws of thermodynamics: the Law of Conservation of Energy, the Second Law of Thermodynamics, and the Third Law of Thermodynamics. It informs that for transformations that occur at a constant temperature and pressure, the relative stability of the system is determined by its Gibbs free energy. The article describes the Gibbs free energy of a single-component unary system and the Gibbs free energy of a binary solution. It schematically illustrates the structure of a binary solid solution with interatomic bonds and shows how the equilibrium state of an alloy can be obtained from the free-energy curves at a given temperature. The article concludes with information on the construction of eutectic and binary phase diagrams from Gibbs free-energy curves.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006229

EISBN: 978-1-62708-163-4

... decomposition has been particularly useful in the production of permanent magnet materials, because the morphologies favor high magnetic coercivities. It also describes the theory of spinodal decomposition with a simple

**binary****phase****diagram**. alloy**phases****binary****phase****diagram**chemical composition...
Abstract

In some phase diagrams, the appearance of several reactions is the result of the presence of intermediate phases. These are phases whose chemical compositions are intermediate between two pure metals, and whose crystalline structures are different from those of the pure metals. This article describes the order-disorder transformation that typically occurs on cooling from a disordered solid solution to an ordered phase. It provides a table that lists selected superlattice structures and alloy phases that order according to each superlattice. The article informs that spinodal decomposition has been particularly useful in the production of permanent magnet materials, because the morphologies favor high magnetic coercivities. It also describes the theory of spinodal decomposition with a simple binary phase diagram.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006216

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which vanadium (V) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which vanadium (V) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006212

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which thorium (Th) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which thorium (Th) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006173

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which lanthanum (La) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which lanthanum (La) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006175

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which lutetium (Lu) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which lutetium (Lu) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006247

EISBN: 978-1-62708-163-4

... Abstract This article provides a discussion on

**binary**alloy**phase****diagrams**published in this handbook. All**diagrams**presented are for stable equilibrium conditions, except where metastable conditions are indicated.**binary**alloy**phase****diagrams**crystal structure The 1083**binary**systems...Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006158

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which cesium (Cs) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which cesium (Cs) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006210

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which terbium (Tb) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which terbium (Tb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006217

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which tungsten (W) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which tungsten (W) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006219

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which ytterbium (Yb) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which ytterbium (Yb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006215

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which uranium (U) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which uranium (U) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006203

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which scandium (Sc) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which scandium (Sc) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006218

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which yttrium (Y) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which yttrium (Y) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006155

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which chlorine (Cl) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which chlorine (Cl) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006197

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which rubidium (Rb) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which rubidium (Rb) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006198

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which rhenium (Re) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which rhenium (Re) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006148

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which barium (Ba) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which barium (Ba) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006220

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which zinc (Zn) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**system...
Abstract

This article is a compilation of binary alloy phase diagrams for which zinc (Zn) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

Book Chapter

Book: Alloy Phase Diagrams

Series: ASM Handbook

Volume: 3

Publisher: ASM International

Published: 27 April 2016

DOI: 10.31399/asm.hb.v03.a0006209

EISBN: 978-1-62708-163-4

... Abstract This article is a compilation of

**binary**alloy**phase****diagrams**for which tantalum (Ta) is the first named element in the**binary**pair. The**diagrams**are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each**binary**...
Abstract

This article is a compilation of binary alloy phase diagrams for which tantalum (Ta) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.