This article focuses on the environmentally assisted cracking (EAC) of structural materials in boiling water reactors (BWRs), reactor pressure vessels, core internals, and ancillary piping. It discusses the effects of water chemistry on materials degradation, mitigation approaches, and their impact on aging management programs. The article reviews the effects of materials, environment, and stress factors on the cracking susceptibility of ferritic and austenitic structural alloys in BWRs. It describes the methods, such as data-based life-prediction approaches and mechanisms-informed life-prediction approaches, for predicting cracking kinetics in BWRs. The article provides information on several EAC mitigation techniques for BWR components, namely material solutions, stress solutions, and environmental solutions.

X-ray spectroscopy is generally accepted as the most useful ancillary technique that can be added to any scanning electron microscope (SEM), even to the point of being considered a necessity by most operators. While “stand-alone” x-ray detection systems are used less frequently in failure analysis than the more exact instrumentation employed in SEMs, the technology is advancing and is worthy of note due to its capability for nondestructive analysis and application in the field. This article begins with information on the basis of the x-ray signal. This is followed by information on the operating principles and applications of detectors for x-ray spectroscopy, namely energy-dispersive spectrometers, wavelength-dispersive spectrometers, and handheld x-ray fluorescence systems. The processes involved in x-ray analysis in the SEM and handheld x-ray fluorescence analysis are then covered. The article ends with a discussion on the applications of x-ray spectroscopy in failure analysis.

This article addresses the effects of damage to equipment and structures due to explosions (blast), fire, and heat as well as the methodologies that are used by investigating teams to assess the damage and remaining life of the equipment. It discusses the steps involved in preliminary data collection and preparation. Before discussing the identification, evaluation, and use of explosion damage indicators, the article describes some of the more common events that are considered in incident investigations. The range of scenarios that can occur during explosions and the characteristics of each are also covered. In addition, the article primarily discusses level 1 and level 2 of fire and heat damage assessment and provides information on level 3 assessment.

This article provides information on the application of nondestructive examination (NDE) technologies to tube and pipe products. These include modeling and simulation methods, eddy-current methods, magnetic methods, acoustic methods, and physical methods. A summary of nondestructive examination methods based on flaw type and product stage is presented in a table. The article also discusses in-service inspection of tubular products and presents an example that illustrates the importance of nondestructive testing (NDT) for welds in austenitic stainless steel tubing.

This article discusses the safety issues associated with the design and operation of thermal spray booths and spray box structures and the equipment or systems required for operating thermal spray processes. It describes the design elements necessary to mitigate sound, dust and fume, ultraviolet light, and mechanical hazards. The means selected for safeguarding personnel must be based on a formal risk assessment that meets ANSI/RIA standards. The safeguards include sensing devices, barriers, awareness signals, procedures, and training. It also provides guidelines that are intended to increase the safety awareness and the use of safety practices for gas and liquid piping and electrical equipment within thermal spray installations.

This article discusses the methods of pulp production, pulp processing, pulp bleaching, and paper manufacturing. It describes various types of digesters, their construction materials, the corrosion problems encountered, and methods to protect these digesters from corrosion. The article examines the corrosion problems in high-yield mechanical pulping, sulfite process, neutral sulfite semichemical pulping, chemical recovery, tall oil plants, wastewater treatment, and recovery boilers. It explains the stages of chlorine-based and nonchlorine bleaching, process water reuse for elemental chlorine-free and nonchlorine bleaching stages, selection of material for bleaching equipment, developments in oxygen bleaching, and the use of highly corrosion-resistant materials for bleach plant equipment. The article reviews the materials used in the construction of paper machine components and specific corrosion problems that affect them. It discusses the composition and corrosive nature of white water. The article also addresses the corrosion and chemical recovery associated with kraft pulping liquors.

This article discusses the particular corrosion problems encountered and the corrosion control methods used in petroleum production (i.e., upstream) and the storage and transportation of oil and gas (i.e., midstream) up to the refinery (i.e., downstream). These control methods include proper material selection, protective coatings, cathodic protection systems, use of inhibitors, use of nonmetallic materials, and control of the environment. The article reviews the aspects of corrosion that tend to be unique to corrosion as encountered in applications involving oil and gas exploration and production. It discusses corrosion problems that are specific to the various types of environments or equipment used in secondary recovery, including producing wells, producing flow lines, and injection wells. Corrosion mitigation methods and guidelines are also discussed for each type of environment.

Quenchant agitation can be obtained by circulating quenchant in a quench tank through pumps and impellers. The selection of the agitation method depends on the tank design, type and volume of the quenchant, part design, and the severity of quench required. This article describes flow measurement methods, temperature control, materials handling, and filtration processes during the agitation process. The maintenance of quenching installations is also discussed.

This article reviews the use of thermal spray polymer coatings as a replacement for paints. It discusses the applications of the thermal spray forming process. The article also provides information on the applications of thermal spray in metal processing, textile and plastics, and ceramic and glass manufacturing industries.

This article describes the technology of thermal spraying with regard to tribological applications. It introduces the basics of tribology and presents the fundamentals of thermal spraying and the relevant process variants and suitable materials. Specific application areas are described regarding the different forms of elementary movement in the corresponding tribological system. The article provides an overview of thermal spray coatings and possible uses for friction and wear control, besides operating as corrosion protection and a thermal barrier. The article provides examples that illustrate how tribological performance can be improved.

This article describes the phenomena of crack initiation and early growth. It examines specimen design and preparation as well as the apparatus used in crack initiation testing. The article provides descriptions of the various commercially available fatigue testing machines: axial fatigue testing machines and bending fatigue machines. Load cells, grips and alignment devices, extensometry and strain measuring devices, environmental chambers, graphic recorders, furnaces, and heating systems of ancillary equipment are discussed. The article presents technologies available to accomplish closed loop control of materials testing systems in performing standard materials tests and for the development of custom testing applications. It explores the advanced software tools for materials testing. The article includes a description of baseline isothermal fatigue testing, creep-fatigue interaction, and thermomechanical fatigue. The effects of various variables on fatigue resistance and guidelines for fatigue testing are also presented.

This article discusses composites for unmanned space vehicles and provides an overview of key design drivers, challenges, and environment for use of composites in spacecraft, launch vehicles, and missiles. It describes the design allowable properties of composite materials. The article provides information on the specific state-of-the-art applications of composite materials for spacecraft missiles and launch vehicles. A discussion on the key applications, including solid rocket motor casings, payload fairings, and payload support structures, is presented.

This article provides practical information and data on property development in engineering plastics. It discusses the effects of composition on submolecular and higher-order structure and the influence of plasticizers, additives, and blowing agents. It examines stress-strain curves corresponding to soft-and-weak, soft-and-tough, hard-and-brittle, and hard-and-tough plastics and temperature-modulus plots representative of polymers with different degrees of crystallinity, cross-linking, and polarity. It explains how viscosity varies with shear rate in polymer melts and how processes align with various regions of the viscosity curve. It discusses the concept of shear sensitivity, the nature of viscoelastic properties, and the electrical, chemical, and optical properties of different plastics. It also reviews plastic processing operations, including extrusion, injection molding, and thermoforming, and addresses related considerations such as melt viscosity and melt strength, crystallization, orientation, die swell, melt fracture, shrinkage, molded-in stress, and polymer degradation.

This article aims to identify and illustrate the types of overload failures, which are categorized as failures due to insufficient material strength and underdesign, failures due to stress concentration and material defects, and failures due to material alteration. It describes the general aspects of fracture modes and mechanisms. The article briefly reviews some mechanistic aspects of ductile and brittle crack propagation, including discussion on mixed-mode cracking. Factors associated with overload failures are discussed, and, where appropriate, preventive steps for reducing the likelihood of overload fractures are included. The article focuses primarily on the contribution of embrittlement to overload failure. The embrittling phenomena are described and differentiated by their causes, effects, and remedial methods, so that failure characteristics can be directly compared during practical failure investigation. The article describes the effects of mechanical loading on a part in service and provides information on laboratory fracture examination.

This article discusses the operation principles, advantages, limitations, process parameters, consumables or electrodes, the equipment used, process variations, and safety considerations of gas metal arc welding (GMAW). It reviews the important variables of the GMAW process that affect weld penetration, bead shape, arc stability, productivity, and overall weld quality. These include welding consumables, equipment settings, and gun manipulation. The major components of a GMAW installation such as a welding gun, shielding gas supply, electrode feed unit, power source, and associated controls are discussed.

This article discusses the influence of the materials, design, package type, and environment on corrosion in microelectronics. It describes the common sources and mechanisms of corrosion in microelectronics, including anodic, cathodic, and electrolytic reactions resulting in uniform corrosion, galvanic corrosion, pitting corrosion, creep corrosion, dendrite growth, fretting, stress-corrosion cracking, and whisker growth. The article presents effective measures for minimizing the moisture retention in hermetic packages and/or moisture ingress in plastic packages. It concludes with information corrosion tests.

This article discusses various control processes carried out in powder feeding, thermal spraying, and gas flow of the thermal spray process to standardize the coating quality. Quality of the entire powder feeding process can be achieved by controlling the processing of feeding equipment as well as the characteristics of the powder being fed. Gas flow control can be achieved by using rotameters, critical orifices, and thermal mass flowmeters, whose ability to provide useful information is defined by their resolution, accuracy, linearity, and repeatability. The commercial thermal spray controls discussed here include the open-loop input-based, open-loop output-based, closed-loop input-based, and closed-loop output-based or adaptive controls. The article discusses the common causes and practical solutions for arc starting problems. It also outlines certain important developments in measuring individual and collective particle velocities, temperature, and trajectories as well as other plume characteristics for the plasma spray process.

This article discusses the most fundamental building-block level, atomic level, molecular considerations, intermolecular structures, and supermolecular issues. It contains a table that shows the structures and lists the properties of selected commodity and engineering plastics. The article describes the effects of structure on thermal and mechanical properties. It reviews the chemical, optical, and electrical properties of engineering plastics and commodity plastics. An explanation of important physical properties, many of which are unique to polymers, is also included. The factors that must be considered when processing engineering thermoplastics are discussed. These include melt viscosity and melt strength; crystallization; orientation, die swell, shrinkage, and molded-in stress; polymer degradation; and polymer blends.

This article presents a detailed account of directed-energy deposition (DED) processes that are used for additive manufacturing (AM) of metallic materials. It begins with a process overview and a description of the components of DED systems followed by sections providing information on the process involved in DED and the materials used for DED. The postprocessing applied to the material after deposition is then covered. The article discusses the properties of metallic materials produced by using DED and ends with a discussion on applications for DED processes in various industries.