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Mercy Thomas, Gary Hanvy, Khuzema Sulemanji
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Arlan O. Benscoter, Bruce L. Bramfitt
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Wayne Hung
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Technical Publications Committee of the Porcelain Enamel Institute, Inc., John C. Oliver, Douglas D. Giese, Jeffrey F. Wright, Ronald L. Allen ...
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Book Chapter
Corrosion in Semiconductor Wafer Fabrication
Available to PurchaseSeries: ASM Handbook
Volume: 13C
Publisher: ASM International
Published: 01 January 2006
DOI: 10.31399/asm.hb.v13c.a0004171
EISBN: 978-1-62708-184-9
... Abstract This article presents a detailed examination of corrosion at the various production stages of wafer fabrication. The corrosion issues related to batch metal-etch systems and single-wafer metal-etch systems are also discussed. The article provides a case study, which illustrates...
Abstract
This article presents a detailed examination of corrosion at the various production stages of wafer fabrication. The corrosion issues related to batch metal-etch systems and single-wafer metal-etch systems are also discussed. The article provides a case study, which illustrates that the factors outside the normal processing of wafers or tool-specific problems can contribute to metal-line corrosion.
Book Chapter
Glass Processing
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003065
EISBN: 978-1-62708-200-6
... glass-ceramic/metal seals glass/metal seals grinding optical fibers polishing THE LARGE MAJORITY of the commercially important glasses are processed from a carefully calculated batch of raw materials that is then melted in special furnaces. There are various types of melting units used...
Abstract
The large majority of the commercially important glasses are processed from a carefully calculated batch of raw materials that is then melted in special furnaces. Providing an introduction to melting practices of glass production, this article focuses on various finishing methods of glass products, including forming, grinding and polishing, and explores the advantages, disadvantages and steps involved in sol-gel process. It also discusses the types, processes and properties of annealed, laminated, and tempered glass, and presents the steps involved in glass decoration. The article gives a detailed account of production, properties and application of fiberglass, optical fibers, glass spheres and ceramic glasses, and describes the forms, classification, compositions and properties of glass/metal and glass-ceramic/metal seals.
Book Chapter
Heat Processing Equipment
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003198
EISBN: 978-1-62708-199-3
... heating elements pumping systems salt bath equipment Types of Heat Treating Furnaces FURNACES commonly used in heat treating are classified in two broad categories: batch furnaces and continuous furnaces. In batch furnaces, workpieces normally are loaded and unloaded manually. A continuous...
Abstract
Batch furnaces and continuous furnaces are commonly used in heat treating. This article provides a detailed account of various heat treating equipment and its furnace types, including salt bath equipment (externally heated, immersed-electrode and submerged-electrode furnaces), and fluidized-bed equipment (external-resistance-heated fluidized beds). It describes various auxiliary equipment used in cold-wall furnaces, namely, heating elements and pumping systems. Five types of heat-resistant alloys are used for furnace parts, trays, and fixtures: Fe-Cr alloys, Fe-Cr-Ni alloys, Fe-Ni-Cr alloys, nickel-base alloys and cobalt-base alloys. The article lists the recommended applications for alloys for parts and fixtures for various types of heat treating furnaces.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 November 1995
DOI: 10.31399/asm.hb.emde.a0003022
EISBN: 978-1-62708-200-6
...—such as those used for metallizing of plastic films for packaging applications, flexible printed circuit boards, and video tapes—are beyond the scope of this article. Batch processes are generally used for vacuum metallizing of discrete plastic parts. The heart of a batch vacuum metallizing system...
Abstract
The process of coating plastics with metals for functional purposes is called metallizing of plastics. This article discusses the metallizing of plastics, provides information on its history, and gives a short note on applications and adhesion properties of metallic coatings. It also discusses the selection of plastics for plating. This article also describes metallizing techniques, including plating (electrolytic or electroplating), vacuum metallizing and thermal spraying, and environmental considerations. The article discusses the quality assurance procedures for metallized plastic parts which include tests that assess the quality of the finish, coating thickness, adhesion, and corrosion resistance, and gives a short note on service performance, which includes service condition classifications.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006056
EISBN: 978-1-62708-175-7
..., contains a higher metallic binder content than the bulk material. Enriched zones are clearly visible in the etched microstructure. Contamination from other grades are identified through patches of different grain size, metallic binder, and solid-solution carbides, which are more readily observed after...
Abstract
Quality control of cemented carbides includes the evaluation of physical and chemical properties of constituent raw material powders, powder blends/formulations, green compacts, and fully dense finished product. This article provides a summary of the underlying principles and size ranges for the American Society for Testing and Materials (ASTM) standard methods of particle sizing and distribution. It presents the methods used to analyze the chemical composition of cemented carbide materials in a tabular form. The article also presents information on microstructural evaluation and physical and mechanical property evaluation of cemented carbides.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002171
EISBN: 978-1-62708-188-7
... Abstract Photochemical machining (PCM), also known as chemical blanking, is a metal-etching process that uses a photoresist to define the locations where the metal will be etched. This article describes the major steps used in the PCM process, namely, the preparation of the phototool, selection...
Abstract
Photochemical machining (PCM), also known as chemical blanking, is a metal-etching process that uses a photoresist to define the locations where the metal will be etched. This article describes the major steps used in the PCM process, namely, the preparation of the phototool, selection of the metal, preparation of the workpiece, masking with photoresists, etching, and stripping and inspection. The article reviews various design considerations for the PCM process. These include dimensional limitations, tolerances, and edge quality. The article also discusses the advantages, disadvantages, and applications of the PCM process.
Series: ASM Handbook
Volume: 18
Publisher: ASM International
Published: 31 December 2017
DOI: 10.31399/asm.hb.v18.a0006360
EISBN: 978-1-62708-192-4
... is a non-carbide-forming metal such as gold, silver, or copper, the metal may form nanometer-scale clusters within the a-C:H matrix ( Ref 12 ). Industrial systems use programmable logic controllers (PLC) to maintain consistency from batch to batch and effectively make these processes “black box” from...
Abstract
This article describes two variations of carbon-base coatings: diamondlike carbon (DLC) coatings and polycrystalline diamond (PCD) coatings. It discusses the basics of a few deposition methods as they apply to industrially relevant coatings. The methods include deposition of tungsten-containing hydrogenated amorphous carbon films, deposition of tetrahedral amorphous carbon films, and deposition of silicon-incorporated hydrogenated amorphous carbon films. The most common deposition technologies for diamond films are also discussed. The article provides information on surface preparation for DLC and diamond deposition. It also provides a discussion on the coating composition and structure, mechanical and tribological properties, and applications of DLC and diamond coatings. The quality control techniques for DLC and diamond coatings are specified to meet customer requirements and ensure repeatable quality.
Book Chapter
Metallography and Microstructures of Zinc and Its Alloys
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003781
EISBN: 978-1-62708-177-1
.... Chromic acid is toxic, may cause cancer by inhalation, and must not enter ground water, bodies of water, or sewage systems. See the Material Safety Data Sheets available from the supplier for conditions of use. Etching should follow soon after final polishing. The specimen should be cleaned in alcohol...
Abstract
This article discusses the specimen preparation techniques for zinc and its alloys and zinc-coated specimens, namely, sectioning, mounting, grinding and polishing, and etching. It describes the characteristics of lead, cadmium, iron, copper, titanium, aluminum, magnesium, and tin, which are present in the microstructure of zinc alloys. The article also provides information on microexamination that helps to determine the dendrite arm spacing, as well as the grain size, grain boundaries, and grain counts.
Series: ASM Handbook
Volume: 4A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v04a.a0005787
EISBN: 978-1-62708-165-8
... and time cycles for annealing of alloy steels and carbon steel forgings. Different combinations of annealed microstructure and hardness are significant in terms of machinability. Furnaces for annealing are of two basic types, batch furnaces and continuous furnaces. The article concludes with a description...
Abstract
Steels may be annealed to facilitate cold working or machining, to improve mechanical or electrical properties, or to promote dimensional stability. This article, using iron-carbon phase diagram, describes the types of annealing processes, namely, subcritical annealing, intercritical annealing, supercritical or full annealing, and process annealing. Spheroidizing is performed for improving the cold formability of steels. The article provides guidelines for annealing and tabulates the critical temperature values for selected carbon and low-alloy steels and recommended temperatures and time cycles for annealing of alloy steels and carbon steel forgings. Different combinations of annealed microstructure and hardness are significant in terms of machinability. Furnaces for annealing are of two basic types, batch furnaces and continuous furnaces. The article concludes with a description of the annealing processes for steel sheets and strips, forgings, bars, rods, wires, and plates.
Book Chapter
Metallography and Microstructures of Low-Carbon and Coated Steels
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003761
EISBN: 978-1-62708-177-1
... steels, such as sectioning, mounting, grinding, polishing, and etching, are discussed. The article also reviews the simple and proven manual sample preparation techniques of coated steel specimens. coated steel etching grinding low-carbon steel metallic coatings metallographic specimen...
Abstract
This article reviews various phases and constituents found in the microstructures of low-carbon and coated steels. It provides information on the criteria for selecting proper metallographic procedures. Techniques used to prepare metallographic specimens of low-carbon steels and coated steels, such as sectioning, mounting, grinding, polishing, and etching, are discussed. The article also reviews the simple and proven manual sample preparation techniques of coated steel specimens.
Book: Machining
Series: ASM Handbook
Volume: 16
Publisher: ASM International
Published: 01 January 1989
DOI: 10.31399/asm.hb.v16.a0002168
EISBN: 978-1-62708-188-7
... is manufacturing methodology. Laser cutting is ideal for batch processes, just-in-time, or low-to-medium volume production. Most laser-cutting work is performed on generic or multipurpose material handling systems, as opposed to dedicated automation controlled systems. Generally, there is a clear-cut reason...
Abstract
Laser beam machining removes, melts, or thermally modifies a material by focusing a coherent beam of monochromatic light on the workpiece. This article describes the principal lasers used in metal processing: neodymium-glass, carbon dioxide, and neodymium-doped yttrium aluminum garnet lasers. It discusses the operating parameters of concern in percussion drilling and trepanning. The process variables in surface treatment and laser cutting, as well as the operating parameters of concern in laser welding are reviewed. The article also explains the various categories of surface treatment: heat treating, cladding, surfacing, glazing, and marking.
Book Chapter
Post-Processing of Additively Manufactured Metal Parts
Available to PurchaseSeries: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006570
EISBN: 978-1-62708-290-7
... as a polishing technique to smooth rough surfaces of AM metallic components. Batch processing can be used for large number of specimens and the etching rate on certain areas can be controlled by masking. The process requires a specific chemical for each material to be effective, which depends on: Chemical...
Abstract
This article describes post-processing techniques for machining, finishing, heat treating, and deburring used to remove additive manufacturing (AM) metallic workpieces from a base plate and subsequent techniques to enhance printed workpieces. The AM processes include powder bed fusion, binder jetting, and direct energy deposition. The discussion provides information on powder removal, powder recycling and conditioning, part removal, and part enhancement. The mechanism, applications, advantages, and limitations of mechanical, radiation, and chemical-finishing processes as well as the properties of the resulting material are also covered.
Book Chapter
Case Hardening of Steel
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003197
EISBN: 978-1-62708-199-3
... in a batch furnace; the 8620 steel, in a recirculating pit furnace. Pack Carburizing PACK CARBURIZING is a process in which carbon monoxide derived from a solid compound decomposes at the metal surface into nascent carbon and carbon dioxide. The nascent carbon is absorbed into the metal...
Abstract
Case hardening is defined as a process by which a ferrous material is hardened in such a manner that the surface layer, known as the case, becomes substantially harder than the remaining material, known as the core. This article discusses the equipment required, process variables, carbon and hardness gradients, and process procedures of different types of case hardening methods: carburizing (gas, pack, liquid, vacuum, and plasma), nitriding (gas, liquid, plasma), carbonitriding, cyaniding and ferritic nitrocarburizing. An accurate and repeatable method of measuring case depth is essential for quality control of the case hardening process and for evaluation of workpieces for conformance with specifications. The article also discusses various case depth measurement methods, including chemical, mechanical, visual, and nondestructive methods.
Book Chapter
Porcelain Enameling
Available to PurchaseBook: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001279
EISBN: 978-1-62708-170-2
... are usually supplied with a light application of oil to minimize rusting. This is particularly important in systems where acid etching is not employed during metal preparation. Sag Characteristics Sag is the permanent deformation or creep of steel due to its own weight during enamel firing. The sag...
Abstract
Porcelain enamels are glass coatings applied primarily to products or parts made of sheet steel, cast iron, and aluminum to improve appearance and to protect the metal surface. This article describes the types of porcelain enamels, and details enamel frits for these materials. It provides a list of steels suitable for porcelain enameling and discusses the most important factors considered in the selection of steel for porcelain enameling. The article briefly presents the preparation methods of these materials for porcelain enameling and covers the methods, and furnaces of porcelain enameling. It examines the role of coating thickness, firing time and temperature, metal substrate, and color on the performance of enameled surfaces. The article concludes with a discussion on the properties of enameled surfaces, factors considered in process control, and test procedures for evaluating the quality of enameled surfaces.
Book Chapter
Surface Cleaning
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003213
EISBN: 978-1-62708-199-3
... carburetor parts, valves, switch components, drawn wire Chips, lubricants, and general grime Moderately alkaline, specially inhibited to prevent etching of metal, or neutral synthetic (usually in liquid form) Copper and brass (also silver, gold, tin, lead, and solder) Printed circuit boards, waveguides...
Abstract
Metal surfaces must often be cleaned before subsequent operations to remove unwanted substances such as pigmented drawing compounds, unpigmented oil and grease, chips and cutting fluids, polishing and buffing compounds, rust and scale, and miscellaneous contaminants. The article describes common cleaning processes, including alkaline, electrolytic, solvent, emulsion, molten salt bath, ultrasonic and acid cleaning as well as pickling and abrasive blasting. It also explains how to select the appropriate process for a given soil type and surface composition.
Book: Powder Metallurgy
Series: ASM Handbook
Volume: 7
Publisher: ASM International
Published: 30 September 2015
DOI: 10.31399/asm.hb.v07.a0006116
EISBN: 978-1-62708-175-7
... suggestions to promote and encourage the safety of those performing metallographic preparation and analysis. chemical etching drying ferrous powders grinding metallic specimens metallographic analysis metallographic preparation mounting polishing powder metallurgy sample selection sectioning...
Abstract
Metallographic analysis is primarily a collection of visual and imaging techniques that provide an insight into the background of a material or part and its behavior. Metallic specimens, both porous and pore-free, are opaque, and as a result, an optical examination must be performed on carefully prepared planar (two-dimensional) surfaces. This article discusses the preparation sequence of ferrous powders, which is normally separated into several well-defined steps: sample selection, sectioning, mounting, grinding, polishing, drying, and chemical etching and/or coating. It provides several suggestions to promote and encourage the safety of those performing metallographic preparation and analysis.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0001229
EISBN: 978-1-62708-170-2
... of hydrochloric acid with base metal forms ferrous chloride and hydrogen gas: (Eq 6) Fe + 2 HCl = FeCl 2 + H 2 ( g ) Sulfuric Acid Pickling Sulfuric acid produces satisfactory results when used for batch pickling of carbon steel rod and wire (up to 0.60% C) and for continuous...
Abstract
Pickling is the most common of several processes used to remove scale from steel surfaces. This article provides a discussion on pickling solutions, such as sulfuric and hydrochloric acid, and describes the role of inhibitors in acid pickling. It discusses the equipment and processes involved in the batch, continuous, and electrolytic pickling of carbon steel components. The article describes the effects of process variables on scale removal in sulfuric and hydrochloric acid. It concludes with a description of pickling defects, spent pickle liquor disposal, and safety practices.
Book Chapter
Dip, Barrier, and Chemical Conversion Coatings
Available to PurchaseSeries: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003217
EISBN: 978-1-62708-199-3
... is often given a prepaint treatment to improve paint adhesion and reduce corrosion. Prepaint treatments include phosphate coatings (see earlier article on this subject) and organic pretreatments known as wash primers or etch primers. The choice of a prepaint treatment depends largely on the substrate metal...
Abstract
There are various coating techniques in practice to prevent the deterioration of steels. This article focuses on dip, barrier, and chemical conversion coatings and describes hot-dip processes for coating carbon steels with zinc, aluminum, lead-tin, and other alloys. It describes continuous electrodeposition for steel strip and babbitting and discusses phosphate and chromate conversion coatings as well. It also addresses painting, discussing types and selection, surface preparation, and application methods. In addition, the article describes rust-preventive compounds and their application. It also provides information on weld-overlay and thermal spray coating, porcelain enameling, and the preparation of enamel frits for steels. The article closes by describing methods and materials for ceramic coating.
Book Chapter
Mechanical Grinding and Polishing
Available to PurchaseSeries: ASM Handbook
Volume: 9
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.hb.v09.a0003747
EISBN: 978-1-62708-177-1
... of abrasion is a system of comparatively fine, uniform scratches on the surface of the specimen. Abrasion also produces a plastically deformed surface layer (disturbed metal) of considerable depth. The microstructure of this layer may be recognizably different from the true structure of the specimen...
Abstract
This article illustrates how objective experiments and comparisons can be used to develop surface preparation procedures for metallographic examination of structural features of metals. These procedures are classified as machining, grinding and abrasion, or polishing. The article describes the abrasion artifacts in austenitic steels, zinc, ferritic steels, and pearlitic steels, and other effects of abrasion damages, including flatness of abraded surfaces and embedding of abrasive. Different polishing damages, such as degradation of etching contrast and scratch traces, are reviewed. The article explains the final-polishing processes such as skid polishing, vibratory polishing methods, etch-attack and electromechanical polishing, and polishing with special abrasives. An overview of special polishing techniques for unusual materials such as very hard and very soft materials is provided. The article concludes with a discussion on semiautomatic preparation procedures, providing information on procedures based on the use of diamond abrasives charged in a carrier paste and in a suspension.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003174
EISBN: 978-1-62708-199-3
... of 30 to 55 °C (50 to 100 °F) can be expected. Lime alone or with various salts can be used as the desulfurizing agent. The efficiency is lower than that with carbide, but there are fewer environmental problems. Injection and porous plug desulfurizing systems can be either batch type, treating...
Abstract
Cast iron, which usually refers to an in situ composite of stable eutectic graphite in a steel matrix, includes the major classifications of gray iron, ductile iron, compacted graphite iron, malleable iron, and white iron. This article discusses melting, pouring, desulfurization, inoculation, alloying, and melt treatment of these major ferrous alloys as well as carbon and alloy steels. It explains the principles of solidification by describing the iron-carbon phase diagram, and provides a pictorial presentation of the basic microstructures and processing steps for cast irons.
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