A catalyst must be designed to have high activity and selectivity. The chemical process being catalyzed should have high productivity within a specified reactor volume with high reaction rates for the desired reactions and low rates for undesired reaction pathways. This article reviews the most general catalyst preparation procedures: impregnation, ion exchange, and precipitation. It explains the various categorizations of carrier materials: active carriers such as alumina, silica-alumina, zeolites, titanium oxide, and carbon in powder or particulate form; inert carriers such as silica, in powder or particulate form; and structural supports such as the monoliths upon which catalyzed carders are deposited. The article also describes catalyst powder processing techniques for tableting, beading, extrusion, spray drying and honeycombing.

Rotary swaging is an incremental metalworking process for reducing the cross-sectional area or otherwise changing the shape of bars, tubes, or wires by repeated radial blows with two or more dies. This article discusses the applicability of swaging and metal flow during swaging. It describes the types of rotary swaging machines, auxiliary tools, and swaging dies used for rotary swaging and the procedure for determining the side clearance in swaging dies. The article presents an overview of automated swaging machines and tube swaging, with and without a mandrel. It analyzes the effect of reduction, feed rate, die taper angle, surface contaminants, lubrication, and material response on swaging operation. The article discusses the applications for which swaging is the best method for producing a given shape, and compares swaging with alternative processes. It concludes with a discussion on special applications of swagging.

Coining is a closed-die forging operation in which all surfaces of the workpiece are confined or restrained, resulting in a well-defined imprint of the die on the workpiece. This article focuses on the coining equipment (hammers and presses), lubricants, and general and special die materials used in the coining process. It discusses the coinability of metals such as steels, copper, and composite metals. The article describes the control of dimensions, surface finishes, and weight of coined items. It concludes with a discussion on processing problems and solutions.

Control of grain flow is one of the major advantages of shaping metal parts by rolling, forging, or extrusion. This article shows the effects of anisotropy on mechanical properties. Cylindrical forgings commonly have a straight parting line located in a diametral plane. The alternate classes of parting lines are called either "straight" or "broken" for brevity. Regardless of whether draft is applied or natural, the forging will have its maximum spread or girth at the parting line. Proper placement of the parting line ensures that the principal grain flow direction within the forging will be parallel to the principal direction of service loading. The article reviews the mutual dependence of parting line and forging process. It provides a checklist for the forging designer that suggests a systematic approach for establishing parting line location. Finally, the article contains examples, with illustrations of parting line locations, accompanied by tables of design parameters.

Mechanical cleaning systems are used to remove contaminants of work surface by propelling abrasive materials through any of these three principal methods: airless centrifugal blast blade- or vane-type wheels; compressed air, direct-pressure dry blast nozzle systems; or compressed-air, indirect-suction (induction) wet or dry blast nozzle systems. This article focuses on the abrasive media, equipment, applications, and limitations of dry and wet blast cleaning. It discusses the health and safety precautions to be taken during mechanical cleaning.

This article describes the methods for removing metallic contaminants, tarnish, and scale resulting from hot-working or heat-treating operations on nickel-, cobalt-, and iron-base heat-resistant alloys. It provides a brief description of applicable finishing and coating processes, including polishing, electroplating, ceramic coatings, diffusion coatings, and shot-peening. The article presents numerous examples that identify cleaning and finishing problems and the procedures used to solve them.

This article describes the presses that are mechanically or hydraulically powered and used for producing sheet, strip, and plate from sheet metal. It also presents the JIC standards for presses, compares the presses based on power source, details the selection criteria and provides information on the various drive systems and the auxiliary equipment. It describes the selection of die materials and lubricants for sheet metal forming and provides information on the lubrication mechanisms and selection with a list of lubricant types for forming of specific sheet materials of ferrous or nonferrous metals. The article reviews the various types of forming processes such as blanking, piercing, fine-edge blanking, press bending, press forming, forming by multiple-slide machines, deep drawing, stretch forming, spinning, rubber-pad forming, three-roll forming, contour roll forming, drop hammer forming, explosive forming, electromagnetic forming, and superplastic forming.

This article describes the steps, bath composition and characteristics, equipment, plating rate, deposit thickness, and applications for different types of nonelectrolytic deposition processes, including electroless nickel plating, electroless copper plating and mechanical plating.

The distinction between an unconfined web and a confined web describes the relative ease of flow of metal to flash during forging. This article describes the various types of unconfined and confined web-and-rib combinations encountered in the design of forgings. It informs that the limits suggested by forging producers and users covering minimum web thicknesses that are producible are helpful in estimating the producibility of a given web thickness in projected-forging design. The article briefly analyzes the web designs of several forgings, including designs for producing flat webs, contoured webs, and oblique webs. It provides a checklist to be reviewed by a web designer.

This article discusses the applications and tensile properties of selected copper tube alloys, as well as the methods for producing copper tubular products, namely extrusion and rotary piercing. It explains the methods available for the finishing of copper tubular products, such as tube welding, cold drawing, and tube reducing. The article lists the standard dimensions and tolerances for several kinds of copper tubes and pipes in the ASTM specifications, along with other requirements for the tubular products.

This article presents a detailed account of the welding parameters, equipment needed, applications, advantages, limitations, and the process variables affecting various types of resistance welding operations, namely, resistance spot welding, resistance seam welding, resistance projection welding, and flash welding.

This article discusses classification of foundry processes based on the molding medium, such as sand molds, ceramic molds, and metallic molds. Sand molds can be briefly classified into two types: bonded sand molds, and unbonded sand molds. Bonded sand molds include green sand molds, dry sand molds, resin-bonded sand molds, and sodium silicate bonded sand. The article describes the casting processes that use these molds, including the no-bake process, cold box process, hot box process, the CO2 process, lost foam casting process and vacuum molding process. The casting processes that use ceramic molds include investment casting, and plaster casting. Metallic molds are used in permanent mold casting, die casting, semisolid casting, and centrifugal casting.

Although stainless steel is naturally passivated by exposure to air and other oxidizers, additional surface treatments are needed to prevent corrosion. Passivation, pickling, electropolishing, and mechanical cleaning are important surface treatments for the successful performance of stainless steel. This article describes the surface treatment of stainless steels including abrasive blast cleaning, acid pickling, salt bath descaling, passivation treatments, electropolishing, and the necessary coating processes involved. It also describes the surface treatment of heat-resistant alloys including metallic contaminant removal, tarnish removal, oxide and scale removal, finishing, and coating processes.

Ring rolling is a process for creating seamless ring shaped components using specialized equipment and forming processes. This article provides information on the applications of ring rolling. It discusses the types of machines used for ring rolling, namely, vertical rolling machines, radial-axial horizontal rolling machines, four-mandrel mechanical table mills, three-mandrel table mills, and automatic radial-axial multiple-mandrel ring mills. The article provides a discussion on the process control technology and ancillary operations of ring rolling. It describes the methods of producing ring blanks and the various types of blanking and rolling tools used in ring rolling process. The article concludes with a discussion on rolled ring tolerances and machining allowances.

This article schematically illustrates the basic types of drafts used in forging design, including outside draft, inside draft, blend draft, natural draft, shift draft, and back draft. The amount of draft, or the draft angle, is designated in degrees and is measured from the axis of a hammer or press stroke. The article illustrates the measurement of draft angle by describing the designs of forgings produced in equipment with vertical and horizontal rams. The use of excessive amounts of draft usually results in an increase in overall cost. The article describes various alternatives for reducing or eliminating draft. It provides a checklist citing major items that should be coordinated with a designer's review of draft.

This article describes the extrusion process, which converts soft, plastic material into a particular form using an extruder, or screw conveyer. It discusses the two main types of plastic extruders, twin-screw and single-screw, estimation of extruder capacity, and design and operations (heating, cooling, downstream sizing, corrugating, and crossheading) of the screw, the most important component of any extruder. It discusses the shapes produced by screw extrusion and the types of extrusion products produced by extrusion processes, including blown-film extrusion, flat-film or sheet extrusion, chill-roll film extrusion, pipe or tube extrusion, wire and cable coverings, extrusion coating, and profile extrusion, and provides some discussion on multiple-screw extruders. The article describes the dimensional accuracy of extrusion products, and lists common defects that occur frequently in the extrusion process.

This article focuses on the forging behavior and practices of carbon and alloy steels. It presents general guidelines for forging in terms of practices, steel selection, forgeability and mechanical properties, heat treatments of steel forgings, die design features, and machining. The article discusses the effect of forging on final component properties and presents special considerations for the design of hot upset forgings.