This article discusses the most common methods of melting steels, namely, electric arc and induction melting. It describes the classification of refractories by an index of the “basicity” of the slag formed on the steel surface. The article provides a discussion on the converter metallurgy, which includes melt refinement in argon oxygen decarburization (AOD) vessels and vacuum oxygen decarburization (VODC) in a converter vessel. It also discusses ladle metallurgy, which includes vacuum induction degassing, vacuum oxygen decarburization, and vacuum ladle degassing.

This article discusses the physical metallurgy of cast cobalt alloys with an emphasis on the crystallography, compositions, phases and microstructure, and properties. Cobalt alloys are cast by several different foundry methods. The article describes the argon-oxygen decarburization and continuous casting process. It provides information on castability and quality of the casted alloys. The article details the postcasting treatment, including heat treatment, hot isostatic pressing, and coatings. It summarizes the applications of cast cobalt alloys.

Controlled atmosphere chambers are used to control the surface chemistry of the metals that are being processed. This article focuses on the various types of controlled atmospheres used in induction heat treating and brazing, namely, inert gas atmospheres based on argon and helium; prepared and commercial nitrogen-base atmospheres; and brazing atmospheres. It provides detailed information on two types of controlled atmosphere chambers: atmosphere and vacuum. The article also describes the selection factors, advantages, and disadvantages of these chambers.

This article discusses the corrosion characteristics of superaustenitic stainless and duplex stainless steels, which are used in pharmaceutical industry. It describes passivation treatments and the electropolishing of stainless steels. The article informs that electropolishing is not a passivation treatment, although the proper execution of the process will result in a passive surface. The article concludes with a discussion on roughing, which is a phenomenon of particular interest to the pharmaceutical industry.

This article describes the effects of furnace atmospheric elements on steels. These elements are air, water vapor, molecular nitrogen, carbon dioxide, and carbon monoxide. The article provides useful information on six groups of commercially important prepared atmospheres classified by the American Gas Association on the basis of method of preparation or on the original constituents employed. These groups are designated and defined as follows: Class 100, exothermic base; Class 200, prepared nitrogen base; Class 300, endothermic base; Class 400, charcoal base; Class 500, exothermic-endothermic base; and Class 600, ammonia base. These are subclassified and numerically designated to indicate variations in the method by which they are prepared. The article also contains a table that lists significant furnace atmospheres and their typical applications.

This article presents a detailed account on the process flow, composition, alternative sources, and the advancement of ironmaking, steelmaking and secondary steelmaking practices. Some steels, such as bearing steels, heat-resistant steels, ultrahigh strength missile and aircraft steels, and rotor steels have higher quality requirements and tighter composition control than plain carbon or ordinary low-alloy steels. The production of special-quality steels requires vacuum-based induction or electric remelting and refining capabilities. The article explores the types and characteristics of various steel manufacturing processes, such as ingot casting, continuous casting, and hot rolling. It provides an outline of specialized processing routes of producing ultralow plain carbon steels, interstitial-free steels, high strength low-alloy steels, ultrahigh strength steels, stainless steels, and cold-rolled products, and briefly explains the analytical techniques for liquid steels.

Vacuum induction melting (VIM) is often done as a primary melting operation followed by secondary melting (remelting) operations. This article presents the process description of VIM and illustrates potential processing routes for products, which are cast from VIM ingots or electrodes. It describes the VIM refinement process, which includes the removal of trace elements, nitrogen and hydrogen degassing, and deoxidation. The article concludes with information on the production of nonferrous materials by VIM.

The melting process often includes refining and treating the metal. The choice of which type of melting to use depends on a number of factors: type of alloy being melted, the local cost of electric power, and local environmental regulations. This article discusses the principles, furnace types, charging practices of metal melting methods, namely induction melting, cupola melting, arc melting, crucible melting, reaction melting, and vacuum melting, and the refractories and charging practice of reverberatory furnaces. Molten metal treatment of steels and aluminum also is discussed in the article.

This article provides a detailed discussion on the types of furnace atmospheres required for heat treating. These include generated exothermic-based atmospheres, generated endothermic-based atmospheres, generated exothermic-endothermic-based atmospheres, generated dissociated-ammonia-based atmospheres, industrial gas nitrogen-base atmospheres, argon atmospheres, and hydrogen atmospheres. Atmospheres for backfilling, partial pressure operation, and quenching in vacuum are also discussed. Furnace atmospheres constitute four major groups of safety hazards in heat treating: fire, explosion, toxicity, and asphyxiation. The article reviews the fundamentals of principal gases and vapors. It describes how the evaluation of the atmospheric requirements of heat treating furnaces is influenced by factors such as cost of operation and capital investment.