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Published: 15 January 2021
Fig. 2 Example of burn marks left behind after arc/spark optical emission spectroscopy, illustrating how this technique is destructive to the surface. Courtesy of J. Sampson, NASA
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Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001728
EISBN: 978-1-62708-178-8
... are often designed to minimize molecular emission. Each of the four types of emission sources; arcs, high-voltage sparks, glow discharges, and flames; has a set of physical characteristics with accompanying analytical assets and liabilities. The article also discusses the applications of each type...
Abstract
This article discusses the general principles, optical systems, and emission sources of optical emission spectroscopy for elemental analysis. Changes in the energy of the valence or outer shell electrons result in the atomic lines used in emission spectroscopy. Each possible combination of electron configurations produces a spectroscopic term that describes the state of the atom. Atomic emission is analytically useful only to the extent that the emission from one atomic species can be measured and its intensity recorded independent of emission from other sources. Emission sources are often designed to minimize molecular emission. Each of the four types of emission sources; arcs, high-voltage sparks, glow discharges, and flames; has a set of physical characteristics with accompanying analytical assets and liabilities. The article also discusses the applications of each type of emission source.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001336
EISBN: 978-1-62708-173-3
... shape and shielding gas composition in the GTAW process. arc welding cathode tip shape electron discharge gas tungsten arc welding heat transfer nonthermionic emission shielding gas composition thermionic emission THE GAS-TUNGSTEN ARC WELDING (GTAW) process is performed using a welding...
Abstract
The gas-tungsten arc welding (GTAW) process is performed using a welding arc between a nonconsumable tungsten-base electrode and the workpieces to be joined. The arc discharge requires a flow of electrons from the cathode through the arc column to the anode. This article discusses two cases of electron discharge at the cathode: thermionic emission and nonthermionic emission, also called cold cathode, or field emission. It schematically illustrates relative heat transfer contributions to workpiece in the GTAW process. The article provides information on the effects of cathode tip shape and shielding gas composition in the GTAW process.
Series: ASM Handbook
Volume: 10
Publisher: ASM International
Published: 15 December 2019
DOI: 10.31399/asm.hb.v10.a0006640
EISBN: 978-1-62708-213-6
... by inductively coupled plasma. The article “Inductively Coupled Plasma Optical Emission Spectroscopy” in this Volume is devoted to this widely used, very powerful technique. Arc Sources The term arc describes various electrical discharges; this description is limited to the direct current (dc) arc...
Abstract
This article is a detailed account of optical emission spectroscopy (OES) for elemental analysis. It begins with a discussion on the historical background of OES and development trends in OES methods. This is followed by a description of the general principles and optical systems of OES, along with various types of emission sources commonly used for OES. Some of the processes involved in calibration and quantification of OES for direct solids analysis by the ratio method are then described. The article ends with a discussion on the applications of each type of emission sources.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005664
EISBN: 978-1-62708-174-0
..., the emission moves to a new location that has a high enough oxide content to sustain the discharge of electrons. The arc root or cathode spot where the emission occurs is highly mobile in ac or DCEP and, as a result, the arc is much less stable than in DCEN. Gas Shielding In all cases, the arc and both...
Abstract
This article provides the basic physics of the two most widely used arc welding processes: gas tungsten arc welding and gas metal arc welding. It describes the various control parameters of these processes such as arc length control, voltage control, heat input control, and metal-transfer control.
Series: ASM Handbook
Volume: 24
Publisher: ASM International
Published: 15 June 2020
DOI: 10.31399/asm.hb.v24.a0006545
EISBN: 978-1-62708-290-7
... Abstract Fusion-based additive manufacturing (AM) processes rely on the formation of a metallurgical bond between a substrate and a feedstock material. Energy sources employed in the fusion AM process include conventional arcs, lasers, and electron beams. Each of these sources is discussed...
Abstract
Fusion-based additive manufacturing (AM) processes rely on the formation of a metallurgical bond between a substrate and a feedstock material. Energy sources employed in the fusion AM process include conventional arcs, lasers, and electron beams. Each of these sources is discussed, with an emphasis on their principles of operation, key processing variables, and the influence of each source on the transfer of heat and material. Common energy sources used for metals AM processes, particularly powder-bed fusion and directed-energy deposition, are also discussed. Brief sections at the end of the article discuss the factors dictating the choice of each of these energy sources and provide information on alternative sources of AM.
Book: Casting
Series: ASM Handbook
Volume: 15
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.hb.v15.a0005205
EISBN: 978-1-62708-187-0
... high current densities are required. The cathodes are usually made of tungsten, along with small additions of thoria to lower the thermionic work function of tungsten. Still, electron emission requires high electrode temperatures (3500 to 6000 K, or 5800 to 10,300 °F) at the attachment of the arc...
Abstract
Plasma melting is a material-processing technique in which the heat of thermal plasma is used to melt a material. This article discusses two typical design principles of plasma torches in the transferred mode: the tungsten tip design and the hollow copper electrode design. It describes the sources of atmospheric contamination in plasma melting furnaces and their control measures. The equipment used in plasma melting furnaces are also discussed. The article provides a detailed discussion on various plasma melting processes, such as plasma consolidation, plasma arc remelting, plasma cold hearth melting, and plasma casting.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001482
EISBN: 978-1-62708-173-3
... at the gas-tungsten arc at the melting point of the metals welded. Hunter, Allemand, and Eager ( Ref 54 , 55 ) developed techniques for temperature measurement using multiwavelength pyrometry to alleviate the emissivity variation problem. However, so far the only proof of the concept was demonstrated...
Abstract
Fusion welding processes involve four phase changes, namely, solid-solid state, solid-liquid, liquid-vapor, and vapor-plasma. Each has its own thermal, momentum, and stress history. This article discusses some important techniques to validate temperature, momentum, stress, and residual strain history observed in the heat-affected zone of fusion welded materials.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005553
EISBN: 978-1-62708-174-0
... for differences in the thermal emissivity of the workpiece. In GTAW, accurate IR temperature measurements can be further hampered by interfering radiation from the arc and the tungsten electrode ( Ref 72 ). Finally, unlike IR sensors, which typically have a fast response time, contact temperature transducers...
Abstract
This article provides an overview of the methods used to control aspects of the arc welding process and research associated with the development of closed-loop feedback control of the process. Successful implementation of a closed-loop feedback control system requires sensing, modeling, and control. The article describes the commonly applied sensing techniques for arc welding control: arc sensing and nonimaging and imaging optics. It reviews the physics-based, empirically-derived, and neural network models for arc welding control. The article also discusses the research and development activities that attempt to extend the commercial, welding process controllers, namely, adaptive control, intelligent control, multivariable control, and distributed, hierarchical control.
Series: ASM Desk Editions
Publisher: ASM International
Published: 01 December 1998
DOI: 10.31399/asm.hb.mhde2.a0003250
EISBN: 978-1-62708-199-3
... Abstract The overall chemical composition of metals and alloys is most commonly determined by X-ray fluorescence (XRF) and optical emission spectroscopy (OES), and combustion and inert gas fusion analysis. This article provides information on the capabilities, uses, detection threshold...
Abstract
The overall chemical composition of metals and alloys is most commonly determined by X-ray fluorescence (XRF) and optical emission spectroscopy (OES), and combustion and inert gas fusion analysis. This article provides information on the capabilities, uses, detection threshold and precision methods, and sample requirements. The amount of material that needs to be sampled, operating principles, and limitations of the stated methods are also discussed.
Book: Surface Engineering
Series: ASM Handbook
Volume: 5
Publisher: ASM International
Published: 01 January 1994
DOI: 10.31399/asm.hb.v05.a0005586
EISBN: 978-1-62708-170-2
... temperatures in steel AEM analytical electron microscope/microscopy AES Auger electron spectroscopy; acoustic emission spectroscopy AESF American Electroplaters and Surface Finishers Society AFM atomic force microscope AG aged; alternating grinding AGMA American...
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0001337
EISBN: 978-1-62708-173-3
... Abstract Power sources are apparatuses that are used to supply current and voltages that are suitable for particular welding processes. This article describes power sources for arc welding, resistance welding, and electron-beam welding. The more-common welding processes that use constant...
Abstract
Power sources are apparatuses that are used to supply current and voltages that are suitable for particular welding processes. This article describes power sources for arc welding, resistance welding, and electron-beam welding. The more-common welding processes that use constant-current and constant-voltage power sources are listed in a table. The article describes the open-circuit voltage characteristics and power source control methods. The control methods employ either pulse width modulation (PWM) or frequency modulation (FM).
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001729
EISBN: 978-1-62708-178-8
.... However, one significant advantage of the ICP over flame and arc-spark techniques is the great reduction, due to high temperatures and inert argon atmosphere, in background emission arising from flame gases, combustion products, and molecular species. Vaporization-Atomization Interference...
Abstract
Inductively coupled plasma atomic emission spectroscopy (ICP-AES) is an analytical technique for elemental determinations in the concentration range of major to trace based on the principles of atomic spectroscopy. This article provides a description of the basic atomic theory, and explains the analytical procedures and various interference effects of ICP, namely, spectral, vaporization-atomization, and ionization. It provides a detailed discussion on the principal components of an analytical ICP system, namely, the sample introduction system; ICP torch and argon gas supplies; radio-frequency generator and associated electronics; spectrometers, such as polychromators and monochromators; detection electronics and interface; and the system computer with appropriate hardware and software. The article also describes the uses of direct-current plasma, and provides examples of the applications of ICP-AES.
Series: ASM Handbook Archive
Volume: 10
Publisher: ASM International
Published: 01 January 1986
DOI: 10.31399/asm.hb.v10.a0001732
EISBN: 978-1-62708-178-8
...-supplied spectral response curves, and solutions of appropriate standard fluorescent compounds. Wavelength Calibration Instrumental emission wavelength settings can be calibrated periodically using a standard source, such as mercury arc lamp. The mercury emission lines (first and second order) from...
Abstract
This article provides an introduction to the molecular fluorescence spectroscopy, and discusses the theory of fluorescence and its application to chemical analysis. It provides information on fluorescence that occurs in organic compounds and inorganic atoms and molecules. The article describes the instruments used in the spectroscopy, namely, radiation sources, sample holders, wavelength selectors, detectors, computers, and ratiometric instruments. The practical considerations include solvent effects, corrected spectra, wavelength calibration, temperature, and scattered light. The article also discusses the uses of some special techniques used in molecular fluorescence spectroscopy.
Series: ASM Handbook
Volume: 17
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.hb.v17.a0006454
EISBN: 978-1-62708-190-0
... Abstract Acoustic emission is the generation of stress waves by sudden movement in stressed materials. This article begins with a comparison of acoustic emission from most other nondestructive testing (NDT) methods, and discusses the range of applicability of acoustic emission. It describes...
Abstract
Acoustic emission is the generation of stress waves by sudden movement in stressed materials. This article begins with a comparison of acoustic emission from most other nondestructive testing (NDT) methods, and discusses the range of applicability of acoustic emission. It describes the instrumentation principles of acoustic emission and reviews the role of acoustic emission in materials studies. The article illustrates the testing of metal-matrix composites (MMCs) using acoustic emission and the use of acoustic emission inspection in production quality control. It concludes with information on the structural test applications of acoustic emission inspection to find defects and to assess or ensure structural integrity.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005717
EISBN: 978-1-62708-171-9
... 3 ), fumes and dust, and so on. Most of the hazards are, in part, proportional to jet energy and velocity, and these hazards are common to all devices and processes. At the upper end of the energy spectrum for these processes are hypersonic velocities and plasma-arc power levels of 720 MJ (200 kW...
Abstract
The hazards associated with thermal spray deposition processes include ultraviolet and infrared radiation; acoustical noise; and by-product production in the forms of nitrous oxides, ozone, fumes, and dust. The most important consideration in health and safety is to use the engineered controls of hazards. This article provides a brief description of the spray booth, the most commonly used engineering tool to separate the operator from the thermal spray process and confine the associated hazards. It also presents guidelines on the proper and safe handling of industrial gases and ventilation and heat exhaust. The article provides information on the personal protective equipment for eyes and skin from radiation, and ears from noise. It also discusses other potential safety hazards associated with thermal spraying, namely, magnetic fields and infrasound.
Book: Thermal Spray Technology
Series: ASM Handbook
Volume: 5A
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.hb.v05a.a0005708
EISBN: 978-1-62708-171-9
... (e.g., Zn15Al) or aluminum/magnesium (e.g., Al5Mg) coatings with thicknesses of 80 to 120 μm (3 to 5 mils) and 200 to 350 μm (8 to 14 mils), respectively ( Ref 3 ). Plain aluminum (99.5% Al) coatings with thicknesses of 150 to 200 μm (6 to 8 mils) also are used. They are deposited by electric arc wire...
Abstract
The use of renewable energy has grown strongly in all end-use sectors such as power, heat, and transport. This article describes thermal spray applications that improve efficiency, lower maintenance costs, and prolong operational life in the renewable energy technologies, including wind power, hydro power, biomass and biofuels, solar energy, and fuel cells.
Book Chapter
Series: ASM Handbook
Volume: 2B
Publisher: ASM International
Published: 15 June 2019
DOI: 10.31399/asm.hb.v02b.a0006592
EISBN: 978-1-62708-210-5
... aluminum. The reflectivity of 1100 aluminum as a function of aluminum oxide coating thickness and emissivity of 1100 aluminum foil as a function of coating thickness are illustrated. aluminum alloy 1100 aluminum alloy 1100A aluminum foil aluminum oxide coating coating thickness commercially pure...
Abstract
This datasheet provides information on key alloy metallurgy, fabrication characteristics, processing effects on physical and mechanical properties, and applications of commercially pure aluminum grades 1100 and 1100A. It contains table that lists the standard specifications for 1100 aluminum. The reflectivity of 1100 aluminum as a function of aluminum oxide coating thickness and emissivity of 1100 aluminum foil as a function of coating thickness are illustrated.
Series: ASM Handbook
Volume: 6A
Publisher: ASM International
Published: 31 October 2011
DOI: 10.31399/asm.hb.v06a.a0005590
EISBN: 978-1-62708-174-0
... of the arc current is carried by positive gas ions that are attracted to the cathode, where they generate approximately 30% of the arc heat. The cathode loses heat by the emission of electrons, and this energy is transferred as heat when the electrons enter or interact with the anode. This is one reason why...
Abstract
The gas tungsten arc welding (GTAW) process derives the heat for welding from an electric arc established between a tungsten electrode and the part to be welded. This article provides a discussion on the basic operation principles, advantages, disadvantages, limitations, and applications of the process. It describes the equipment used for GTAW, namely, power supplies, torch construction and electrodes, shielding gases, and filler metals as well as the GTAW welding procedures. The article concludes with a review of the safety precautions to avoid possible hazards during the GTAW process: electrical shock, fumes and gases, arc radiation, and fire and explosion.
Series: ASM Handbook
Volume: 6
Publisher: ASM International
Published: 01 January 1993
DOI: 10.31399/asm.hb.v06.a0005663
EISBN: 978-1-62708-173-3
... in crystal structure; speed of DIN Deutsche Industrie-Normen (German In- AAR Association of American Railroads light; specific heat; constant dustrial Standards) C cementite; coulomb; heat capacity DPH diamond pyramid hardness AASHTO American Association of State CAC carbon arc cutting DRA discontinuously...
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