The two major types of beryllium-containing alloys are copper-berylliums and nickel-berylliums. The most widely used beryllium-containing alloys are wrought copper-berylliums, which provide good strength while retaining useful levels of electrical and thermal conductivity. This article provides information on the specimen preparation procedures, macroexamination, microexamination, and microstructures of beryllium, copper-beryllium alloys, as well as nickel-beryllium alloys. It also discusses health and safety measures associated with the specimen preparation of beryllium and beryllium-containing alloys.

This article describes the four major conditions that can cause beryllium to corrode in air. These include beryllium carbide particles exposed at the surface; surface contaminated with halide, sulfate, or nitrate ions; surface contaminated with other electrolyte fluids; and atmosphere that contains halide, sulfate, or nitrate ions. The article provides information on the behavior of beryllium under the combined effects of high-purity water environment, stress and chemical environment, and high-temperature environment. The compositions of the structural grades for intentionally controlled elements and major impurities are tabulated. The article discusses the in-process problems and procedures that are common but avoidable when processing beryllium and aluminum-beryllium composites. It also describes the types of coatings used on beryllium and aluminum-beryllium. These include chemical conversion coatings, anodized coatings, plated coatings, organic coatings, and plasma-sprayed coatings.

This article briefly describes the production of beryllium powder and beryllium/beryllium oxide metal-matrix powder. It discusses fully dense consolidation methods: vacuum hot pressing, hot isostatic pressing, and cold isostatic pressing. Secondary fabrication operations of beryllium and aluminum-beryllium alloys such as extrusion, rolling, welding, joining, and machining are discussed. The article discusses quality control and provides information on the structural, optical, and high-purity grades of beryllium.

Addition of beryllium, up to about 2 wt″, produces dramatic effects in copper, nickel, aluminum, magnesium, gold, zinc, and other base metal alloys. This article provides information on the chemical composition, microstructure, heat treatment, fabrication characteristics, production steps and physical metallurgy of beryllium-copper, beryllium-nickel, and beryllium-aluminum alloy, and tabulates their mechanical, electrical and physical properties, and temper designations. It describes the important features of this alloy group, including information on safe handling. Additionally, the article presents examples of the beneficial properties of beryllium-copper alloys and quantifies some of the major reasons for their selection for particular applications.

This article is a compilation of binary alloy phase diagrams for which beryllium (Be) is the first named element in the binary pair. The diagrams are presented with element compositions in weight percent. The atomic percent compositions are given in a secondary scale. For each binary system, a table of crystallographic data is provided that includes the composition, Pearson symbol, space group, and prototype for each phase.

This article describes the effect of temperature, composition, strain rate, and fabrication history on the results obtained in the forming of beryllium as well as the safety measures required. It provides information on the equipment, tooling, dies, and workpieces used for forming beryllium. The article discusses the role of lubrication, blank development, tool designs, and strain rates, in deep drawing. It also provides information on the tooling and applications of three-roll bending, stretch forming, and spinning.

Beryllium possesses an unusual combination of physical and mechanical properties, suiting it for specialized applications where its relatively high cost can be justified. It has very low density, a moderately high melting point, high elastic modulus, and good electrical and thermal conductivity. The article describes structural, instrument, and optical grade beryllium and the corresponding compositional ranges. It also discusses processing and product forms as well as factors affecting corrosion resistance. The article concludes with a short note on health and safety considerations when handling beryllium.

Beryllium is a metal with an unusual combination of physical and mechanical properties that make it particularly effective in optical components, precision instruments, and specialized aerospace applications. Almost all of the beryllium in use is a powder metallurgy (P/M) product. Beginning with an overview of the mining and refining processes of beryllium, this article discusses powder production and consolidation methods, beryllium grades and their designations, and the protective measures that have been enacted to reduce exposure to beryllium.

This article discusses the properties of beryllium metals that require special attention when machining. It provides information on the considerations of S65 and selects 65 beryllium materials that are used for conducting tool wear studies and surface damage studies. The article highlights some of the precautions to be followed while machining beryllium metals. Information on the cutting oils, cutting tools, and speeds and feeds used in turning the beryllium are also provided. The article describes the chemical milling and photochemical machining methods that are used for etching beryllium components.

Copper alloys are classified by the International Unified Numbering System designations to identify alloy groups by major alloying element. This article presents the designations and compositions of various copper alloys, such as brasses, nickel silvers, bronzes, beryllium coppers, and spinodal alloys. It discusses the fatigue testing of the copper alloys and tabulates the tensile and fatigue strengths of the copper alloys. The article schematically illustrates S-N curves for the solid-solution (non-aging) strengthened alloys. It concludes with a discussion on the role of microstructure in the fatigue performance of beryllium copper alloys.

The properties of copper alloys occur in unique combinations found in no other alloy system. This article focuses on the major and minor alloying additions and their impact on the properties of copper. It describes major alloying additions, such as zinc, tin, lead, aluminum, silicon, nickel, beryllium, chromium, and iron. The article discusses minor alloying additions, including antimony, bismuth, selenium, manganese, and phosphorus. Copper alloys can be cast by many processes, including sand casting, permanent mold casting, precision casting, high-pressure die casting, and low-pressure die casting. The article provides information on the types of copper castings and tabulates the nominal chemical composition and mechanical properties of several cast alloys.

This article focuses on the monolithic form of nonferrous alloys, including aluminum, copper, nickel, cobalt, titanium, zinc, magnesium, and beryllium alloys. Each metal and alloy offers unique combinations of useful physical, chemical, and structural properties that are made available by its particular composition and the proper choice of processing method. The article describes the composition, designation system, properties, and processing method of these metals and alloys. It discusses the effect of alloying elements in these alloys. The article explains microstructure/property relationships that are used to make specific properties available to the designers of structural applications. It provides examples of phase diagrams that illustrate eutectic and peritectic reactions.

Electron-beam welding (EBW) can produce deep, narrow, and almost parallel-sided welds with low total heat input and relatively narrow heat-affected zones in a wide variety of common and exotic metals. This article discusses the joint configurations and shrinkage stresses encountered in various joint designs for electron-beam welding, as well as special joints and welds including multiple-pass welds, tangent-tube welds, three-piece welds, and multiple-tier welds. It provides a comparison of medium vacuum EBW with high-vacuum EBW. Scanning is a method of checking the run-out between the beam spot and the joint to be welded. The article describes various scanning techniques for welding dissimilar metals and provides information on the application of electron-beam wire-feed process for repairs. It concludes with a discussion on EBW of heat-resistant alloys, refractory metals, aluminum alloys, titanium alloys, copper and copper alloys, magnesium alloys, and beryllium.

This article provides a detailed account on forming operations (blanking, piercing, press-brake forming, contour rolling, deep drawing, cold forming, and hot forming) of various nonferrous metals, including aluminum alloys, beryllium, copper and its alloys, magnesium alloys, nickel alloys, titanium alloys, and platinum metals. It discusses the formability, equipment and tooling, and lubricants used in the forming operations of these nonferrous metals.

Magnesium and its alloys are among the most difficult metals to prepare for metallographic examination. This article describes specimen preparation processes, including sectioning, mounting, grinding, and polishing. It discusses macro and microexamination techniques as well as related etching processes, including macroetching and color etching based on polarized light enhancement. The article concludes with an overview of the effects of alloying elements, including aluminum, beryllium, calcium, copper, iron, lithium, manganese, rare earth metals, silicon, silver, strontium, thorium, tin, zinc, and zirconium.

Cast and wrought coppers can be strengthened by cold working. This article provides information on minor alloying elements, such as beryllium, silicon, nickel, tin, zinc, and chromium, used to strengthen copper. It details annealing and recrystallization and grain growth characteristics of copper. The article also discusses the tensile-stress-relaxation behavior of selected types of copper wires.

Bronzes generally are used to describe many different copper-base alloys in which the major alloying addition is neither zinc nor nickel. They are generally classified by their major alloying elements, for example, tin bronzes with phosphorus used as a deoxidizer, aluminum bronzes, nickel-aluminum bronzes, silicon bronzes, and beryllium bronzes. This article briefly discusses the types, hardening mechanisms, heat treatment processes, applications, and mechanical properties of these bronzes and high-copper alloys.

This article provides information on nickel alloying elements, and the heat treatment processes of various nickel alloys for applications requiring corrosion resistance and/or high-temperature strength. These processes are homogenization, annealing, solution annealing, solution treating, stabilization treatment, age hardening, stress relieving, and stress equalizing. Discussion of furnaces, fixtures, and atmospheres is included. Nickel alloys used for the heat treatment processes include corrosion-resistant nickel alloys, heat-resistant nickel alloys, nickel-beryllium alloys, special-purpose alloys such as nitinol shape memory alloys, low-expansion alloys, electrical-resistance alloys and soft magnetic alloys. Finally, the article focuses on heat treatment modeling for selecting the appropriate heat treatment process.

Metal contamination of the environment reflects both natural sources and industrial activity, affecting human health. This article begins with a discussion on the level of metal exposure resulting in toxicological effects, the factors influencing toxicity of metals, and carcinogenicity of metal compounds. It discusses some commonly used chelating agents for treating metal intoxication, and clinical effectiveness in treating poisoning by different metals. The metals discussed are grouped into four categories: (1) major toxic metals with multiple effects, including arsenic, beryllium, cadmium, chromium, lead, mercury, and nickel; (2) essential metals with potential for toxicity, including cobalt, copper, iron, manganese, molybdenum, selenium, and zinc; (3) metals with toxicity related to medical therapy, including aluminum, bismuth, gallium, gold, lithium, and platinum; and (4) minor toxic metals, including antimony, barium, indium, magnesium, silver, tellurium, thallium, tin, titanium, uranium, and vanadium. The main factors included in the discussion are their disposition, toxicity, biological factors and treatment.

This article provides a discussion on filler metal selection, brazing procedures, and brazing equipment for brazing refractory metals. These include molybdenum, tungsten, niobium, and tantalum, and reactive metals. Commercially pure and alpha titanium alloys, alpha-beta alloys, zirconium alloys, and beryllium alloys are some reactive metals discussed in the article.