Surface treatments are applied to magnesium parts primarily to improve their appearance and corrosion resistance. Mechanical and chemical cleaning methods are used singly or in combination, depending on the specific application and product involved to ensure repetitive reliability. This article focuses on mechanical finishing methods, namely, barrel tumbling, polishing, buffing, vibratory finishing, fiber brushing, and shot blasting. It provides useful information on process control and difficulties with chemical and anodic treatments of magnesium alloys. The use and applications of plating and organic finishing of magnesium alloys are also reviewed. The article concludes with a description of health and safety precautions to be followed during the surface treatment process.

This article discusses the effects of heavy metal impurities, environmental factors, the surface condition (such as as-cast, treated, and painted), and the assembly practice on the corrosion resistance of a magnesium or a magnesium alloy part. It provides information on stress-corrosion cracking and galvanic corrosion of magnesium alloys, as well as the surface protection of magnesium assemblies achieved by inorganic surface treatments.

Chemical brightening (bright dipping) and electrolytic brightening (electropolishing) are essentially selective-dissolution processes, in which the high points of a rough surface of aluminum are attacked more rapidly than the depressions, and the peaks and valleys are smoothed to produce a bright and beautiful finish. This article discusses the metallurgical factors, optical factors, and applications of the chemical and electrolytic brightening. It compares the chemical brightening and electrolytic brightening, and presents the advantages of the chemical and electrolytic brightening processes in terms of performance and economy. The article describes the phosphoric-nitric acid baths and phosphoric-sulfuric acid baths used for chemical brightening. Solution compositions and operating conditions for three commercial electropolishing processes, as well as for suitable post-treatments, are presented in a table.

Anodizing refers to conversion coating of the surface of aluminum and its alloys to porous aluminum oxide. This article provides the reasons for performing anodizing and discusses the three principal types of anodizing processes, namely, chromic acid process, sulfuric acid process, and hard anodic process. It describes the limitations imposed by variables, such as alloy composition, surface finish, prior processing, temper or heat treatment, and the use of inserts, on the anodizing processes. The article explains the causes and means adopted for correcting several specific problems in anodizing aluminum. It also discusses the process control techniques and equipment used for anodizing. The article reviews the sealing processes for anodic coatings and the method for coloring the coatings. It concludes with a discussion on the effects of anodic coatings on the surface and mechanical properties of aluminum and its alloys.

Anodizing is one of the most common surface treatments of aluminum and is performed for corrosion protection. This article describes the structure and growth characteristics of the types of anodic oxide films such as a barrier-type oxide film and a porous-type anodic oxide film. It discusses each step involved in the anodizing process of an aluminum or aluminum alloy specimen. The anodizing process includes pretreatments (degreasing, etching, and polishing), anodizing, coloring, and sealing. The article provides an observation of the morphology of the anodic oxide films by transmission electron microscopy and the scanning electron microscopy for testing properties of anodic oxide films.

This article discusses surface engineering of nonferrous metals including aluminum and aluminum alloys, copper and copper alloys, magnesium alloys, nickel and nickel alloys, titanium and titanium alloys, zirconium and hafnium, zinc alloys, and refractory metals and alloys. It describes various techniques to improve functional surface properties and enhance the appearance of product forms. The article discusses various cleaning and finishing techniques such as abrasive blast cleaning, polishing and buffing, barrel burnishing, chemical cleaning, pickling, etching and bright dipping, electrochemical cleaning, mechanical cleaning, and mass finishing. It also examines coating processes such as plating, anodizing, chemical conversion coating, and thermal spray, and concludes with a discussion on oxidation-resistant coatings for refractory metals.

Hard chromium plating is produced by electrodeposition from a solution containing chromic acid and a catalytic anion in proper proportion. This article presents the major uses of hard chromium plating, and focuses on the selection factors, plating solutions, solution and process control, equipment, surface preparation, and crack patterns and other characteristics of hard chromium plating. It offers recommendations for the design and use of plating racks, describes the problems encountered in hard chromium plating, and their corrective procedures. The article provides information on the removal of chromium plate from coated metals, recovery and disposal of wastes, and stopoff media for selective plating.

This article describes the methods used for coloring anodized aluminum coatings: integral coloring, electrolytic coloring, chemical coloring, and organic dyeing. It discusses organic dye chemistry in terms of single-component organic dyes and multicomponent dyes. The article reviews optimal dyeing conditions, such as temperature, time, concentration, and pH. It concludes with a discussion on the factors considered for choosing a coloring method: the desired shade, light fastness, heat fastness, and contamination.

This article addresses the general effects of the composition, mechanical treatment, surface treatment, and processing on the corrosion resistance of aluminum and aluminum alloys. There are five major alloying elements: copper, manganese, silicon, magnesium, and zinc, which significantly influence the properties of aluminum alloys. There are organic coatings or paints that provide a barrier between a corrosive environment and aluminum surface. Inorganic coatings, including claddings, and enhanced oxides, such as anodized films, Boehmite films, and conversion coatings also help in corrosion prevention. The article assists in the information on selection of fabrication operations, as they play an important role in corrosion resistance.

This guide rates the compatibility of dissimilar structural materials joined together for service in seawater, marine atmosphere, or industrial atmosphere. It contains a table that indicates the material code and most generally effective surface treatment typically used to reduce corrosion of bare metals.

Zinc and zinc alloys require surface engineering prior to coating or use to improve adhesion and corrosion resistance. Die-cast zinc parts, in addition, must be trimmed and finished to remove flash and parting lines. This article covers zinc cleaning procedures as well as coating and finishing processes. It explains how to remove parting lines and presents several mechanical finishing methods, including surface polishing, brushing, controlled shot peening, and buffing. It also provides information on solvent cleaning, emulsion cleaning, aqueous detergent or alkaline cleaning), electrocleaning, acid dipping, and zinc conversion coating treatments.

Zirconium and hafnium surfaces require cleaning and finishing for reasons such as preparation for joining, heat treatment, plating, forming, and producing final surface finishes. This article provides information on various surface treatment processes, surface soil removal, blast cleaning, chemical descaling, pickling or etching, anodizing, autoclaving, polishing, buffing, vapor phase nitriding, and electroplating. Applications of these surface treatment processes are also reviewed.

This article discusses the factors affecting corrosion behavior. It describes galvanic corrosion and its protection methods. The article also provides information on coatings and inhibitors, which are used in corrosion protection.

Copper alloys are widely used as electroplated coatings. They can also be used with practically any substrate material that is suitable for electroplating. This article focuses on the solution composition and operating conditions for brass and bronze plating solutions. It describes the decorative and engineering applications of brass and bronze plating. The article also provides information on the treatment of waste water from brass and bronze plating operations.

Aluminum or aluminum alloy products have various types of finishes applied to their surfaces to enhance appearance or improve functional properties. This article discusses the procedures, considerations, and applications of various methods employed in the cleaning, finishing, and coating of aluminum. These include abrasive blast cleaning, barrel finishing, polishing, buffing, satin finishing, chemical cleaning, chemical brightening, electrolytic brightening, chemical etching, alkaline etching, acid etching, chemical conversion coating, electroplating, immersion plating, electroless plating, porcelain enameling, and shot peening.

This article discusses the properties of aluminum surface and the applications of aluminum alloys. It explains the effects of trace elements on aluminum alloys. The article considers microstructural development of aluminum in terms of the surface and explains how it will impact corrosion resistance and surface treatment. It describes the thermodynamics of equilibrium oxidation processes and non-equilibrium corrosion processes. The article provides a discussion on aluminum oxidation under atmospheric and dynamic conditions. It presents the potential/pH (Pourbaix) diagram for aluminum under atmospheric and dynamic conditions. The article also explains the polarization effects during the formation of stable aluminum oxide under dynamic conditions. It concludes with information on the designation system for aluminum finishes.

Coatings and other surface modifications are used for a variety of functional, economic, and aesthetic purposes. Two major applications of thermal spray coatings are for wear resistance and corrosion resistance. This article discusses thermal (surface hardening) and thermochemical (carburizing, nitriding, and boriding) surface modifications, electrochemical treatments (electroplating, and anodizing), chemical treatments (electroless plating, phosphating, and hot dip coating), hardfacing, and thermal spray processes. It provides information on chemical and physical vapor deposition techniques such as conventional CVD, laser-assisted CVD, cathodic arc deposition, molecular beam epitaxy, ion plating, and sputtering.

The corrosion process that occurs in industrial systems is often difficult to discern until extensive deterioration has occurred. For boilers to function properly, the incoming water must be processed to meet the water quality required for the boiler. This article discusses pretreatment methods of the incoming water and preboiler corrosion protection methods. It analyzes internal treatment and condensate treatment of boilers. The article discusses three types of cooling systems: once-through systems, open recirculating systems, and closed recirculating systems. The corrosion processes which occur in water-recirculating systems and the effect of dissolved gases, temperature, pH, suspended solids, dissolved salts, and scale deposition on corrosivity of water, are also reviewed. The article also considers anodic and cathodic inhibitors and the control of corrosion in municipal water systems.

This article begins with a discussion on the environmental factors that induce corrosion in magnesium alloys. It reviews the factors that determine the severity of different forms of localized corrosion, namely, galvanic corrosion, corrosion fatigue, and stress-corrosion. The article discusses corrosion protection in magnesium assemblies and the protective coating systems used in corrosion protection practices. Protection schemes for specific applications and the production of novel magnesium alloys with improved corrosion resistance are also reviewed. The article concludes with a discussion on the corrosion of bulk vapor-deposited alloys and magnesium-matrix composites.

Aluminum components are often plated with other metals to mitigate the effects of corrosion and wear, improve application performance, and extend service life. This article discusses some of the more common aluminum plating processes, including electroplating, immersion plating, and electroless plating, and describes various plating materials and the types of applications in which they are used. It provides critical processing details such as temperatures, ratios, ranges, times, and rates. The article explains how to prepare aluminum components for electroplating, discussing surface roughening, anodizing, and immersion procedures along with expected results.